层次式级联多网络模型及其性能

本文提出了一种层次式级联多网络结构，论述了其训练算法，并验证了该结构的收敛性。这种结构在处理高阶非线性分布数据的分类问题方面具有优良的性能，用北京谱仪事例过滤进行性能测试结果表明，其训练和泛化性能都优于单个ＢＰ网络。     

Electrochemical,FTIR and morphological study of polypyrrole—Polystyrenesulphonate conducting films

The electrochemical behaviour, FTIR spectrum and the morphology of polypyrrole-polystyrenesulphonate (PPy-PSS) films obtained potentiostatically at 0.6 V in a 0.05m Py + 1.7 × 10^?2m NaPSS medium have been analysed. Different electrochemical parameters have been modified in order to establish the first polaron formation, the reversibility of the redox process and the doping mechanism. The FTIR spectrum confirms the existence of C?O groups in the film structure and two possible explanations are suggested. SEM reveals a higher homogeneity in these films than in PPy films doped with smaller counterions.     

Carbon fibre composites based on polyimide/silica ceramers: aspects of structure-properties relationship

Polyimide/silica ceramers, based on the products of the hydrolysis of tetraethoxysilane (TEOS) and a commercial poly(amic acid) solution, were used to fabricate unidirectional carbon fibre composites, which were subsequently evaluated with respect to thermal and mechanical properties. There is evidence to suggest that the silica component of these ceramers is present as dispersed discrete particles at low silica concentration (i.e. 7 wt%) and as fine interconnected domains trapped within the polyimide matrix at higher silica content (i.e. 14 wt%). The dimensions of the silica domains were in the region of 7–20 nm. Carbon fibre composites produced from ceramer solutions (CF/ceramers) were found to exhibit lower thermal expansion and a greater retention of flexural and interlaminar shear properties at elevated temperature than the corresponding polyimide-matrix composites (CF/polyimide). The properties of CF/ceramers were generally better for systems containing the higher amount of silica and were improved further by lowering the pH value of the precursor ceramer solution. This is believed to have resulted from the enhanced fluidity of the ceramer gel within the pre-impregnated fibres, giving rise to a higher packing density of the fibres and a more homogeneous distribution of fibres. CF/ceramers were also found to exhibit a better thermal oxidative stability at 350°C than the corresponding CF/polyimide, although a substantial amount of porosity developed in the case of ceramers with the higher silica content.     

冗余技术在维持DCS系统稳定运行中的作用

以浙江中控JX300-XP为例,介绍冗余系统在系统长周期运行中的关键作用。     

Analysis of oceanaut operating performance using an integrated Bayesian network aided by the fuzzy logic theory

Because the oceanaut plays a significant role in safety and capability during manned deep-diving scientific tasks, preventing oceanaut performance decline is of paramount importance. However, the factors responsible for oceanaut performance are almost entirely unexplored. To address the preceding issues, a quantitative method of fuzzy integrated Bayesian network (FIBN) was modeled within the limits of oceanaut operating procedures. To quantify the probabilities of the influencing factors, the probability of each node in the FIBN was calculated using integrated expert judgement, fuzzy logic theory, and Bayesian network. By considering a total of 28 factors related to oceanaut performance in the “Jiaolong” manned submersible, this study found that difficult sampling, long sampling times, cabin equipment failure, oceanaut physical decline, and declining decision-making ability are important factors that affect oceanaut performance. The FIBN proposed in our study fused the qualitative and quantitative methods and can be developed into a versatile tool for analysis of comprehensive systems that contain both static and dynamic factors.Relevance to industryThe results provide a powerful basis for the design of manned submersible and assignment of tasks to oceanauts, while the fuzzy integrated Bayesian network (FIBN) method proposed can be effectively applied to various quantitative assessment fields which direct researchers to deal with analysis problems of complex systems.     

Authority updating: An expert authority evaluation algorithm considering post‐evaluation and power indices in social networks

In group assessment, the focus is on finding high‐authority experts to improve the reliability of assessment results. In this study, we propose an authority updating algorithm while considering the power and judgement reliability of an expert on the basis of social networks and post‐evaluations. A network power index is established and used to reflect the power of an expert while considering social networks. The measurement of the judgement reliability of an expert considers the post‐evaluation of the objects selected by experts, thereby more scientifically reflecting the reliability of experts. The analysis shows the following: although the social‐network structure influences the authority of experts, the influence weakens when the assessment group is a highly or even fully connected group; the network effect may increase the authority of some experts and reduce that of others, and it will weaken as the network connectivity increases; moreover, the judgement reliability and authority of an expert while considering post‐evaluation can encourage him/her to make fair assessments and strive to reduce his/her motivation and cognitive biases.     

The pulse distributed file system

A network of powerful personal computers, linked by a high-speed local area network, is being seen increasingly as an alternative to a traditional centralized time-sharing operating system. The PULSE project is investigating how such a system may be constructed to give the benefits of a self-sufficient personal computer to each user without losing the facilities for communication and sharing of data inherent in centralized systems. In particular, a distributed file system has been built which provides a single global UNIX

1 UNIX is a trademark of Bell Laboratories.

-like hierarchy, with a consistent appearance when accessed from any machine. Replicated copies of files are maintained to improve reliability, increase performance, and enable each machine to run stand-alone, albeit with reduced facilities.     

高吸水性树脂的性能及应用

综述了高吸水性树脂的性能及其应用，并预测其广阔的开发前景。     

悬浮法合成聚丙烯腈高吸水性树脂

以偶氮二异丁腈为引发剂，用悬浮聚合法合成了交联聚丙烯腈，然后对其进行水解，得到了高吸水性聚丙烯腈。交联剂用量和水解条件对树脂吸水倍数的影响很大。树脂吸去离子水倍数为420倍，平均粒径为250μm。     

A spectroscopic study of the self-association and inter-molecular aggregation behaviour of pH-responsive poly(l-lysine iso-phthalamide)

The pH mediated intra-molecular association and inter-molecular aggregation of a range of amphiphilic poly(l-lysine iso-phthalamide) polymers have been investigated in aqueous solution over a range of pH values and concentrations. The desired functionality of these novel bioresponsive amphiphilic polymers was achieved by incorporating pendant hydrophilic carboxyl groups along the polymer backbone, via the l-lysine moiety, balanced by a degree of hydrophobicity introduced via the iso-phthaloyl moiety. Incorporation of low levels of bis-functional Cy3 (poly-Cy3) and/or Cy5 dye (poly-Cy3/5 or poly-Cy5) co-monomers in the responsive polymer backbone allowed detailed probing of the pH mediated hydrophobic association using a combination of optical spectroscopic techniques. Both steady-state fluorescence spectroscopy and fluorescence lifetime measurements of poly-Cy3 revealed a conformational transition at pH 4.5. Thus, below a critical pH the polymer collapsed into a compact globular structure (hypercoil) bringing the fluorophore molecules into close proximity with one another. This resulted in a dramatic reduction in fluorescence intensity and fluorescent lifetime in the single fluorophore systems (poly-Cy3) accompanied by a red shift in the maximum emission wavelength. Observed redshifts in the emission maxima and enhancements of fluorescent lifetimes with increasing polymer concentration suggested the formation of polymer aggregates. Fluorescence resonance energy transfer (FRET) was measured in mixtures of single fluorophore containing poly-Cy3 (donor) and poly-Cy5 (acceptor) and dual fluorophore containing poly-Cy3 (donor)/Cy5 (acceptor) in an effort to distinguish between intra-molecular versus inter-molecular association. The relevance of the results with respect to potential in vivo applications (drug delivery and biodiagnostics) is discussed.