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211.
根据实验样品的成分,制定一定的浮法成型的温度制度,采用自制小型石墨锡槽,模拟硼硅酸盐玻璃的浮法成型过程,用电子探针结合能谱仪,测试浮法硼硅酸盐玻璃在1250~650℃温度范围内不同温度段下表面渗锡的分布情况,研究硼硅酸盐玻璃不同于传统钠钙硅浮法玻璃的渗锡特点。研究结果表明,在特定的浮法工艺制度下,硼硅酸盐玻璃渗锡的深度达到40μm左右,并且高温段锡离子以纵向深度扩散为主,低温下锡离子主要在玻璃的近表面富集。在浮法成型的过程中,渗锡的分布曲线上会出现卫星峰,但是最终在出锡槽的温度下渗锡曲线是单调递减的。 相似文献
212.
废弃木粉与短切玻璃纤维组合增强聚丙烯的力学性能 总被引:1,自引:0,他引:1
用废弃木粉与短切玻璃纤维作为增强材料,制得了组合增强的聚丙烯复合材料,研究了制备工艺及设备、材料配方及界面改性方法等对材料力学性能的影响。结果表明,用单螺杆挤出机制备组合增强材料,可减少对玻璃纤维的损伤,保持较长的玻璃纤维,有利于其增强作用的发挥;随着玻璃纤维含量的增加,体系的力学性能提高,而木粉含量对材料力学性能的影响与玻璃纤维的含量相关;采用硅烷偶联剂对木粉进行表面处理,在基体中添加接枝极性基团的改性聚丙烯,可改善体系的界面结合,提高力学性能。 相似文献
213.
Mataz Alcoutlabi 《Polymer》2004,45(16):5629-5634
Prior work from this laboratory has reported anomalous differences in the viscoelastic responses between temperature-jump formed glasses and carbon dioxide pressure-jump or relative humidity formed glasses. In the present work, we investigate the anomalous behaviour further by examining the structural response of an epoxy resin after pre-annealing treatments. In particular, we have measured the volume change of amine-cured diglycidyl ether of bisphenol A after thermal and carbon dioxide pressure (PCO2) treatments. Our results show that contrary to prior interpretations in the literature, a plasticizer quench is different from a temperature hyperquench. Consistent with our prior work, the CO2-formed glass is more stable than the temperature-formed glass in spite of the former having a higher excess volume. Our new results show that the stability persists to above the nominal glass temperature, contrary to what happens in a temperature hyperquench. 相似文献
214.
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216.
The effect of hygrothermal aging on a particle‐filled, epoxy‐based adhesive was studied using a gravimetric sorption technique. This study has explored moisture sorption characteristics as well as the associated behaviors of swelling and the depression of the glass transition temperature (Tg). We observed that the diffusion of water in this adhesive has a non‐Fickian behavior, and the depression of Tg proceeds to a definite value that is independent of the final equilibrium water content of the system. Our observations suggest that water diffuses into the polymer in a dual‐sorption mode, in which water resides in two populations. In one population, water is considered to occupy apparent free volume of the adhesive, and the second population water infiltrates polymer structure and forms hydrogen‐bonded clusters. Our results show that hygrothermal aging temperature and swelling do not alter the apparent free volume of this adhesive. We conclude that the constant value of Tg depression at saturation implies that only water in the apparent free volume is responsible for the Tg depression, whereas the swelling proceeds through the formation of hydrogen bonds in the adhesive. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1436–1444, 2003 相似文献
217.
包边技术是提高大尺寸激光玻璃饱和增益系数的关键技术.采用传统的方法熔制玻璃,研究了P2O5含量对P2O5-Al2O3-B2O3-CuCl-Na2O-ZnO磷酸盐包边玻璃的折射率、热膨胀系数、玻璃转变温度、膨胀软化温度以及化学稳定性的影响.结果表明:当P2O5的摩尔分数为60%左右,玻璃样品具有最高的折射率(1.5220)、最低的玻璃转变温度(352.4℃)、较好的化学稳定性[0.52mg/(cm2·d)]和适宜的热膨胀系数(128.427×10-7/℃),是用作钕磷酸盐激光玻璃硬包边的理想材料. 相似文献
218.
制造泡沫玻璃的方法与模具 总被引:3,自引:0,他引:3
将泡沫玻璃配合料制备成块状物,将配合料块按规定间隙在模具中平铺码放并烧成,使配合料块熔为一体,形成较小变形的平板状泡沫玻璃.其制造模具是由底板、上盖及L型围板构成的箱型结构,模具各部位通过V字沟相互联结,保证各部位能自由地附着和脱离.模具多层码放烧制,模具间必须设置间隙.在模具上设置通孔可以有效地抑制膨胀过量问题. 相似文献
219.
We have synthesized a series of fully aliphatic polyimides (APIs) from bicyclo[2,2,2]oct‐7‐ene‐2,3,5,6‐tetracarboxylic dianhydride (BOCA) and various aliphatic diamines, including linear aliphatic, flexible alicyclic, and rigid adamantyl diamines. We performed the polymerization reactions using one‐step syntheses in m‐cresol at elevated temperatures without the isolation of poly(amic) acid. The chemical composition and structure of the polymers were characterized by nuclear magnetic resonance (NMR) and infrared (IR) spectrometry. The characterization data are reported from analyses using gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimeter (DSC), and wide‐angle X‐ray diffraction (WXAD) measurements. The polyimides are also subjected to solubility, solution viscosity, tensile strength, transparency, and dielectric constant measurements. The resultant polyimides possess well‐controlled molecular weight, reasonable intrinsic viscosity, good transparency, enhanced solubility, low dielectric constants, and high glass transition temperature, together with marginal thermal and mechanical stability. These properties were enhanced in copolyimides containing equimolar amounts of rigid and flexible moieties. These rigid‐rod APIs derived from the alicyclic dianhydride and aliphatic diamines are promising candidates as advanced materials for future applications in micro‐ and photoelectronic devices. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3316–3326, 2006 相似文献
220.
Toshinobu Yoko Toshio Nishiwaki Kanichi Kamiya Sumio Sakka 《Journal of the American Ceramic Society》1991,74(5):1104-1111
Cu+ ⇌ R+ (R = Li, Na, and K) ion exchange experiments were conducted for 20R2 O·10Al2 O3 ·70SiO2 glasses in molten CuCl at 550°C in air and nitrogen atmospheres. The depth profiles of the copper incorporated into glasses were determined with an electron microprobe X-ray analyzer. The total amount of diffusing copper, M t , strongly depended on the type of alkali ion in the glass and the ion-exchange atmosphere; i.e., M t increased with increasing cationic size in the order Li < Na < K and M t was greater in air than in nitrogen. The Cu ⇌ R+ ion exchange kinetics are discussed in detail. 相似文献