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121.
用己二酸二酰肼(ADH)对透明质酸(HA)进行化学修饰,制备交联透明质酸(HA-ADH)薄膜。粘度法测试表明HA-ADH是一种可降解的生物材料,并且与HA相比,HA.ADH的降解速率减慢。在此基础上,研究了以疏水性的替硝唑(TDZ)和亲水性的头孢唑啉钠(CEZ)为模拟药物的HA-ADH药物载体薄膜的释药性能。紫外-可见(UV-Vis)吸收光谱检测表明,HA-ADH是一种疏水性药物TDZ的优良缓释制荆,这是由于TDZ的疏水性和HA-ADH薄膜的缓慢溶胀和降解性能的结合而得到的,药物的释放主要受扩散机制控制。 相似文献
122.
A lubrication-flow model for a free film in a corner is presented. The model, written in the hyperbolic coordinate system
ξ = x
2 −y
2, η = 2xy, applies to films that are thin in the η-direction. The lubrication approximation yields two coupled evolution equations
for the film thickness and the velocity field which, to lowest order, describes plug flow in the hyperbolic coordinates. A
free film in a corner evolving under surface tension and gravity is investigated. The rate of thinning of a free film is compared
to that of a film evolving over a solid substrate. Viscous shear and normal stresses are both captured in the model and are
computed for the entire flow domain. It is shown that normal stress dominates over shear stress in the far field, while shear
stress dominates close to the corner.
This revised version was published online in October 2005 with corrected page numbers. 相似文献
123.
This study is concerned with the stability of a two-dimensional incompressible conducting liquid film surrounded by a passive
conducting medium, when an electric field is applied in a direction parallel to the initially flat bounding fluid interfaces.
Currents generate charges at the bounding interfaces which in turn affect the stress balances there. In the absence of an
electric field, the viscous liquid film is stable (instability can be induced by the inclusion of van der Waals forces for
ultra thin films). A complete model is presented, at arbitrary Reynolds number, which accounts for conductivity and permittivity
contrasts between the fluid and surrounding medium, as well as surface tension. The linear stability of the system is considered
for arbitrary Reynolds numbers and it is shown that the stable film can become unstable if, (i) σ
R
ɛ
p
>1, or (ii) σ
R
ɛ
p
<1 and (σ
R
−1)(1−ɛ
p
)<0, where σ
R
is the ratio of outer to inner conductivity and ε
p
is the ratio of inner to outer permittivity. Instability is possible only if the electric field is non-zero and the scalings
near bifurcation points that can be used to construct nonlinear theories are calculated. Several asymptotic limits are also
considered including zero Reynolds numbers and short or long waves. The instability criteria given above are constructed explicitly
in the case of Stokes flow. 相似文献
124.
The dynamics of a thin liquid film falling down a uniformly heated wall is studied. The model introduced by Kalliadasis et al. [J. Fluid Mech. 475 (2003) 377] for the same problem is revisited and its deficiencies, namely the prediction of a critical
Reynolds number with 20% error, cured. For the energy equation a high-order Galerkin projection in terms of polynomial test
functions is developed. It is shown that not only does this more refined formulation correct the critical Reynolds number,
but it also gives, with an appropriate expansion close to criticality, the long-wave theory. Bifurcation diagrams for permanent
solitary waves are constructed and compared with the solution branches obtained from different models. It is shown that, in
all cases, the long-wave theory exhibits limit points and branch multiplicity, while the other models predict the continuing
existence of solitary waves. Time-dependent computations show that the free surface and interfacial temperature approach a
train of coherent structures that resemble the infinite-domain stationary solitary pulses. 相似文献
125.
Preparation of Plate Fe_(60)Co_8Zr_(10)Mo_5W_2B_(15) Bulk Amorphous Alloy and Its Fracture Toughness
肖华星 《武汉理工大学学报(材料科学英文版)》2005,20(2)
1Introduction Duwez[1]synthesizedthefoilAu Siamorphousalloyforthefirsttimewithrapidsolidification,whichinitiatedthepreparationofamorphousalloysintheprocessofalloysolidification,andthereaftertheresearchonamorphousal loysdevelopedrapidly.Since1980s,withthec… 相似文献
126.
The switchable optical properties of Pd-protected RCo2-type Ho0.6Mm0.4Co2 alloy thin films have been investigated in a KOH electrolyte. The reversible optical switching has been carried out simultaneously by measuring transmitted light through the thin film during electrochemical charging–discharging of hydrogen. The dependence of switching speed and cyclic durability of the film on the charging and discharging current density as well as concentration of KOH electrolyte has been studied. In addition, cyclic voltammetric measurements have been performed to examine the hydride formation and decomposition reactions. 相似文献
127.
李彩虹 《南京工业职业技术学院学报》2008,8(2):1-3
根据PET薄膜的特点和高分子熔融态流动理论,分析了挤出回收用螺杆的各段结构,及螺杆参数选择,设计出大长径比、深槽、双排气、高效专用螺杆。 相似文献
128.
129.
The breakdown processes of oil films under quasi-static loading have been investigated by using a newly developed steel-oil-mercury system. The relationship between the thickness and breakdown ratio of a hexadecane film is represented by a single master curve independently of the indentation speed, indentation load, and temperature. The master curve shows that the breakdown process of hexadecane includes two stages; one is the decrement of the thickness without breakdown and the other is the decrement of the thickness with a drastic progress of breakdown. By solving a small amount of fatty acid in hexadecane, the thickness increases and the breakdown ratio decreases noticeably; a multilayer residual film supporting normal load is formed between two metal surfaces. Experiments at different temperatures reveal a negative relationship between the temperature and thickness of residual film, which indicates that the residual film is organized by physical interaction rather than chemical interaction. At least under a lower concentration, the residual film appears to consist of not only fatty acid molecules but also hexadecane molecules. 相似文献
130.
Preparation and Properties of Rare Earth Modified Carbon Black/Natural Rubber Composites 总被引:2,自引:2,他引:0
Lin Yaling Xiao Kongqing Zhang Anqiang Wang Lianshi 《中国稀土学报(英文版)》2005,23(6):720-720
The oxides Eu, Ho, Er and Dy were used to prepare the hydroxides of rare earth modified carbon black. Then natural rubber latex (NRL) was added into the reactor. The system reacted at 85 ℃ with stirring for 1 h to prepare powdered HAF-Ln(OH)3/NR composites. The effects of the kind and content of Ln on the particle size distribution of P [ NR/HAF-Ln (OH)3 ] and mechanical properties of its vulcanizate were studied respectively. It is found that rare earth can help to get the powder of the composite, the product particle with a diameter less than 0.9mm will be get when the composites containing the compound of Ho, Er and Dy with dosage of 1.0, 1.0, O. 5 percent, respectively. The adding of Ln can improve the tensile strength and tear strength of the vulcanizate effectively, what's more, Er and Dy can decrease the permanent set of vulcanizate significantly. The SEM studies shows that P[ NR/HAF-Dy (OH)3 ] vulcanizate shows superior mechanical properties that depend primarily on the absence of free carbon black, the fine dispersion of carbon black in the rubber matrix and better polymer-filler interaction. 相似文献