通过室内实验及同位素测井技术评价高分子聚合物驱油效果

2500万超高分聚合物室内驱油实验研究了聚合物分子量、浓度、粘度、聚用量、段塞组合等各项性能指标对驱油效果的影响。本文根据室内实验结果,在北一区断西注聚后期开展矿场试验,取得了较好的开发效果。试验前后对比,注入粘度明显增大,月含水上升速度得到有效控制,吸入剖面有了新的动用,有63.1%的油井出现了明显的二次受效特征,取得了显著的经济效益。同时对驱油效果进行系统分析。驱油效果表明:应用2500万超高分聚合物是进一步提高聚驱采收率的有效途径。     

Corrosion protection of iron by polypyrrole coatings electrosynthesised from a surfactant solution

This work is a study of the electropolymerisation of pyrrole onto iron electrodes in the presence of sodium bis(2-ethylhexyl) sulfosuccinate in a wide pH interval. The characterisation of the films was done using electrochemical techniques, SEM/EDX and IR spectroscopy. We show that it is possible to synthesise homogeneous, adherent and very compact films in the pH range between 7 and 12 under potentiodynamic, galvanostatic and potentiostatic conditions without substrate dissolution. The effects of various parameters on electrodeposition were investigated. The new procedure for the electrochemical synthesis of polypyrrole results in improved anticorrosion properties. The inhibition is proposed to be due to the sum of a repulsion of chloride ions because AOT remains entrapped in the polymer matrix and the presence of the iron oxide. Advantages of the use of surfactants in the electropolymerisation solution are discussed.     

Effect of cationic surfactant and inorganic anions on the electrochemical behavior of carbon steel in formation water

Corrosion behavior of carbon steel in formation water associated crude oil from Egyptian western desert was studied at various concentrations of dodecyl dimethyl ammonium chloride (CS) as a cationic surfactant. Polarization curves indicate that CS has a good inhibition efficiency for carbon steel in formation water and behaves as cathodic inhibitor. The inhibition efficiency was found to increase with increase in CS concentration until reaches a maximum constant value corresponding to the critical micelle concentration of CS and decrease with increase in solution temperature. The adsorption of CS follows the kinetic thermodynamic model and Flory-Huggins isotherm. Thermodynamic parameters obtained indicate that that the presence of the CS increases the activation energy. Polarization and Impedance measurements indicate that the addition of KI has a significant synergistic effect with CS and results in increase the inhibition efficiency of CS in formation water.     

连续蒸煮器内洗涤结合器外扩散洗涤的应用

连续蒸煮器内洗涤结合器外扩散洗涤，具有洗涤时间长、洗涤效率高、提取黑液浓度高、浆层厚度均匀、浆层结构组织和浓度一致等特点，运行可靠，易于自动化控制，实现了洗涤用水的封闭循环。     

Investigation of texture effect on visual colour difference evaluation

The texture effect on visual colour difference evaluation was investigated in this study. Five colour centers were selected and textured colour pairs were generated using scanned textile woven fabrics and colour‐mapping technique. The textured and solid colour pairs were then displayed on a characterized cathode ray tube (CRT) monitor for colour difference evaluation. The colour difference values for the pairs with texture patterns are equal to 5.0 CIELAB units in lightness direction. The texture level was represented by the half‐width of histogram, which is called texture strength in this study. High correlation was found between texture strength and visual colour difference for textured colour pairs, which indicates that an increasing of 10 units of texture strength in luminance would cause a decreasing of 0.25 units visual difference for the five colour centers. The ratio of visual difference between textured and solid colour pairs also indicates a high parametric effect of texture. © 2005 Wiley Periodicals, Inc. Col Res Appl, 30, 341–347, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.     

阳离子化多元醇防塌剂的研制

室内研究和现场应用表明,聚乙烯醇类防塌剂表现出较明显的增粘负效应,可引起钻井液粘度的急剧增加,严重影响其推广应用.通过金属盐催化降解和阳离子化反应,研制出了抑制性好且增粘负效应低的阳离子化改性多元醇防塌剂.考察了阳离子化试剂、反应温度、反应时间对取代度、反应效率和产品主要性能的影响,得出了阳离子化多元醇防塌剂最佳制备条件,即：PVA与阳离子化试剂物质的量比为1：1,反应温度为50℃,反应时间为4 h,阳离子度可达0.435.     

井下伴热电缆导体集肤效应的有限元法分析

运用有限元法, 对交频井下伴热电缆导体内部的集肤效应现象进行了数值模拟和分析,比较直观地得出交频电缆中电流密度的分布特性, 以及交流电的不同频率对导体集肤深度的影响。在集肤效应作用下, 电缆导体内部的有效过流面积减小, 交流阻抗显著加大, 其发热量也很大,井下电缆伴热加热技术就是利用这一原理来加热原油的。通过数值模拟, 可以定量地说明电参数对加热效果的影响, 为稠油井井下电缆伴热技术中优化加热参数提供指导。     

Tunnel stability and arching effects during tunneling in soft clayey soil

A series of centrifuge model tests and numerical simulations of these tests were carried out to investigate the surface settlement troughs, excess pore water pressure generation, tunnel stability and arching effects that develop during tunneling in soft clayey soil. The two methods were found to provide consistent results of the surface settlement troughs, excess pore water generation, and the overload factors at collapse for both single and parallel tunneling. The arching ratio describes the evolution of the arching effects on the soil mass surrounding tunnels and can be derived from the numerical analysis. The boundaries of the arching zones for both single tunneling and parallel tunneling were determined. In addition, the boundaries of the positive and negative arching zones were also proposed.     

锡矿山重复水利用的措施及效果

本介绍了锡矿山前闪星锑业有限责任公司如何加强对关键耗水工序的管理及提高重复水利用率的措施，并对所取得的效果进行了阐述，可供用水大户如何节水以借鉴。     

The temperature dependence of luminescence from a long-lasting phosphor exposed to ionizing radiation

The temperature dependence of luminescence from a long-lasting phosphor (LLP), SrAl₂O₄ : Eu²⁺,Dy³⁺, exposed to ionizing radiation has been measured to understand the LLP luminescence mechanism. Evaluation of the decay constants of the LLP exposed to -, β- or γ-rays at temperatures from 200 to 390 K showed that the decay constant is divided into four components ranging from 10⁻⁴ to 10⁻¹ s⁻¹ with activation energies of 0.02–0.35 eV.

Total luminous intensity from the LLP with changing irradiation temperature has its maximum value around the room temperature. Irradiation at elevated temperature (390 K) has the total luminescence pattern with monotonous decrease as temperature rises. As a result of evaluating the temperature dependence of luminescence, the luminescence mechanism is considered as follows:

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