An electrochemical study of the dissolution of gold in thiosulfate solutions. Part II. Effect of Copper

Thiosulfate has been considered as one of the most promising of the non-toxic alternatives to cyanide for the leaching of gold and much work has been carried out with the aim of understanding and improving the ammoniacal thiosulfate leaching process. In particular the behaviour of gold in thiosulfate solutions containing copper in the absence of ammonia has received little attention. It has been shown in this study involving electrochemical and leaching tests that copper ions catalyze not only the oxidation of thiosulfate but also the dissolution of gold in alkaline thiosulfate solutions. Electrochemical studies have shown that copper has a positive effect on the anodic dissolution of gold with increasing concentrations of copper resulting in higher dissolution rates of gold at a potential of 0.3V. Studies on the dissolution of gold powder in alkaline oxygenated thiosulfate solutions containing low concentrations of copper have shown that the role of copper in enhancing the dissolution rate of gold is possibly associated with the formation of a copper–thiosulfate–oxygen intermediate which is more reactive in terms of cathodic reduction than dissolved oxygen. The electrochemical experiments have been complemented by a leaching study which has shown that milling of gold powder in the presence of copper (added as ions, metal, or oxide) assists with the dissolution of gold in thiosulfate solutions.     

铜及其合金电解仿金着色工艺

详细介绍了一种铜及铜合金阴极还原着仿金色工艺及其配方。探讨了该工艺的着色原理、电流密度的影响及所得着色膜层的性能。结果表明，该工艺所得的膜层呈金黄色，结晶致密，耐蚀性好。     

自含砷合碳难处理金矿中提取金的研究─Ⅰ.氨水脱砷-石灰加压氧化-氰化

针对甘肃省坪定金矿含金、砷高、金部分地赋存于脉石、脉石为碱性、属于难选难冶矿的特点，提出了氨水脱砷－石灰加压氧化－氰化新工艺．当原矿含金8．7g／t及13．0％砷时，砷可脱除95％，金可浸出85％．技术及经济指标预计均较满意．     

Promotional effect of hydroxyl on the aqueous phase oxidation of carbon monoxide and glycerol over supported Au catalysts

Gold particles supported on carbon and titania were explored as catalysts for oxidation of CO or glycerol by O₂ at room temperature in liquid-phase water. Although Au/carbon catalysts were not active for vapor phase CO oxidation at room temperature, a turnover frequency of 5 s⁻¹ could be achieved with comparable CO concentration in aqueous solution containing 1 M NaOH. The turnover frequency on Au/carbon was a strong function of pH, decreasing by about a factor of 50 when the pH decreased from 14 to 0.3. Evidently, a catalytic oxidation route that was not available in the vapor phase is enabled by operation in the liquid water at high pH. Since Au/titania is active for vapor phase CO oxidation, the role of water, and therefore hydroxyl concentration, is not as significant as that for Au/carbon. Hydrogen peroxide is also produced during CO oxidation over Au in liquid water and increasing the hydroxyl concentration enhances its formation rate. For glycerol oxidation to glyceric acid (C₃) and glycolic acid (C₂) with O₂ (1–10 atm) at 308–333 K over supported Au particles, high pH is required for catalysis to occur. Similar to CO oxidation in liquid water, H₂O₂ is also produced during glycerol oxidation at high pH. The formation of the C-C cleavage product glycolic acid is attributed to peroxide in the reaction.     

