消除磨齿裂纹的工艺措施

介绍了磨齿裂纹的产生机理，给出了防止磨齿裂纹产生的工艺措施，收到了良好的效果。     

Composite corrosion inhibitors for secondary alkaline zinc anodes

The corrosion inhibition property of PEG600 and In(OH)3 as composite corrosion inhibitors for secondary alkaline zinc electrodes was studied, and the inhibition efficiency was determined as 81.9%. The research focused on the mechanism by the methods of electrochemical impedance spectroscopy, polarization curves and IR spectroscopy. The results indicate that the corrosion inhibition effectiveness is attributed to the joint inhibition of anodic zinc dissolution and cathodic hydrogen evolution. And the anodic process is depressed to a greater extent than the cathodic process. The synergistic mechanism of the composite inhinbitors proves to be the enhancement of adsorption of PEG600 by In(OH)3. Potentiostatic experiment results and SEM images verify the inhibition of dendritic growth by the composite inhibitors.     

Cu—Zn—Al合金逆形状记忆组织的电镜观察

用透射电镜观察了Cu-Zn-Al合金中逆形状记忆的贝氏体组织。在外加约束应力作用下,逆记忆量可以提高一个数量级,贝氏体片侧相界面的抛物线轮廓和贝氏体片交叉曲折的现象说明了贝氏体展宽是扩散控制的切变过程。     

宝钢热轧厂轧辊磨床的技术改造

介绍了宝山钢铁股份有限公司热轧厂对其轧辊磨床进行床身导轨、数控系统、测量系统、中心架、砂轮主轴及动平衡装置、集中控制、在线涡流探伤等方面的技术改造情况。改造后，磨床精度、效率和稳定性明显提高。     

等离子显示器(PDP)用BaMgAl10O17:Eu2+蓝粉的烧结工艺研究

研究了烧结温度、保温时问以及粘结剂对荧光粉二次性能的影响。结果表明，当采用较低烧结温度时，有机粘结剂没有完全分锵是造成荧光粉亮度下降的主导因素，包覆在荧光粉表面的残留部分降低了荧光粉的表面光透率；当烧结温度升高，粘结剂的影响逐渐下降，而过高的烧结温度在导致荧光粉劣化各种因素之间起到了决定性的作用。在此基础上，依据对粘结剂中成膜物质乙基纤维素的降解特性的分析，对浆料烧结工艺进行了优化。结果表明，当浆料加热至480℃，有机粘结剂分解已趋于饱和，从而可以有效降低烧结工序对荧光粉的不利影响。     

钨合金的磨削加工去除机理

目的 解决钨合金磨削加工去除机理不明晰的问题。方法 基于单磨粒刻划有限元仿真、单磨粒刻划和磨削加工实验，探究钨合金的磨削加工去除机理。结果 在刻划过程中，划痕的不同位置材料的去除特性存在显著差异。在单颗粒刻划切入端，材料依次发生了塑性变形、隆起、微裂纹，再到钨相与黏结相的混杂交融。在划痕中段以材料去除为主，出现了材料微卷起和材料卷起现象，沿着刻划方向卷起现象越来越严重。在划痕切出端，划痕边缘和尾部均出现了“飞边”现象，且相较于切入端，切出端的形貌较差，实验与仿真吻合。此外，在不同相位处，材料的去除特性也存在一定不同。在钨相区域，同时存在脆性特征和塑性特征。在黏结相区域，刻划深度较浅时主要呈现塑性变形、塑性流动等特征，刻划中端深度较大时主要呈现与钨相的混杂和交融。在钨相与黏结相的相界处，相邻钨颗粒呈现不同的损伤或去除特征，且相界会阻断特征形貌的传递。最后，磨削后的钨合金表面存在单颗粒刻划痕上出现的所有去除特征，与单颗粒划痕的去除特征吻合。不同的是，磨削后划痕底部出现了区域性和放射状的裂纹。结论 钨合金的两相特性使得磨削表面的去除特征较复杂，存在塑性变形、微裂纹、微卷起、卷起、裂纹和两相交...     

