超微粒乳剂的制备及量子尺寸效应的研究

本文制备了四种不同粒度的超微粒AgBr照相乳剂,用X射线衍射技术对其粒子的大小进行了测定;观察到乳剂的紫外吸收峰随晶体颗粒的减小表现出逐渐蓝移;本文提出晶体表面的悬键的存在使得纳米晶体的平均键能升高,并对纳米AgBr乳剂的量子尺寸效应进行了解释。     

大断面交岔点失稳分析及治理

通过工程地质调查、室内围岩物化分析和力学试验 ,深入研究了围岩变形力学机制和破坏机理 .根据新奥法施工原理 ,采取了有针对性的综合治理措施 ,将围岩复杂的变形力学机制转化为单一的变形力学机制 ,使该工程得到了有效治理 .取得的技术经验推广应用于该矿井其它失稳破坏工程 ,均获得了圆满成功     

The current and residual value of superphosphate for lupins grown in rotation with oats and wheat on a deep sandy soil

In a field experiment on a deep pale-yellow sand in a 600 mm per annum rainfall Mediterranean environment of south-western Australia, six levels of phosphorus (P) as superphosphate (O up to 546 kg P ha^–1) were applied once only, to the soil surface, before sowing lupins (Lupinus angustifolius). The lupins were grown in a continuous arable cropping rotation with, in successive years, oats (Avena sativa), wheat (Triticum aestivum), lupins. Five such rotations were started in the experiment from 1985 to 1989. The experiment continued until the end of 1990.The relationship between lupin seed (grain) yields and the level of P applied was measured in the year of P application for five successive years (1985 to 1989). The relationship had the same general form but it varied between years, largely due to different maximum yields (yield plateaux) in each year.The residual value of superphosphate applied three years previously was measured for lupins on two occasions (1988 and 1989) relative to superphosphate applied in the current year. The residual values was different in the two years. The superphosphate applied three years previously was about 30% as effective as freshly applied superphosphate in 1988, and 12% as effective in 1989.At each harvest, the relationship between grain yield and the P concentration in the grain differed for different species. However, for each species at each harvest, the relationship was similar regardless of when the P was applied in the previous years. Thus each species had the same internal efficiency of P use curve, and yields varied only with P concentration in tissue.Bicarbonate-extractable soil P was determined on soil samples taken in mid-July of 1989 and 1990. These soil test values were related to grain yields at harvest. The relationship between yield and soil test values had the same general form but varied for different species within years and for each species between years. It also varied for each species within years depending on the year the P was applied.     

Superplastic behaviour of Ti-48at.%Al two-phase titanium aluminide compacts made from mechanically alloyed powder

An HIP compact of MA-processed powder having a nominal composition of Ti-48at.% Al was produced. The compact consisted of a large amount of TiAl(λ) and a small amount of Ti₃Al (₂), in a completely ultra-fine equiaxed grain structure. This two-phase compact showed typical superplastic deformation behaviour. A maximum elongation of 550% was obtained. A strain exponent, n = 2, and grain size exponent, p = 2, were determined from the results of a strain-rate-change test and a creep test at constant initial stress using samples having various grain sizes, respectively. The activation energy for creep, Q_c at constant stress was calculated to be 350 kJ/mole. It is concluded that the superplastic deformation mechanism of the material under study is grain boundary sliding controlled by lattice diffusion in the TiAl phase.     

某含砷浮选金精矿的细菌氧化预处理-氰化提金试验研究

云南省某含砷难浸金精矿，常规氰化金浸出率仅为26．17％，通过采用细菌氧化预处理后，金浸出率达到98．25％，获得了非常理想的试验指标。     

Mechanism for the Peritectic Reaction and Growth of Aligned Grains in YBa2Cu3O6+x

It is experimentally observed that the peritectic reaction, 211 + liquid → 123, can be driven essentially to completion in 1 h at an undercooling of only ∽30°C. The kinetic data, together with the observed microstructures, are inconsistent with the normal mechanism of the peritectic reaction. It is proposed that the mechanism of the reaction involves dissolution of 211 particles into the liquid and precipitation of solid 123. The aligned grain structure is explained through sympathetic nucleation of new 123 grains on existing grains.     

微波热液法制备光催化TiO2功能材料

采用微波加热法，研究了钛配离子热分解水解反应的规律。结果表明，水解产物在大气气氛和300℃下煅烧2h，所得产物为锐钛型TiO2粉末。在紫外线照射下，乙酸经Ti02光催化反应12h后，残余量小于初始量的20％。     

铁水脱硫扒渣是包钢发展的重要环节

脱硫扒渣站的建成,既解放了炼铁厂的高炉,又减轻了炼钢厂转炉冶炼的负担,同时可以实现铁水预脱硫→顶底复吹转炉炼钢→钢水二次精炼→连铸这一炼钢四位一体的现代化生产工艺流程,从而生产有市场竞争力的产品.镁基脱硫剂是世界上冶金企业采用最先进的脱硫剂,脱硫技术和设备也是世界上最先进的.     

超强吸水树脂的吸水性能研究

对自制的超强吸水树脂的吸收性能进行了研究，分别考察了吸水树脂的粒径，溶液的pH值，几种离子如Na^ ,K^ ,Ca^2 ,Mg^2 等的水溶液对吸水树脂吸收性能的影响。实验结果表明，在pH为6－8，树脂粒径为100mesh-120mesh时，树脂的吸水性能最好，各种离子对吸水树脂吸收性能的影响大小顺序为：Na^ ＜K^ ＜Mg^2 ＜Ca^2 。     

SOLUBILISATION OF NITROGENOUS CONSTITUENTS OF BREWERS' SPENT GRAIN

The extraction of nitrogenous material from Brewers' spent grain (BSG) by solvents (water, sodium chloride solution, aqueous alcohol, acidic and alkaline solutions) commonly used to extract cereal proteins, resulted in the relatively low (0·2 to 8·5%) recovery of the total nitrogen. The recovery of nitrogenous material by the use of aqueous alkaline solutions was increased from 3–4% to 41% when the BSG was subjected to cellulase incubation prior to extraction. Approximately 75% of the nitrogen was solubilized with trifluoracetic acid. Detergent solutions (acid, neutral) solubilized more than 80% of the total nitrogen of the BSG. The low solubility of the nitrogenous constituents by conventional protein solvents could be the result of association between cellulosic material and protein.