桂东大瑶山地区金矿床的成矿构造类型及其成矿指示

广西大瑶山地区金矿的成矿构造类型可分为两大类：一类为流体型成矿构造,另一类为构造型成矿构造。其中：流体型成矿构造有流体脉型、流体角砾岩型及流体细脉型;构造型成矿构造有构造蚀变岩型、构造脉型。构造解析后认为：桃花金矿床的控矿构造（指控制成矿构造的构造）为伸展型脆-韧性剪切带,早期成矿构造类型主要为流体脉型,晚期为构造蚀变岩型;古袍志隆金矿床的控矿构造为逆-平型脆-韧性剪切带,早期成矿构造类型为流体细脉型、流体脉型,晚期为构造蚀变岩型;古袍湾岛金矿床的控矿构造为发育于顺层侵位花岗斑岩中的脆性破裂带,早期成矿构造类型为流体细脉型,属雏形成矿构造（控制特富金矿包）,晚期为构造蚀变岩型;龙水金矿床的控矿构造为走滑型脆-韧性剪切带,其成矿构造类型为流体脉型;六岑金矿床的控矿构造为与隐伏酸性岩体侵位有关的节理-断裂型脆性破裂构造,其成矿构造类型为构造脉型及构造蚀变岩型。基于对该区金矿床成矿构造类型的划分及控矿构造类型的研究,本文对广西大瑶山地区主要金矿床（点）的成矿前景作出了评估。     

硅基上金粒子诱导的聚氧硅烷纳米线的合成

采用液相法以硅基上原位合成的金纳米粒子作为催化剂和模板,在不同的反应条件下,用十八烷基硅烷（Octadecylsilane）作为前驱体合成了纳米线状化合物．研究了不同反应条件对该线状化合物形貌的影响,能量散射光谱实验结果表明该线状化合物为聚氧硅烷,扫描电镜结果显示当反应温度控制在110℃和反应时间90min的条件下,可得到均匀的纳米线状化合物．最后提出了聚氧硅烷化合物可能的形成机理,同时也为制备硅基上的硅氧纳米线状化合物提供了一种方便而简单的方法．     

金免疫层析试条检测线的提取

针对反射型光纤传感器测量金免疫层析试条反应结果的工作原理和不足,在扫描检测的基本原理下,提出积分扫描的方法提取试条的检测线,并且分析该方法的可行性,给出了检测线提取的程序流程图,试验结果表明：该方法在检测线不倾斜的情况下,可以较精确地提取检测线。     

HPV16型免疫胶体金诊断试纸条的制备

建立一种快速、准确、简便检测高危型人乳头瘤病毒16型的胶体金诊断试纸条,以用于宫颈癌的早期筛查。用柠檬酸三钠还原法制备了酒红色的30 nm胶体金颗粒,胶体金颗粒标记的单抗的实际标记量为6μg/mL。选用了2种稳定剂BSA和PEG20000获得了稳定的金标抗体溶液。实验结果表明:第7种样品垫处理液和第7种结合垫处理液处理样品垫和结合垫组装的试纸条效果最好;试纸条检测HPV16E6蛋白为阳性,检测HPV16L1蛋白为阴性。     

对苯二酚在金、银纳米粒子修饰的玻碳电极上电化学响应的比较

制备了柠檬酸钠保护的金和银纳米粒子,并用自组装法制备了金和银纳米粒子修饰的玻碳电极,在近中性的磷酸缓冲溶液中,比较研究对苯二酚在金和银纳米粒子修饰玻碳电极上的电化学响应情况。结果表明金和银纳米粒子均对对苯二酚的电氧化过程具有优越的电催化效果;与银纳米粒子修饰电极相比,金纳米粒子修饰电极表现出了良好的稳定性;对苯二酚在金纳米粒子修饰玻碳电极上的电化学反应是受扩散控制的。     

贵州省盘县陇英大地金矿床成矿地质特征及找矿评价

通过对贵州省盘县陇英大地金矿床金矿矿区地层、构造、矿体特征、矿石特征等方面的研究,初步认为该区金矿体主要产于峨眉山玄武岩组一段及二段玄武质熔岩底部,受断层旁侧的节理、裂隙控制金矿体在断层破碎带内呈顺层和穿层两种状态产出。此外,通过对贵州省盘县地区峨眉山玄武岩底部和玄武岩之间的凝灰岩中的微细粒浸染型金矿床的研究,认为此类金矿的区域分布受控于峨眉山玄武岩及其边缘凝灰岩分布区;区域性控矿构造如扬子陆块西南缘的深部构造和区域性深大断裂,控制了金矿成矿及矿体的形成和分布,局部性构造决定了矿体的空间分布及产出特征。最后提出在该区寻找相同类型金矿的找矿标志及找矿远景。