Nanostructured β‐Bi2O3 Fractals on Carbon Fibers for Highly Selective CO2 Electroreduction to Formate

3D Bi₂O₃ fractal nanostructures (f‐Bi₂O₃) are directly self‐assembled on carbon fiber papers (CFP) using a scalable hot‐aerosol synthesis strategy. This approach provides high versatility in modulating the physiochemical properties of the Bi₂O₃ catalyst by a tailorable control of its crystalline size, loading, electron density as well as providing exposed stacking of the nanomaterials on the porous CFP substrate. As a result, when tested for electrochemical CO₂ reduction reactions (CO₂RR), these f‐Bi₂O₃ electrodes demonstrate superior conversion of CO₂ to formate (HCOO^?) with low onset overpotential and a high mass‐specific formate partial current density of ?52.2 mA mg^?1, which is ≈3 times higher than that of the drop‐casted control Bi₂O₃ catalyst (?15.5 mA mg^?1), and a high Faradaic efficiency (FE_HCOO^?) of 87% at an applied potential of ?1.2 V versus reversible hydrogen electrode. The findings reveal that the high exposure of roughened β‐phase Bi₂O₃/Bi edges and the improved electron density of these fractal structures are key contributors in attainment of high CO₂RR activity.     

A Multifunctional Blue‐Emitting Material Designed via Tuning Distribution of Hybridized Excited‐State for High‐Performance Blue and Host‐Sensitized OLEDs

Actualizing full singlet exciton yield via a reverse intersystem crossing from the high‐lying triplet state to singlet state, namely, “hot exciton” mechanism, holds great potential for high‐performance fluorescent organic light‐emitting diodes (OLEDs). However, incorporating comprehensive insights into the mechanism and effective molecular design strategies still remains challenging. Herein, three blue emitters (CNNPI, 2TriPE‐CNNPI, and 2CzPh‐CNNPI) with a distinct local excited (LE) state and charge‐transfer (CT) state distributions in excited states are designed and synthesized. They show prominent hybridized local and charge‐transfer (HLCT) states and aggregation‐induced emission enhancement properties. The “hot exciton” mechanism based on these emitters reveals that a balanced LE/CT distribution can simultaneously boost photoluminescence efficiency and exciton utilization. In particular, a nearly 100% exciton utilization is achieved in the electroluminescence (EL) process of 2CzPh‐CNNPI. Moreover, employing 2CzPh‐CNNPI as the emitter, emissive dopant, and sensitizing host, respectively, the EL performances of the corresponding nondoped pure‐blue, doped deep‐blue, and HLCT‐sensitized fluorescent OLEDs are among the most efficient OLEDs with a “hot exciton” mechanism to date. These results could shed light on the design principles for “hot exciton” materials and inspire the development of next‐generation high‐performance OLEDs.     

HACMP技术在数字图书馆中的应用

本文介绍了HACMP双机热备技术的工作原理及相关术语,并通过实例将HACMP技术应用于数字图书馆核心业务平台,对数字图书馆关键性系统建设具有一定的现实指导意义。     

高可靠性P-LDMOS研究

分析了沟道高电场分布产生原因及各个参数对高电场的影响,提出了两条沟道设计的原则——拉长沟道同时降低沟道浓度.模拟结果显示,两条原则能够有效地降低沟道两端的两个峰值电场,从而缓解沟道热载流子效应,提高P-LDMOS的可靠性.     

The Role of Higher Lying Electronic States in Charge Photogeneration in Organic Solar Cells

The role of excess photon energy on charge generation efficiency in bulk heterojunction solar cells is still an open issue for the organic photovoltaic community. Here, the spectral dependence of the internal quantum efficiency (IQE) for a poly[2,6‐(4,4‐bis‐(2‐ethylhexyl)‐4H‐cyclopenta[2,1‐b;3,4‐b]­dithiophene)‐alt‐4,7‐(2,1,3‐benzothiadiazole)]:6,6‐phenyl‐C₆₁‐butyric acid methyl ester (PCPDTBT:PC60BM)‐based solar cell is derived combining accurate optoelectronic characterization and comprehensive optical modeling. This joint approach is shown to be essential to get reliable values of the IQE. Photons with energy higher than the bandgap of the donor material can effectively contribute to enhance the IQE of the solar cell. This holds true independently of the device architecture, reflecting an intrinsic property of the active material. Moreover, the nanomorphology of the bulk heterojunction plays a crucial role in determining the IQE spectral dependence: the coarser and more crystalline, the lesser the gain in IQE upon high energy excitation.     

