单长链烷基酸性磷酸酯对锆的萃取和保留

本文研究了在30％TBP-单长链烷基酸性磷酸酯(MLCAP)-煤油-HNO_3和MLCAP-煤油-HNO_3两个体系中,萃取剂浓度、水相中H~+、总NO_3~-、稳定锆和铀的浓度及温度等因素对Zr的萃取行为和酸、碱洗涤后Zr的保留行为的影响。还对萃取反应机制进行了初步探讨。结果表明,在实验条件下,MLCAP与Zr生成组成为2:1的萃合物;当MLCAP存在于30％TBP-煤油中时,会使Zr的萃取明显增加并易产生界面物;在用Na_2CO_3洗涤有机相时,不能将Zr有效洗脱并易产生乳化现象,使溶剂质量变坏和造成分相困难。乳化生成的程度与体系中稳定锆的浓度和MLCAP的存在量有关。     

Mechanical behavior of a single polymer chain in a non-solvent

Mechanical properties of a single polystyrene chain in mixtures of dioxane and methanol were measured with AFM. The effect of the solubility of the surrounding liquid on mechanical behavior of a polymer chain was examined. In good and Θ solvents, the force-extension curves exhibit a freely jointed chain (FJC)-like trend with good reproducibility. In a non-solvent, the profile of force-extension curve was dependent on the extension speed: an FJC-like nature emerged at the lower speed of 200 nm/s while saw-toothed curves were obtained at the higher speed of 2000 nm/s. The shape of saw-toothed curves varied from measurement to measurement. A force relaxation was also observed in the non-solvent under a fixed extension distance after 2000 nm/s extension. The mechanical behavior in non-solvents suggests that inhomogeneous deformation of a PS chain occurs due to reduction of the chain mobility.     

轴角数字转换器在感应同步器测角系统中的应用及误差分析

介绍了跟踪型轴角数字转换器的工作原理,然后对其转换误差进行了分析,给出了系统最大跟踪转速与系统激磁频率、压控振荡器最大输出频率以及输出位置信号字长之间的关系。     

Modeling Continuous Powder Mixing by Means of the Theory of Markov Chains

This article demonstrates the efficiency of the application of the theory of Markov chains as a tool to model and simulate continuous powder mixing to aid in better design of such equipment. Markov chain models allow calculating practically all parameters of the process necessary for its characterization, and in particular those related to particle residence time distribution (RTD). Some numerical examples from the model, which are important for better understanding the process, are also included. It is shown that the main factor defining the efficiency of continuous mixing, through the variance reduction ratio (VRR), is the ratio of the mean residence time and the period of inflows fluctuation, rather than the variance of the RTD. Also, the influence of the dimensions of the mixer outlet on the mean residence time, and in turn on the VRR, is examined as another way of improving the design.     

溶胀动力学方法测定高分子链结构

本文成功地用溶胀动力学方法测定了交联、线型及支化高分子的溶胀特征曲线，并认为可由这种溶动力学探针技术判别高分子链的结构类型及特征，是一个很有特色的研究方法。     

溢出效应和网络贴合度扰动下的二级供应链网络广告投放策略分析

为研究溢出效应和网络贴合度扰动下,二级供应链的网络广告投放策略问题,以强势制造商和两个网络零售商组成的二级供应链为研究对象,考虑产品的网络贴合度和网络广告计费特征,构建基于溢出效应的期望需求模型,通过博弈论方法给出了完全不合作、合作、半合作、战略联盟等4种模式下的均衡解,并对以上4种均衡结果进行比较分析。研究结果表明:无论在何种模式下,制造商批发价格与产品的网络贴合度成反比;固定位网络广告投资额和网络广告投资总额与产品的网络贴合度成正比,固定位网络广告投资额与溢出效应成反比;合作状态下的利润总额通常情况下较低;当产品的网络贴合度超过一定阈值范围时,采用战略联盟使得供应链成员利润最大化。     

绿色建筑供应链运作参考模型研究

本着社会经济持续发展的宗旨,以建立高效和谐、良性循环、少废少污的绿色建筑体系为目标,在绿色制造、建筑供应链和供应链运作参考模型等概念的基础上,提出了绿色建筑供应链运作参考模型,并对其流程即绿色计划、绿色采购、绿色施工、绿色交付和绿色回收等进行了详细的分析。     

自然灾害链及其断链减灾框架构建

基于灾害的链式理论及断链减灾思想,构建了自然灾害孕源断链减灾框架,并提出了减灾措施,对减灾措施的任务要点进行了阐述,从而正确的预测和有效的防治灾害链。     

玻化砖挂贴施工技术

结合工程实例,介绍了玻化砖挂贴施工难点,通过对铺贴的分析论证,得出该工程应采用背栓嵌入式湿贴法作为铺贴方案,并对其施工工艺及工艺要点进行了阐述,工程实践表明该施工技术具有广泛的发展前景且值得推广应用。