Substitutional diffusion and Kirkendall effect in binary crystalline solids containing discrete vacancy sources and sinks

We investigate vacancy-mediated diffusion in a binary substitutional alloy by explicitly accounting for discrete vacancy sources and sinks. The regions between sources and sinks are treated as binary crystals with a perfect lattice structure containing a dilute concentration of vacancies. The sources and sinks are assumed ideal, maintaining an equilibrium vacancy concentration in their immediate vicinity. Diffusion within the perfect lattice is described with a diffusion-coefficient matrix determined by kinetic Monte Carlo simulations for a binary, thermodynamically ideal alloy in which the components have different vacancy-exchange frequencies. Continuum simulations are performed for diffusion couples with discrete grain boundaries acting as vacancy sources and sinks. Effective grain coarsening due to the Kirkendall effect is observed even in the absence of Gibbs-Thomson driving forces. As in standard ternary systems, uphill diffusion is observed. We also find that the drift of the lattice frame of reference as a result of the Kirkendall effect increases with the source/sink density. Upon increasing the density of vacancy sources and sinks, we recover the conventional treatment of substitutional diffusion, which assumes a dense and uniform distribution of vacancy sources and sinks that maintain an equilibrium vacancy concentration throughout the solid. The inverse Kirkendall effect, where the slower component segregates at grain boundaries acting as vacancy sinks, is also observed in the simulations.     

Mechanical alloying of Mo—Si—Fe powders

Mechanical milling behavior of Mo-Si-Fe powders was investigated u sing XRD, SEM and TEM techniques. The mixtures of elemental molybdenum (>99%), s ilicon (>99%) and iron (>98%) powders with a stoichiometry of Mo5-xFe xSi3 (x=0.5, 1, 2) were milled in a planetary mill for up to 195 h. For all three powder mixt ures, high-energy milling of 60h led to formation of the Mo(Fe, Si) supers aturated solid solution (Moss); and to a remarkable expansion of the solub ility of Fe, Si in molybdenum. The transformation of Moss to an amorphous phase was identified after longer time milling. In the milling process, the grain size of Mo (Fe, Si) decreased gradually and the internal stress increased linearly. After 40 h milling, the grain size was reduced to about 11 nm. SEM analysis of milled powders showed that the particle size increased initially with milling time. After 195 h milling, particles exhibited a spherical morphology and the particle size were reduced to about 100 nm.     

电场作用对提高微生物浸矿性能的影响

在排土场微生物强化浸出过程中,结合电场生物工程技术,以氧化亚铁硫杆菌为研究对象,提出利用电场作用提高微生物浸矿性能的方法,探讨电场作用对微生物生长代谢以及渗流特性的影响。结果表明：电场作用对氧化亚铁硫杆菌生长代谢的影响非常明显,适当的电场可有效强化其生长代谢能力,过高的电流会抑制氧化亚铁硫杆菌生长;电场作用下,排土场孔隙中微生物的渗流能力明显增强,微生物电动渗流效应在渗透率高排土场中尤为明显。     

Effects of secondary carbide precipitation and transformation on abrasion resistance of the 16Cr-1Mo-1Cu white iron

The relationship between secondary carbide precipitation and transformation of the 16Cr-1Mo-1Cu white iron and abrasion resistance were investigated. The results show that secondary carbide precipitation and transformation at holding stage play an important role in the hardness and abrasion resistance. After being held for a certain time at 853 K for subcritical treatment, the grainy secondary carbide, (Fe,Cr)₂₃C₆, precipitated first and then Fe₂MoC or MoC carbides precipitated in the alloy, both of which improve the bulk hardness and abrasion resistance of the alloy. The reasons for these improvements are the secondary carbide precipitates from the austenite and the retained austenite transforms into the martensite, both make the matrix strengthen. So the matrix has more effective support to the harder eutectic carbide against exterior abrasion. With expanding the holding time, the in situ transformation from the granular (Fe,Cr)₂₃C₆ carbide into laminar M₃C carbide causes the formation of the pearlitic matrix and an associated decrease of the alloy abrasion resistance.