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81.
在不同反应温度条件下采用原位聚合法在石英基片上制备了聚苯胺薄膜.对薄膜样品进行了紫外光谱、SEM、电性能表征。实验结果表明,过高的合成温度会加速聚合反应过程,抑制膜厚的增长,引起薄膜的热降解,进而对样品的导电性产生不良影响。根据生长速率与合成温度的依赖关系,估算了聚合反应的活化能Ea=34.4kJ/mol。 相似文献
82.
SARS流行预测分析 总被引:3,自引:1,他引:2
表面上突如其来的SARS本质上却有极规律的内在发展演化机制,遵从初始缓慢增长、加速、减速和稳定终止四个阶段总体道路,自然和社会生活领域众多事件演化都符合这一规律,因而可以运用广义的Logistic生长模型进行描述。基于先期流行的广东SARS感染病例数据,以及尚未结束的北京、全国2003年SARS流行统计数据,借助于最优化分析技术,运用广义的Logistic生长模型对该事件演化特征参量进行了辨识;在此基础上,又借助于广义生长模型的特例——Gompertz函数进行了演化过程的预测,并与其他生长模型结果进行了比较。研究表明,生长模型模拟结果均与实际数据有很好的一致性,可以用来预测事件的发生演化过程,此次SARS事件堪称生长模型的经典实例。 相似文献
83.
Creep crack growth rates were measured using centrally cracked tension specimens of thin polypropylene film with different
crack lengths at various stresses and temperatures. The creep crack growth rates were correlated with the stress intensity
factor. There was the region of the minimum constant crack growth rate which occupied more than 70% of the total creep failure
life. This constant creep crack growth rate characteristics were analyzed on the basis of the stress-dependent Arrhenius type
thermally activated process. 相似文献
84.
Shaobing Zhou Qiuxiang Su Xiaohong Li Jie Weng 《Materials Science and Engineering: A》2006,430(1-2):341-345
In the paper, we found a novel method to synthesize dicalcium phosphate dehydrate (DCPD) nanocrystals by in situ reaction in biodegradable PDLLA matrix. Calcium hydrid was selected as calcium source of DCPD, which is different from general methods. The method is not only simple and effective to synthesize Ca–P particles, but also can avoid the aggregation of inorganic nanoparticles in the course of their being dispersed into polymer matrix. 相似文献
85.
Summary We introduce a very simple model for thermally activated atomic migration on a lattice, and several techniques to handle it. For thermodynamical systems, the model can be used for simulating decomposition paths taking into account relevant metallurgical features. Close to equilibrium, the simplest mean-field approximation of the model can be linearized with respect to the departure from equilibrium; one then gets a microscopic interpretation of classical phenomenological coefficients, such as mobility, interfacial transfer coefficient, rate constants for the coupled relaxation of concentration and order fields. Further away from the equilibrium, the nonlinearities can be taken into account in a consistent way. For driven alloys, i.e. alloys submitted to external forcing, forced atomic migration is added to the model and new features emerge: the model is supported by several experimental results some of which confirmed its predictions a posteriori. 相似文献
86.
Andrea Engl Benno Kunz 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):257-261
Studies took place to investigate the effects of different nutrient conditions on the biosorption ability and selectivity of heavy metals by Saccharomyces cerevisiae. After having grown in media supplemented with additional glucose, ammonium, phosphate or cysteine, the yeast was exposed to an equimolar solution of lead, cadmium, zinc and copper. Lead removal from a mixed solution was significantly higher than that of copper, followed by zinc and cadmium. Generally, yeasts from cysteine-rich media showed greatest sorption capacity whereas phosphate addition influenced zinc selectivity. In addition, glucose, fructose and sucrose as carbon sources were examined. Cultures grown in glucose had a better uptake than those cultivated with fructose at an incubation time of 30 min. 相似文献
87.
本文研究了用金属有机物热发解法制备PLT8薄膜的工艺过程和基片对薄膜结构的影响,并且给出了铁电性能的测量结果。 相似文献
88.
通过力学性能评估和金相组织观察,研究五种热处理制度,两个周期的试验结果,确定了K418B合金细晶铸造整体涡轮的真空热处理工艺。 相似文献
89.
Heat-shock induction of heat-shock protein genes is due to a specific promoter element (the heat-shock element, HSE). This study used lacZ under HSE control (HSE-lacZ) to characterize HSE activity in Saccharomyces cerevisiae cells of different physiological states and differing genetic backgrounds. In batch fermentations HSE-lacZ induction by heat shock was maximal in exponential growth, and showed marked decline with the approach to stationary phase. Expression in the absence of heat shock was unaffected by growth phase, indicating that the growth-dependent expression of many yeast heat-shock genes uses promoter elements in addition to the HSE. Heat-induced expression was strongly influenced by the temperature at which cultures were grown. While basal, uninduced expression was constant during growth at different temperatures to 30 degrees C, induction by transfer to 39 degrees C was reduced by increases in growth temperature as low as 18-24 degrees C. Maximal HSE-lacZ induction (30- to 50-fold) was in cultures grown at low temperatures (18-24 degrees C), then heat shocked at 39 degrees C. Ethanol was a poor inducer. Mutations having little effect on HSE-lacZ expression included a respiratory petite; ubi4 (which inactivates the poly-ubiquitin gene); also ubc4 and ubc5 (which each inactivate one of the ubiquitin ligases involved in degradation of aberrant protein). pep4-3 increased both basal and induced beta-galactosidase about two-fold, probably because of slower turnover of this enzyme in pep4-3 strains. 相似文献
90.
06NiCuCrMoNb钢高温加热时表层铜的行为 总被引:2,自引:2,他引:0
将06NiCuCrMoNb钢试样在不同的加热温度保温不同时间后,观察并分析试样表层的形貌和成分。结果表明,在一定条件下铜会扩散进入表层奥氏体晶界,得到沿奥氏体晶界分布的富铜相,并在热变形加工时导致热脆。试验得到了沿奥氏体晶界分布的富铜相与加热温度和保温时间的关系。 相似文献