纳米金丝电导量子效应

综述了纳米金丝电导量子效应的基本概念，介绍了金丝电导研究背景及现状，并从理论上分析了电导量子效应的机理。介绍了用STM和MCBJ等工具对纳米金丝的原子基链进行的研究。纳米金丝原子基链的电导是量子化的，量子电导受到包括电场、磁场、温度等各种因素的影响。在综述的基础之上，提出了该领域未解决的科学问题并指出了该领域未来的发展方向。     

用电生的Fe(Ⅱ)-EDTA络合物在Fe(Ⅲ)-EDTA-ClCH2COOH-NaOAc缓冲溶液中精密库仑滴定金

提出了在Fe(Ⅲ)-EDTA—ClCH2COOH—NaOAc缓冲溶液中利用电生Fe(Ⅱ)-ED-TA络合物精密库仑滴定Au的方法。采用电位法检测终点，测定范围在5．2～17．0mg Au时，相对平均误差和标准偏差≤0．03％。方法可用于纯金、金合金和首饰等材料中Au含量的精密分析，选择性很好。讨论了电生Fe(Ⅱ)-EDTA络合物作库仑滴定剂的理论基础，获得了有益的结论。     

Ar^39／Ar^40 dating of three typical gold deposits in southern Qinling and its implication

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Effects of gold plating on the resistance to high temperature discoloration of the cavity for ceramic packages

The effects of thickness and types of gold plating on the resistance to high temperature discoloration of gold plating on cavity surface of ceramic package were investigated. It was found that the thicker gold plating, the less discoloration degree for ceramic packages. Non-cyanide gold plating performed better resistance to high-temperature aging than cyanide gold plating. The relationship between the gold plating thickness and the amount of diffused Ni to the gold plating of ceramic packages with Au/Ni and Au/Ni-Co platings after heating at 420℃for 15 min was also studied. When the gold plating thickness reach 2.0 μm and 1.6 μm for Au/Ni and Au/Ni-Co plating systems, respectively, no discoloration was observed on the gold plating surface of cavity, and the corresponding diffused Ni amounts (mass fraction) are 1.0% and 0.4%, while the diffused Co to the gold plating is 0.04%.     

晋东北金矿床石英流体包裹体与找矿

晋东北各种类型金矿中都广泛发育热液型石英脉，与矿化有关的石英流体包裹体的特征反映了不同的矿床类型。对该区石英脉型、蚀变岩型及磁铁石英岩型金矿床的研究表明，石英中流体包裹体的成分、温度和红外吸收光谱等特征可以作为划分矿床类型和作为金矿找矿评价的标志     

XPS characteristics of sulfur of bio-oxidized arsenic-bearing gold concentrate and changes of surface nature of bio-oxidation residue

During bio-oxidation of sulfides, the chemical state change of sulfur is a complex and key factor. It is not only an indicator of the extent and intensity of the bio-oxidation, but also controls the property of bio-leaching medium and the period of oxidation. The chemical state of sulfur in sulfides oxidized by leaching bacteria was studied with XPS. Sulfide minerals in the arsenic-bearing gold concentrate consist of pyrite, arsenopyrite, chalcopyrite, galena, sphalerite and so on. In order to probe the pattern of the chemical state change of sulfur in the bio-oxidation residue of arsenic-bearing gold concentrate, the structure of the grains, and the surface nature of the residue, XPS test was carried out through different sputtering duration. The study of XPS clearly shows that: sulfides is progressively oxidized from the surface of minerals to the core by leaching bacteria; the chemical valence of sulfur changes from S^2- or [S2]^2- to [SO4]^2- ; sulfur in the core is in a reduction state, S^2- or [S2]^2- , but exists in an oxidation state S^6 on the surface; due to the chemical state change of sulfur, mineral phase of the bio-oxidation residue is also changed(sulfides inside, while sulfates outside); the layered structure is found in the grains of the bio-oxidation residue.     

Gold leaching with elemental sulfur in alkaline solutions under oxygen pressure

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Bioleaching of refractory gold ore （ Ⅲ ）——Fluid leaching Jinya refractory gold concentrate by Thiobacillus ferrooxidans

A novel fluidized-bed reactor was designed and installed for bloleaching in a semi-continuous way, by which a process for biuleaching-cyanidation of Jinya refractory gold arsenical concentrate was studied. The arsenic extraction rate reaches 82.5 % after 4-day batch biooxidation of the concentrate under the optimized condition of pH 2.0, ferric ion concentration 6.Sg/L and pulp concentration 10%. And leached rate of gold in the following cyanida.tion is over 90%. The parameters of three series fluidized-bed reactors exhibit stability during the semi-continuous bioleaching of the concentrate.Armmic in the concentrate can be got rid of 91% after 6-day leaching. Even after 4 days, 82% of arsenic extraction rate was still obtained. The recovery rates of gold are 92 % and 87.5 % respectively in cyaniding the above bioleached residues.The results will provide a base for further commercial production of gold development.     

铜基仿金合金

为了寻找金的代用品,长期以来研究者竞相研制铜基仿金合金以满足制造较大的金色艺术品。文中阐述了研制铜基仿金合金的原理及其金色度和抗变色性的测试方法,分别叙述了铝、锌、锡、铟、硅、镍、稀土等元素对合金金色度和抗变色性的影响。鉴于各研究者得出的合金化学成分相差极大,最后提供了较为合理的铜基仿金合金的化学成分。     

无氰电刷镀金技术在航天工业中的应用

应用FJY-18无氰电刷镀金技术制得的金镀层具有孔隙率低、色泽金黄、光亮、结合力好,镀厚能力大于20μm,显微硬度HV=130～150,施工温度范围宽、无毒等特点,该技术已用于航天工业中某一关键部件的表面减磨密封镀金.