曲轴激光喷丸强化试验研究

采用实验的方法,研究了激光冲击强化对175A型柴油机曲轴疲劳寿命的影响,取得了激光冲击强化试验条件下曲轴过渡圆角处残余应力场的数据。并将激光冲击强化工艺效果和曲轴滚压强化效果做了对比性分析,结果表明：虽然激光冲击强化效果不如曲轴滚压强化,但考虑到激光工艺参数精确可控、加工质量好、成本低以及可避免滚压强化所造成的表面疲劳、撕痕等,激光冲击强化工艺可望代替滚压强化成为新型的曲轴强化手段。通过此类激光冲击强化强化实验可优化激光冲击的相关参数,使曲轴过渡圆角产生有利的残余应力场。     

Rutile-type TiO2 thin film for high-k gate insulator

We investigated rutile-type titanium dioxide (TiO₂) films for possible use as a high-k gate insulator. The TiO₂ thin films were directly deposited on Si substrates using a RF magnetron sputtering method with a sintered oxide target. A single phase of rutile-type TiO₂ whose dielectric constant of approximately 75 was obtained when the film was deposited in an inert gas atmosphere and annealed at 800 °C in an oxidizing gas atmosphere. The oxygen ions were deficient in the as-deposited film, and consequently, a sufficient oxygen supply was needed to crystallize the film to a single phase of rutile during the post-annealing. However, the interfacial SiO₂ layer between the TiO₂ and the Si substrate simultaneously grew thicker than 2 nm. As the interfacial SiO₂ grew, the leakage current was decreased and the equivalent oxide thickness was increased, in the Au/rutile-type TiO₂/Si capacitor. Therefore, we concluded that the growth of the interfacial SiO₂ layer thicker than 2 nm is inevitable to form the single phase of rutile-type TiO₂ and to decrease the leakage.     

Nanoweb Formation: 2D Self‐Assembly of Semiconductor Gallium Oxide Nanowires/Nanotubes

This paper reports a method to produce networks of crystalline gallium oxide comprised of one‐dimensional (1D) nanostructures. Because of the unique arrangement of wires, these crystalline networks are termed as ‘nanowebs’. Nanowebs are of great technological interest since they contain wire densities of the order of 10⁹ cm^–2. A possible mechanism for the fast self‐assembly of crystalline metal oxide nanowires involves multiple nucleation and coalescence via oxidation–reduction reactions at the molecular level. The preferential growth of nanowires parallel to the substrate enabled them to coalesce into regular polygonal networks. The individual segments of the polygonal network consist of both nanowires and nanotubules of β‐gallium oxide. Individual wire properties contribute to a nanoweb’s overall capacity and the implications for devices based on nanowebs are expected to be enormous.     

Catalytic dehydrogenation of ethylbenzene with carbon dioxide: promotional effect of antimony in supported vanadium–antimony oxide catalyst

Alumina-supported vanadium oxide, VO_x/Al₂O₃, and binary vanadium–antimony oxides, VSbO_x/Al₂O₃, have been tested in the ethylbenzene dehydrogenation with carbon dioxide and characterized by S_BET, X-ray diffraction, X-ray photoelectron spectroscopy, hydrogen temperature-programmed reduction and CO₂ pulse methods. VSbO_x/Al₂O₃ exhibited enhanced catalytic activity and especially on-stream stability compared to VO_x/Al₂O₃ catalyst. Incorporation of antimony into VO_x/Al₂O₃ increased dispersion of active VO_x species, enhanced redox properties of the systems and formed a new mixed vanadium–antimony oxide phase in the most catalytically efficient V_0.43Sb_0.57O_x/Al₂O₃ system.     

Hydrolysis of Fe(OH)SO4 in the presence of metallic iron

Hydrolysis of Fe(OH)SO₄ was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe₂O₃ and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol.     

Properties and Performance of Cation-Doped Ceria Electrolyte Materials in Solid Oxide Fuel Cell Applications

Cation-doped CeO₂ electrolyte has been evaluated in single-cell and short-stack tests in solid oxide fuel cell environments and applications. These results, along with conductivity measurements, indicate that an ionic transference number of ∼0.75 can be expected at 800°C. Single cells have shown a power density >350 mW/cm². Multicell stacks have demonstrated a peak performance of >100 mW/cm² at 700°C using metallic separators.     

汽车发动机电机铁芯用钢(ADW2)的研制开发

鞍钢研制开发的汽车发动机启动电机用钢是针对汽车电机铁芯用钢（定、转子）而开发的电机钢类产品。介绍了该产品的研制过程及规格、特点。通过批量试制及装机试验，产品巳满足用户的使用要求。     

油气田开发中的CO2腐蚀及防护技术

综述了二氧化碳均匀腐蚀和局部腐蚀的机理，分析了二氧化碳腐蚀的各种影响因素，并对二氧化碳腐蚀的防护技术进行了概括，着重介绍了缓蚀剂防护技术研究进展，并提出了研究CO2腐蚀及其缓蚀剂应注意的几个问题。     

BYJ型防喷脱接器的设计与应用

本文介绍了BYJ型防喷脱接器的结构和工作原理。它既有抽油杆与大泵活塞脱接功能,又能实现不压井作业施工,是大型抽油泵理想的配套工具。现场应用表明,该防喷脱接器对接成功率较高,并实现了大泵井不压井施工。     

天津钢管公司DRC直接还原厂生产工艺与自动控制

天津钢管公司DRC直接还原厂将采用英国戴维国际工程公司的DRC煤基直接还原技术,以铁矿石、煤、石灰石为原燃料,用回转窑来生产直接还原铁(DRI)。该厂将由两条回转窑生产线组成,每条生产线的生产能力为15万tDRI/年,回转窑规格为φ5.0m×80m。工厂生产主线将采用计算机集散控制系统(DCS)以实现对生产过程的自动控制。