工艺参数对陶瓷注射成型的影响与分析

本研究通过改变注射温度，注射压力，保压压力等几个主要参数，对形状，体积不同的注射成型体，试条，圆柱及子部件进行了一系列注射工艺实验。相应地对成型体的密度，弯曲强度及烧结体的密度和强度进行测量，并从陶瓷注射成型混合物的流动行为，热物理特性方面对注射这一复杂过程进行分析，探讨工艺参数对成型过程的内在影响，从而确定合理的注射工艺条件。     

水泥流动性的测量及其在助磨剂助磨效果评价中的应用

介绍了使用粉体物性测试仪测量、计算粉体流动性指数的方法。用化验室统一试验小磨将不同种类、不同掺入量的助磨剂与熟料共同粉磨,检验水泥的流动性指数。结果表明,流动性指数可以区分不同助磨剂相同掺入量和相同助磨剂不同掺入量水泥的流动性,可以作为水泥助磨剂评价与选择的参考。     

水泥粉磨系统技术措施及技术改造的优化

水泥粉磨系统的每一个环节，如粉磨工艺、选粉机、磨机结构、研磨体级配等都有潜力可挖，均可通过技术改造优化选择使粉磨系统的能力得到充分发挥、实现优质、高产、低消耗。     

提高Φ2.2 m×7.5 m矿渣磨产量和细度的措施

福建三明水泥厂矿渣和熟料易磨性不同,制约了 2.2 m×6.5m闭路水泥磨系统的产质量,导致产量低仅12 t/h;矿渣掺量低,仅7％;水泥强度低R28仅达47.0MPa。为此该厂增加了2台 2.2m×7.5m开流磨单独粉磨矿渣,实现熟料矿渣分别粉磨工艺。同时对 2_2m×6.5m矿渣磨进行结构改造和工艺操作参数调整。这样二套粉磨系统可根据熟料和矿渣的不同粉磨特性分别进行操作控制,工厂实现了高产高质,高矿渣掺量(达15％)和低成本生产。     

辊压机水泥粉磨技术的研究及应用

辊压机料床粉磨技术是一项先进而成熟的粉磨技术;在辊压机的各种粉磨流程中,由V型静态选粉机和辊压机组成的联合粉磨系统尤其具有优质、高产、低消耗等综合优势。CDG辊压机和静态选粉机的运用实践证实了这个结论。     

泥岩隧道光面爆破的技术参数研究及应用

针对泥岩隧道的特殊性,通过优化光面爆破的爆破参数,讨论泥岩隧道掘进的经济性、安全性。采用预埋振速传感器监测的方式,分析光面爆破对隧道周围岩体的扰动。现场光爆技术应用效果显著,隧道开挖轮廓线内基本未出现超欠挖现象,半孔率达86%以上,爆破进尺提升约15%,孔痕长度基本均匀分布一般都在孔长的66%以上;萨道夫斯基公式的系数K衰减明显、α基本稳定,光爆的振动速度和围岩扰动都得到了有效控制。     

Mixed monolayer and mixed micelle formation in binary mixture of surfactants—Systems for trioxyethylenated dodecyl sulfonate and some polyoxyethylenated fatty alcohol ether nonionic surfactants

The interaction and synergism of some polyoxyethylenated fatty alcohol ether (POE) nonionic surfactants (C₁₂E₂, C₁₂E₃, C₁₀E₅, C₁₀E₇, where C_x indicates number of carbon atoms in the chain and E_y indicates number of oxyethylene glycol ethers) with trioxyethylenated dodecyl sulfonate (C₁₂E₃S) in mixed monolayer formation at the surface and in mixed micelle formation in aqueous solutions were studied at 25 and 40°C by calculating interaction parameters (β_α, β_M) from surface tension-concentration data by use of Rosen's equations based on the nonideal solution theory. All the systems investigated adapt reasonably well to the nonideal model, with negative values of β_σ and β_M (where M means micelle and σ refers to the air-liquid interface) indicating a favorable interaction between the mixed surfactants. Either at a monolayer or in a mixed micelle, the attractive interaction becomes stronger when the alkyl chain in the POE surfactant is longer, i.e., when the POE becomes more hydrophobic. The interaction increases in the order C₁₀E₇<C₁₀E₅<C₁₂E₃, C₁₂E₂. For the two C₁₀E _n (n= 5,7)/C₁₂E₃S systems, as temperature increases from 25 to 40°C, the interaction increases in a mixed micelle, but it decreases in a mixed monolayer. Synergism in mixed micelle formation exists for C₁₂E₃S/C₁₀E _n mixtures when X₁ ^M , the mole fraction of POE in a mixed micelle, is ≈0.4–0.8, whereas synergism does not occur in the systems of C₁₂E₃S/C₁₂E _m due to the large difference between CMC₁ and CMC₂, i.e., large |In(C ₁ ^M /C ₂ ^M )| value (where CMC=critical micelle concentration). The degree of synergism in mixed micelle formation is temperature independent and is 0.23, 0.18, and close to zero for C₁₀E₅/C₁₂E₃S, C₁₀E₇/C₁₂E₃S, and C₁₂E _m (m=2,3)/C₁₂E₃S systems, respectively. Synergism in surface tension reduction effectiveness occurs in C₁₂E₃S/C₁₂E₂ and C₁₂E₃S/C₁₂E₃ systems. The mole fractions of POE in the solution phase are 0.302 and 0.333 for the two mixtures at the point of maximum synergism.     

采用高性能搅拌设施生产适应市场的水泥

在欧洲和世界其它地区，CEMⅠ水泥(渡特兰水泥)日益为CEMⅡ水泥(有几个主要组份的渡特兰水泥)和CEMⅢ水泥(高炉矿渣水泥)所替代。为了满足生产具有特定粒径分布的高质量水泥的要求，现广为采用的不同水泥组分的混合粉磨工艺已经被单独粉磨然后再在高性能均化设施中进行均化的工艺所代替。依据情况不同，可以采用连续或间歇式搅拌机。文章描述了不同工艺技术．并介绍了最近的几个实例：     

Molar volume and ultrasonic studies of europium soaps in mixed organic solvents

The ultrasonic velocity and density measurements of europium soaps in a mixture of benzene and methanol (3:2, vol/vol) were used to evaluate various acoustic parameters and molar volume and to determine the critical micelle concentration. The results showed that the ultrasonic velocity, specific acoustic impedance, molar sound velocity, and molar compressibility increase, and intermolecular free length, adiabatic Compressibility, and relative association decrease with increasing concentration and chainlength of the soap. The results were interpreted in terms of soap-solvent interaction.