Effect of yttrium on the stability of aluminide-yttrium composite coatings in a cyclic high-temperature hot-corrosion environment

A composite coating of aluminide-yttrium has shown excellent corrosion resistance in a cyclic high-temperature hot-corrosion environment. To understand the effect of yttrium on the stability of the composite coating, the specimens were prepared with various coating parameters of Y thickness, sequence of post heat treatment and surface condition before Y-ion plating. Performance of the composite coating was evaluated by isothermal oxidation and cyclic high-temperature hot corrosion. Isothermal-oxidation-test results show that the Y in the composite coating helps to form a thick and dense Al₂O₃ scale which is ductile and resistant to thermal stress. The Y in Al₂O₃ may act as a donor which leads to an increase in concentration of interstitial oxygen and, thus, increases in oxidation rate. The presence of Y₂O₃ and (Y, Al) O-type compounds in grain boundaries of Al₂O₃ and boundaries between the Al₂O₃ and NiAl effectively prohibits the fast diffusion of oxidants (such as O and S) and Al along grain boundaries. Consequently, it may induce slow diffusion through the matrix, and thus the corrosion resistance of the composite coating under cyclic hot corrosion increases substantially.     

Sodium sulfate: Deposition and dissolution of silica

The hot-corrosion process for SiO₂-protected materials involves deposition of Na₂SO₄ and dissolution of the protective SiO₂ scale. Dew points for Na ₂SO₄ deposition are calculated as a function of pressure, sodium content, and sulfur content. Expected dissolution regimes for SiO₂ are calculated as a function of Na₂SO₄ basicity, hence generated by fuels with 0.5% and 0.05% S. Controlled-condition burner-rig tests on quartz verify some of these predicted dissolution regimes. However, the basicity of Na₂SO₄ is not always a simple function of (Na₂O) show that carbon creates basic conditions in Na₂SO₄, which explains the extensive corrosion of SiO₂-protected materials containing carbon, such as SiC.     

热连轧机工作辊热辊形仿真研究

采用差分法建立了轧辊二维瞬态温度场及热辊形的预报模型 ,可用于实际生产的在线热辊形预报 ;利用实际生产参数模拟轧制和空冷过程中的工作辊热辊形 ,计算结果与实测值相符 ;就不同条件下工作辊热变形规律进行了分析 ,对热轧生产的工艺安排、组织和热磨辊具有实际意义     

板坯连铸结晶器Co基合金涂层抗冷热疲劳性能研究

采用HVOF对板坯连铸结晶器窄边CrZrCu板喷涂C0基合金涂层，与电镀Co—Ni镀层进行对比分析。结果表明：450℃下进行冷热疲劳试验，Co基合金涂层经过113次后，涂层还保持完好无损，未出现任何缺陷，而电镀镀层只能承受37．8次；800℃时，Co基合金涂层经过29．4次冷热疲劳后，有3l％的涂层剥落，而电镀层只能承受21．4次。这说明HVOF涂层具有非常高的抗冷热疲劳性能。     

Rapidly solidified hypereutectic Al-Si alloys prepared by powder hot extrusion

Rapidly solidified hypereutectic Al-Si alloys were prepared by powder hot extrusion.By eliminating vacuum degassing procedure.the fabrication routine was simplified.The tensile fracture mechanisms at room temperature and elevated temperature were investigated by SEM fractography.Compared with KS282 casting material,the tensile strength of rapidly solidified Al-Si alloy is greatly improved due to silicon particles refining while its density and coefficient of thermal expansion are lower.than those of KS282.The wear resistance of RS AlSi is better than that of KS282.     

Role of platinum in the Na2SO4-Induced hot corrosion resistance of aluminum duffusion coatings

Electrochemical corrosion measurements have been carried out with Pt-containing and Pt-free Al-diffusion coatings on IN 738 LC in a 90Na₂SO₄+ 10K₂SO₄ (mol%) melt at 1173 K. Pt improves the resistance to basic fluxing while there are no significant differences between both coating types in their resistance to acidic fluxing. The corrosion resistance of the Pt-containing coating is also higher in the passive potential region where protective scales rich in Al₂O₃ are formed. The reason for the different behavior of both coating types appears to be related to the high corrosion resistance of the Pt-rich surface layer of the coating and an increased Al₂O₃ content in the scale of the Pt-containing type.     

高速钢轧辊在热轧窄带钢精轧机组上的应用

为提高轧机作业率，降低轧辊消耗，在热轧窄带钢精轧机组上试用了高速钢轧辊，并对其耐磨性能、抗表面粗糙性能、抗热裂纹和剥落性能进行检测，同时针对高速钢轧辊的特点制定了相关的使用措施。试用表明，换辊次数、换辊时间明显减少。     

Structures of ceramics coatings on steel fabricated by hot-dipping and micro-arc oxidation

Firstly, an aluminum coating was produced metallurgically on mild steel by hot-dipping, then an aluminum oxide coating was formed self-growingly from the aluminum coating by micro-arc oxidation treatment. The structures of the composite coatings were investigated by means of SEM, TEM and XRD. The results show that the composite coating consists of three layers which are Fe-Al alloy, aluminum coating and aluminum oxide orderly outward from the steel substrate. There are amorphous phases, k-Al2O3 and θ-Al2O3 mainly in the aluminum oxide.     

H13钢经不同表面处理后的静态抗铝热熔损性能比较

将经过蒸汽氧化、离子渗氮和渗硼等不同表面处理的H13钢试样浸入铝液进行静态熔损试验，探索并建立了一套熔损评定方法一即用试样质量损失的方法评定熔损情况。对铁铝界面进行了显微观察和能谱分析。结果表明，在相同试验条件下熔损后，铁铝界面组织颜色自深至浅依次为：深色的H13钢基体、深灰色致密金属问化合物层、浅灰色致密金属问化合物层、含游离金属间化合物的铝层以及附着的铝。离子渗氮试样和渗硼试样的热熔质量损失要比氧化试样更少，显示了更好的热熔损抗力。     

四辊热轧机支承辊表面裂纹的修复

本文介绍了用局部不接触法修复轧机支承辊表面裂纹的方法。实践证明,这种方法操作简单、节省金属、效果良好、可在现场进行,而且具有较大的经济效益。