（Ba1-xSrx）（Zn1/3Nb2/3）O3微波介质陶瓷温度系数的异常

研究了（Ba1-xSrx）（Zn1/3Nb2/3）O3微波介质陶瓷温度系数的非线性变化以及异常的原因。根据CM公式，随着系统中Sr（Zn1/3Nb2/3）O3的增多，τc的异常是由于氧八面体的畸变导致的相转变（对称性降低）所造成的（晶体结构由无序立方相向有序赝立方相的连续变化）。相转变的发生相应影响了极化以及极化模式，这是造成τc异常的根本原因。     

Study on Dihydrated Praseodymium Acetylacetonate by Photoacoustic Spectra with Broad Wavelength Range

Photoacousticspectroscopy (PAS)hasbeenusedtonondestructivelyinvestigatealmostallkindsofsam ples,whetherthesampleiscrystalline ,powderorgel .PAspectr oscopyisacalorimetrictechniquewhichmeasurestheenergyabsorbedandsubsequentheatingofthesamplesduetoanonradiativerelaxationpro cess .ThereforePAScanbeusedtostudyopaque ,highlyreflectiveandscatteringsamples ,whicharedif ficulttostudybyconventionalspectroscopytech niques[1] .Withouttheneedofsamplepreparation ,PASavoidstheriskofsamplealteration ,pre…     

溶胶-凝胶生物玻璃多孔材料显微结构和生物活性的扫描电镜及红外光谱分析

本文利用溶胶．凝胶法制备了CaO-P2O5-SiO，系统生物活性玻璃，并以其为原料制备了用于骨修复及骨组织工程支架的块状生物活性材料。利用体外实验方法(invitro)结合x射线衍射(XRD)、扫描电子显微镜(SEM)和傅立叶变换红外光谱分析(FTIR)技术对不同烧结工艺制备的材料结构、晶相和生物活性的影响进行了分析研究。研究表明，经800℃和1100℃烧结5min的两种材料均有硅磷酸钙Ca5(PO4)2SjO4微晶相析出。烧结温度越高，析出微晶相的体积比例越大，材料的生物活性则越低。在模拟生理溶液中碳酸羟基磷灰石(HCA)只在烧结体中的玻璃颗粒表面形成，而在其硅磷酸钙Ca5(PO4)2SiO4微晶相表面未发现HCA形成。     

棒状液晶分子相变问题的机械旋转模型研究

综述一种关于棒状液晶材料的分子结构与液晶相的相关关系的研究成果。介绍了有关液晶分子的机械旋转模型。该模型将液晶分子视作一种高速旋转的转子,通过分子参数计算,对液晶材料的相变温度和分子结构之间的关系给出了一种全新的解释。最新研究表明,含氟三苯液晶材料的分子结构中存在slim和fat现象,能够对液晶材料的相变进行合理解释。该模型能够通过简单的模型方法对新型液晶材料的分子设计与合成提供有用的信息。     

转动玻璃圆筒激光器

本文介绍了转动玻璃圆筒激光器的设计及实验结果,得到了脉冲能量为13J,重复频率为15Hz的激光输出。电光转换效率为2.2％,斜效率为3.4％。     

燕山石化巨型塔器整体液压连续平移技术

北京燕山石化两巨型塔器在国内首次使用整体液压连续平移技术安装成功。该项技术可缩短工期,降低费用,提高安装的平稳性。     

Crystallization of glass in fireclay refractories; part III: Detailed study on the mullite crystal size in the ‘synthetic’ glass

Poor-grade fireclay products contain substantial amount of glass. A glass of similar composition was synthesized, nucleated and heat-treated for crystallization of mullite. The size and size-distribution of mullite crystals, the rate of change of size and the aspect ratio of the crystals were investigated in relation to the nucleating agents and temperature.     

RLL码的计算机辅助设计

本文着重讨论计算机辅助设计RLL码的具体实现问题.该过程首先根据RLL码两个参数d,k确定一个编码率p/q,然后构造出RLL码的高阶状态转换-输出符号矩阵并求相应的近似特征向量.最后通过状态分裂和状态归并过程,即可得到一个满足d,k约束的编码输出表.其中状态转换-输出符号矩阵为实现计算机辅助设计RLL码提供了有效的数据结构,而且要优化RLL码编码器,就必须有选择地进行状态分裂.     

Photoresponsive peptide and polypeptide systems: part II. Photochromism of poly(l-ornithine) containing various azo-contents in side chains

Poly(L-ornithine)s having various azo-contents in the side chains were synthesized by the water-soluble carbodiimide procedure. The photochemical properties of the polypeptides poly[N^δ-p-(phenylazo)benzoyl-L-ornithine] (PPABLO) containing 3–77 mol% azobenzene were investigated by absorption and circular dichroism spectroscopy in hexafluoro-2-propanol (HFIP) or water, and in HFIP-water or methanol-water solvent mixtures. The photochromism of the dichroic bands of the PPABLOs containing 20–77 mol% azobenzene in the visible and ultraviolet wavelength regions was found to be mostly reversible as a function of irradiation time at different wavelengths due to the photostationary state (above 80% trans-cis photoisomerization) of the azo aromatic moieties. The PPABLO containing 3.2 mol% azobenzene in water exhibited conformational changes from random coil to helix by the addition of methanol or sodium dodecyl sulphate (SDS). The photo-induced conformational change was observed in HFIP-water-SDS solvent mixtures, while no conformational change was seen in water and HFIP-water solvent mixtures.     

氟挥发对氟化物乳白玻璃瓶罐生产的影响

氟挥发对氟化物乳白玻璃瓶罐生产的影响陆德明，周俊梅，付希英（山东轻工业学院２５０１００）（山东德州玻璃厂２５３０１９）ＴｈｅＩｎｆｌｕｅｎｃｅｏｆＦｌｕｏｒｉｎｅＶｏｌａｔｉｌｉｚａｔｉｏｎｏｎＰｒｏｄｕｃｔｉｏｎｏｆＦｌｕｏｒｉｄｅｏｐａｌＧｌａｓ...