WD615曲轴箱清理磨削裂纹的机理初探

WD615曲轴箱在机加工过程中，经常发现在铸件的上下平面出现细小的裂纹，其中一部分主要是在曲轴箱毛坯铸造过程中采用磨床磨削清理时产生的磨削裂纹。作者提出了铸件毛坯磨削裂纹的定义，并引用机加工磨削加工中的磨削烧伤理论进行了分析。     

A Methionine Chemical Shift Based Order Parameter Characterizing Global Protein Dynamics

Coupling of side chain dynamics over long distances is an important component of allostery. Methionine side chains show the largest intrinsic flexibility among methyl-containing residues but the actual degree of conformational averaging depends on the proximity and mobility of neighboring residues. The ¹³C NMR chemical shifts of the methyl groups of methionine residues located at long distances in the same protein show a similar scaling with respect to the values predicted from the static X-ray structure by quantum methods. This results in a good linear correlation between calculated and observed chemical shifts. The slope is protein dependent and ranges from zero for the highly flexible calmodulin to 0.7 for the much more rigid calcineurin catalytic domain. The linear correlation is indicative of a similar level of side-chain conformational averaging over long distances, and the slope of the correlation line can be interpreted as an order parameter of the global side-chain flexibility.     

煤粉炉粉煤灰提取氧化铝活化技术研究进展

介绍了近年来采用煤粉炉粉煤灰作为原料制备氧化铝的预处理活化工艺技术,指出了粉磨法、硫酸法、氯化钙法、铵盐法、碳酸盐法、氟化盐法、物理-化学联合活化法的优缺点及在工程转化过程中需重点关注的环节。虽然部分工艺技术实现了工业化,但因成本高等因素导致项目关停,建议粉煤灰综合利用研究方向应以工程转化难点问题为导向,理论研究与工程设计相结合,逐步探索出一条经济效益好、安全环保的粉煤灰制备氧化铝工业化路线。     

Effect of deposition conditions on the properties and annealing behavior of cold-sprayed copper

The deposition of copper by cold gas dynamic spraying has attracted much interest in recent years due to the capability to deposit low-porosity oxide-free coatings. However, it is generally found that as-deposited copper has a signicantly greater hardness, and potentially lower ductility, than bulk material. In this article, copper was deposited by cold spraying using helium as the driving gas at both 298 and 523 K. Evidence is presented indicating that the material sprayed at the lower temperature exhibits a lower dislocation density throughout the grain structure than the material sprayed at the higher temperature. The low stacking fault energy of copper restricts recovery during annealing, and thus microstructural changes during annealing only proceed once recrystallization begins. The material sprayed at low temperature (with the low dislocation density) exhibited recrystallization at annealing temperatures as low as 373 K with a corresponding reduction in hardness. However, the copper sprayed with helium at 523 K was resistant to annealing at temperatures up to 473 K where the dislocations in the structure prevented recrystallization. However, at higher temperatures, recrystallization did proceed (with corresponding reductions in hardness). The fracture behavior of the copper that was cold sprayed with helium at 523 K, both in the as-sprayed condition and following annealing, was measured and explained in terms of the annealing mechanisms proposed. The original version of this paper was published in the CD ROM Thermal Spray Connects: Explore Its Surfacing Potential, International Thermal Spray Conference, sponsored by DVS, ASM International, and HW International Institute of Welding, Basel, Switzerland, May 2–4, 2005, DVS-Verlag GmbH, Düsseldorf, Germany.     