Mesostructured Arrays of Nanometer‐spaced Gold Nanoparticles for Ultrahigh Number Density of SERS Hot Spots

A novel one‐trough synthesis via an air‐water interface is demonstrated to provide hexagonally packed arrays of densely spaced metallic nanoparticles (NPs). In the synthesis, a mesostructured polyoxometalate (POM)‐silicatropic template (PSS) is first self‐assembled at the air‐water interface; upon UV irradiation, anion exchange cycles enable the free‐floating PSS film to continuously uptake gold precursors from the solution subphase for diffusion‐controlled and POM‐site‐directed photoreduction inside the silica channels. NPs ≈ 2 nm can hence be homogeneously formed inside the silica‐surfactant channels until saturation. As revealed via X‐ray diffraction, small‐angle X‐ray scattering (SAXS), grazing incidence SAXS, and transmission electron microscopy, the Au NPs directed by the PSS template are arrayed into a 2D hexagonal lattice with inter‐channel spacing of 3.2 nm and a mean along‐channel NP spacing of 2.8 nm. This corresponds to an ultra‐high number density (≈10¹⁹ NPs cm^?3) of narrowly spaced Au NPs in the Au‐NP@PSS composite, leading to 3D densely deployed hot‐spots along and across the mesostructured POM‐silica channels for surface‐enhanced Raman scattering (SERS). Consequently, the Au‐NP@PSS composite exhibits prominent SERS with 4‐mercaptobenzoic acid (4‐MBA) adsorbed onto Au NPs. The best 4‐MBA detection limit is 5 nm , with corresponding SERS enhancement factors above 10⁸.     

无线传感器网络自适应区域路由算法

2009年8月,随着‘感知中国’的提出,国内众多学者对无线传感器网络开展了日益深入的研究,而节省网络能耗则是研究的首要问题。主要针对延长传感器网络生存时间、增强网络的可靠性的目标,提出一种自适应区域路由算法（ARRA）,它包括对WSN进行区域规划、区域自治以及区域负载均衡三个方面。分析和仿真同时表明,ARRA实现了传感器网络的能量均衡,降低了网络能耗,并能提升某些热点区域的生存周期和可靠性。     

新型槽栅MOSFETs的特性

采用SIVALCO软件对槽栅与平面器件进行了仿真对比分析,结果表明槽栅器件能够有效地抑制短沟道及热载流子效应,而拐角效应是槽栅器件优于平面器件特性更加稳定的原因.对自对准工艺下成功投片所得沟道长度为140nm的槽栅器件进行测量,结果有力地证明了槽栅器件较平面器件的优越性.     

TEA CO2激光器11μm波段谱线特性研究

采用双光栅谐振腔和增长放电增益区的方法,进行了TEA CO2 激光器11μm波段谱线输出特性研究。在混合气体的比例为CO2 ∶N2 ∶He = 70∶90∶270和总压430 ×133. 3Pa情况下,获得数条谱线的激光输出。着重研究了波长为11013nm 的激光谱线的输出特性,其脉宽为400ns左右,且脉宽随电压变化。谱线能量随光栅中心的位移而变化,当光栅中心在放电区中心轴线上时有最大的能量输出。光斑能量分布接近低阶模或基模分布。     

气流式加速度传感器的敏感机理

介绍了在研制气流式加速度传感器过程中，为对气流式加速度传感器进行建模，作者对气流式加速度传感器的工作机理进行了理论性探讨。在分析过程中以流体力学、传热学和惯性理论为基础并结合实验结果，建立了适合于气流式加速度传感器的气体运动方程和能量方程。同时还讨论了热线测量加速度的方法及根据实验分析了输入加速度对腔体内温度及传感器输出电压的影响，从而为进一步研究一系列气流式传感器的工作机理提供了方法。