A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

叠后地震剖面的线性化波阻抗反演

本文提出了由井旁道出发逐道进行的叠后地震剖面的线性化波阻抗反演方法。每一道反演采用逐次线性化对波阻抗进行修正，反演的纵向分辨率为一个采样时间间隔，并以合成记录道与实际地震道的相似系数作为迭代收敛准则，已处理的地震道波阻抗作为下一道反演初始值。实际资料处理表明，该方法具有较高的分辨率和运算速度快的优点。     

一种基于稳健匹配准则的视频文本跟踪方法

本文首先根据文本中各个字符的颜色相似的特性,确定已知文本块的文本的颜色,利用文本的颜色信息二值化文本图像以得到文本块中的字符数、字符的尺寸和间距;其次,根据视频图像的大小和视频的播放速度确定搜索窗口的大小,并利用文本的运动信息来预测搜索窗口的位置;第三,根据在相邻两帧中具有相同内容文本的颜色相似的特性,提出了一个可以解决脉冲噪声和部分缺损或遮挡问题的稳健匹配准则来跟踪文本块;最后,确定跟踪输出的文本的颜色、尺寸和运动方式。本文方法可以很好地跟踪平移、缩小或放大、旋转、淡入淡出和部分被遮挡的水平或倾斜排列的文本,并且可以记录文本平移、旋转和缩放的速度。     

Construction of a control system for disturbance rejection using a dual observer

A well‐known control system which can reduce the adverse effects of disturbances is a disturbance observer. However, in many cases of mechanical systems, system disturbances which do not satisfy the matching condition may be imposed. Therefore, it may be difficult to reduce the adverse effects of the disturbances by the traditional disturbance observer. In this paper, a method of control system synthesis for disturbance rejection using a dual observer is proposed. This method is based on the zeroing induced by the disturbance localization problem. This problem may be solved by dividing the state space into observable subspace and unobservable subspace. As compared with an H_∞ controller based on perfect observation, the usefulness of the proposed control system for disturbance rejection is demonstrated by numerical simulations for a two‐mass spring system. © 2002 Scripta Technica, Electr Eng Jpn, 138(4): 50–60, 2002; DOI 10.1002/eej.1138     

串扰耦合的低频分析有效性及阻抗特性研究

从传输线模型出发，分析了二平行直导线间串扰的低频模型有效性，得出允许3dB误差的条件下，低频模型在工程计算串扰中的电学短线和频率足够小的具体限值；同时分析了端接阻抗大小对串扰耦合的影响。对电磁兼容性中的串扰耦合的工程应用有实际指导和参考意义。     

低压宽温高频铝电解电容器工作电解液

在传统的己二酸铵/乙二醇加水体系中,通过增加水的含量实现高电导率,同时在电解液中添加多种有机高分子物质形成复合添加剂,改善工作电解液的高温稳定性,使电容器上限工作温度扩展到105℃,形成高频宽温低阻抗工作电解液。     

非晶软磁合金的巨磁阻抗效应及应用

近来在ＦｅＣｏＳｉＢ等Ｃｏ基非晶体丝带中现了巨磁阻抗效应，由于在一小的直流纵向偏置场下该效应能使丝带两端的交流电压发生大而灵敏的变化，因而在磁记录头和传顺技术中具有巨大的应用科学潜能，受到各国学者的关注，本文简单介绍了巨磁阻抗效应的来源，并综述了近年来非晶体软磁合金材料的的巨磁阻抗效应及应用的研究进展，文章最后说明了尚待深入解决的问题。     

Electrochemical impedance spectroscopy of a free-standing oxide film

The corrosion of low carbon steel in natural sea-water is characterized by the formation and growth of compact and thick layers composed of oxides, insoluble salts and organic materials. These layers are the result of corrosion processes induced by local environmental conditions, water oxygen supply; ionic species; bacteria and organic matter. The exchange of various species (ions, molecules, gas) between sea-water and the rust layers or the metal depends both on the kinetics of the Faradaic reactions of the entities with either the oxides or the metal, as well as on their transport properties through the different strata of the rust layers. In this work, an impedance study was carried out using the 4-electrodes cell arrangement with corrosion products picked up on steel sheet piling immersed for 25 years and analyzed as free standing membranes. This new approach is a good way to reach the specific transport and transfer properties of the oxide without being blurred by the metal influence. The physical model developed in this work was based on a transmission line, and accurately described the experimental diagrams. The electronic resistivity of the oxide layer, its porosity, the mean pore size and the reaction kinetics parameters could be determined from the fittings.     

稀疏脉冲反演技术在井间地震反演中的应用

将传统的波阻抗反演技术应用于井间地震资料反演时，存在着方法适用的域和资料的域不同，井间地震资料的频带比地震资料的频带宽以及频率比地震资料频率高，多对井间地震资料拼接等问题。为此，在胜利油田K71井区，探讨了利用传统波阻抗反演技术（稀疏脉冲反演）进行井间地震资料波阻抗反演的一些技术问题，并用利11对井间地震资料进行了波阻抗反演，获得了较好的反演结果，在井间地震资料反演中，采用匹配滤波方的井间地震资料转换到时间域；利用高分辨率地面三维地震资料，采用统计方法提取反演子波，子波的波形和相位较稳定，频带宽；对测井资料进行标准化处理，在反演的波阻抗剖面上砂体的空间展布形态清晰，对储层的描述更精细；利用时深转换模型，将时间域的波阻抗剖面转换到深度域，直接与测井资料进行对比分析，对储层的描述更直观可靠。     

一维波动方程反演波阻抗的实现及效果

利用波动方程反演波阻抗，由于计算工作量大、稳定性差等原因，一直没有在地震勘探资料处理中得到实际应用。本文提出的一维波方程逐段折叠反演方法能较好地克服上述缺陷，具有计算量相对较小、精度高、稳定性好等特点。并在大庆长垣东部和西部的实际资料处理中见到了良好的效果。