某含铜尾矿粗砂工艺矿物学特征及选矿试验研究

为查找铜损失在尾矿中的原因并制定选矿回收工艺,对某低品位含铜尾矿粗砂进行了工艺矿物学分析和选矿试验研究。结果表明：含铜矿物主要是黄铜矿（CuFeS2）,嵌布粒度微细且呈浸染状分布,未能充分单体解离而损失在尾矿中。经过选矿优化试验确定粗尾砂可采用立式搅拌磨,使微细粒级铜矿物充分单体解离;然后,采用优先浮选工艺回收铜,闭路试验可获得Cu品位18.02%、Cu回收率41.05%的铜精矿。     

解析参数对活性焦再生过程及再生效果的影响

 活性焦的热解析参数对再生活性焦的脱硫脱硝性能和机械强度至关重要。为了明确解析参数对活性焦再生过程和再生效果的影响规律,通过热解析试验探究活性焦硫残余比例、CO₂和CO生成量及再生活性焦脱硫脱硝性能随解析温度和解析时间的变化规律,继而明确适宜的活性焦热解析参数。结果表明,活性焦升温解析过程中,脱硫产物在317 ℃左右迅速分解,随后分解速率下降;在进入恒温解析阶段后脱硫产物分解速率先快速下降,而后进入缓慢解析状态。硫残余比例随恒温解析温度的升高而下降,在530 ℃下解析3 h可使脱硫产物完全解析;解析温度高于430 ℃后,活性焦表面的酚基、醌基、内酯基等含氧官能团分解量明显增加,并随恒温解析温度的升高而持续增加,分解所生成的CO和CO₂也随之大幅增加,这将使活性焦的孔隙结构进一步发展,继而不利于活性焦机械强度的保持;解析温度低于530 ℃时,硫残余比例随解析温度的升高而持续降低,使再生活性焦的脱硫脱硝性能持续提高;解析温度高于530 ℃后,含氧官能团分解量随解析温度的升高而持续增加,这将有利于提高活性焦表面SO₂氧化反应速率,继而使再生活性焦的脱硫性能持续升高,但酚基、内酯基等酸性含氧官能团的分解使再生活性焦对NH₃的吸附性能降低,进而使其脱硝性能降低。在兼顾再生活性焦脱硫脱硝性能、机械强度和生产效率等多方面因素时,430 ℃恒温解析3 h是相对较优的解析参数。在此解析条件下,再生活性焦的硫残余比例仅为1.8%,含氧官能团尚未发生大量分解,脱硫脱硝性能相对较为优良。     

平板类气体辅助注射成型产品的CAE模拟研究

通过建立具有代表性的平板类气体辅助注射成型产品模型,借助注塑成型CAE软件Moldflow对该模型进行了一系列分析模拟。通过对模拟结果数据的综合分析和数学处理,得到了气体注射参数对气道穿透长度的影响规律、气体注射参数设置及气道穿透长度预测公式。     

硬脆材料专用ELID磨削液的研制

本文在已有新型通用ELID磨削液(HDMY-20型)的基础上，根据硬脆材料的磨削特点和ELID磨削过程中磨削液的电解修锐生膜缓蚀作用、结合通用ELID磨削液的研制经验．通过增添表面活性剂、稳定剂、防锈剂、油性极压剂和调整无机盐等成分的比例关系．优化出适合硬脆材料ELID磨削最佳状态的专用ELID磨削液。应用此磨削液磨削硬质合金表面粗糙度可达Ra0．007μm比通用型磨削液磨削的硬质合金Ra值降低了0．005μm。     

脆硬材料加工机理的研究

为了了解脆硬材料的加工情况，本文采用扫描电镜和高速摄影机对典型的脆硬材料，玻璃的磨削过程，静态，动态地进行了细致的观察和分析，提出了脆理材料的磨削模型，该模型全面地反映出整个加工过程中所发生的现象，对脆硬材料的加工有指导意义。     

高速重负荷磨钢坯砂轮的研制

研制的80m/S高速重负荷磨钢坯砂轮具有强度高,安全可靠,磨削效果好等特点。其磨削效率和磨削比分别为60m/s中速中负荷砂轮的2倍和7倍以上,大大提高了钢坯修磨的质量和产量,并能减轻工人劳动强度,改善劳动条件和环境污染,有利于钢屑回收。