胜利原油350～510℃馏分糠醛精制的研究

对胜利原油 350～ 510℃馏分每 4 0℃切割一种馏分进行糠醛精制 ,考察了实验室条件下不同温度、不同醛油比条件下精制对提余油质量和收率的影响。采用醛油比 3× 1∶1,抽提温度在 70～ 95℃ ,可使精制馏分油粘度指数提高 10～ 2 7个单位 ,精制油收率高于 70 %。     

2.0 Mt/a渣油加氢脱硫装置新氢压缩机性能标定

介绍了中国石化茂名分公司 2 .0Mt/a渣油加氢脱硫装置中的 4M80 30 /2 2 2 0 0 BX型新氢压缩机的特点、技术特征及标定情况。采用国际通用标准对压缩机气体组成、容积流量、轴功率、进排气压力和进排气温度等指标进行了测定。标定表明 ,该机组设计方案合理 ,运转平稳 ,性能指标达到设计要求 ,较好的满足了工艺操作的需要     

用菱锌矿制取轻质氧化锌的研究

介绍了以菱锌矿为原料生产轻质氧化锌的方法，论述了反应酸浓度，煅烧温度，溶液PH值对实验的影响，并对生产工艺条件进行了研究。其工艺流程是将粉碎后的菱锌矿进行循环酸浸，净化后再直接和碳化母液反应，经沉降后再煅烧分解为轻质氧化锌，产品质量符合国家标准，视比容大，活性强，成本低，经济效益显著。     

The Synthesis of Sulfated Titanium Oxide Nanotubes

TiO₂ nanotubes can be prepared in gram quantities by treating anatase TiO₂ powder with concentrated NaOH solution. These TiO₂ nanotubes acquired strong acidity after being impregnated with sulfuric acid solution and calcined at 300 °C. The anatase TiO₂ powder used to prepare the nanotube did not catalyze the esterification between cyclohexanol and acetic acid, while sulfated TiO₂ nanotubes were very reactive toward the esterification reaction.     

高铬锰白口铸铁的软化处理

研究了 4种退火工艺对高铬锰白口铸铁组织和硬度的影响规律。结果表明 ,采用 85 0℃保温 4h ,随后于 72 0℃保温 6h退火工艺 ,硬度最低为 36～ 38HRC ,机加工性能最好。     

Growth Stresses in the Oxide Scales on TiAl Alloys at 800 and 900°C

In the oxidation of TiAl alloys, the role of scale-growth stresses formed during oxidation has, thus far, been unknown. In the present paper the oxide-growth stresses were investigated by the deflection-test method in monofacial oxidation (DTMO) accompanied by acoustic-emission measurements. On unmodified surfaces the growth stresses are compressive and reach levels of around –100 MPa. At the same time, significant acoustic emission occurs indicating that even under isothermal conditions, stresses are relieved by a scale-cracking mechanism. For oxide scales on TiAl surfaces, which had been ion implanted with chlorine before oxidation, a very thin protective alumina layer is formed which, however, develops growth stresses in the range of several GPa, accompanied by intensive acoustic emission. In all stress–time curves, a dynamic situation is observed. This consists of phases of stress relief by scale microcracking and phases of stresses increase due to crack healing and further oxide growth. As a result, the level of stress as a function of oxidation time, is characterized by an oscillating course.     

首钢烧结配加扬地粉试验研究

介绍了首钢原料条件下配加扬地粉对烧结生产影响的实验室研究.随着扬地粉配入量的增加,烧结矿转鼓强度、成品率改善,燃耗有少量上升,利用系数增加,低温还原粉化指数变差.研究结果表明:在首钢目前条件下,配入10%～20%的扬地粉是可行的.二烧车间进行了扬地粉工业试验,其最高配比达到30%,工业试验时烧结各项指标变化与实验室试验结果基本一致.     

A probabilistic model for cleavage fracture with a length scale--parameter estimation and predictions of stationary crack experiments

This study presents a large experimental investigation in the transition temperature region on a modified A508 steel. Tests were carried out on single-edge-notch-bend specimens with three different crack depth over specimen width ratios to capture the strong constraint effect on fracture toughness. Three test temperatures were considered, covering a range of 85 °C. All specimens failed by cleavage fracture prior to ductile tearing. A recently proposed probabilistic model for the cumulative failure by cleavage was applied to the comprehensive sets of experimental data. This modified weakest link model incorporates a length scale, which together with a threshold stress reduce the scatter in predicted toughness distributions as well as introduces a fracture toughness threshold value. Model parameters were estimated by a robust procedure, which is crucial in applications of probabilistic models to real structures. The conformity between predicted and experimental toughness distributions, respectively, were notable at all the test temperatures.     

熔融碳酸盐燃料电池阴极材料的导电性

通过交流阻抗方法研究了熔融碳酸盐燃料电池阴极材料锂镍氧化物、锂钴氧化物和锂铁氧化物的导电性能。结果表明:锂镍氧化物电极的导电性最好,锂钴氧化物电极的导电性次之,锂铁氧化物电极的导电性最差;它们的导电性都随着温度的升高而按指数规律增加;在合成锂钴氧化物(或锂铁氧化物)的过程中,使Li2CO3轻微过量,可以提高锂钴氧化物(或锂铁氧化物)电极的导电性,而且在同一温度下,随着nLi∶nCo(或nLi∶nFe,摩尔比)值的增大,锂钴氧化物(或锂铁氧化物)电极的导电性显著增加。     

In situ formation of multi scale reinforcing phases to improve performance of Al2O3-SiC C castables

In order to improve the physical properties and slag corrosion resistance of refractory materials for hot metal pretreatment, different contents of composite metal powders (CMP) were introduced into Al2O3-SiC-C refractory castables. The effect of CMP on the microstructure, physical properties and slag corrosion resistance of Al2O3-SiC-C refractory castables were studied. The results show that the multi scale reinforcing phases including flake crystals, rod shaped fibers, filamentous fibers and whiskers are in situ formed in the samples with addition of CMP, which result to the improvement of the cold modulus of rupture and cold crushing strength. When the addition of CMP is 6 wt.%, the high temperature modulus of rupture increases by 231%, the thermal shock resistance increases by 77% after thermal shock by water cooling 5 times and the percentage of the slag resistant area reduces by 37.2%.