纳米氧化铟粉体的形貌与结构研究

用湿化学法制备了纳米极氧化铟超细粉体。利用透射电子显微镜、图像分析仪研究了纳米氧化铟粉体的形貌、尺寸分布和结构特征。结果表明，氧化铟粉体呈方片状，尺寸在10-30nm，化学组分高纯，达到了纳米级粉末要求；粉体的尺寸均匀，但在不同条件下制得的粉体，其尺寸相差较大；制备得到的氧化铟超细粉体的结构为体心立方。     

On the Yustova threshold plates

A response to criticism of threshold plates for the study of color vision developed at the Mendeleev All-Russia Research Institute of Metrology and published in 1994 is presented. The critics base their conclusions on colorimetric testing and the examination of the plates. In response to the article by M. V. Danilova and J. D. Mollon [4]. __________ Translated from Izmeritel’naya Tekhnika, No. 1, pp. 37–39, January, 2007.     

Mechanism for the Peritectic Reaction and Growth of Aligned Grains in YBa2Cu3O6+x

It is experimentally observed that the peritectic reaction, 211 + liquid → 123, can be driven essentially to completion in 1 h at an undercooling of only ∽30°C. The kinetic data, together with the observed microstructures, are inconsistent with the normal mechanism of the peritectic reaction. It is proposed that the mechanism of the reaction involves dissolution of 211 particles into the liquid and precipitation of solid 123. The aligned grain structure is explained through sympathetic nucleation of new 123 grains on existing grains.     

乙二醇合成工艺的研究进展

对国内外乙二醇合成的传统工艺:直接水合法、催化水合法和碳酸乙烯酯法进行了介绍;对乙二醇合成的新工艺,包括乙二醇和碳酸二甲酯联产法和C1化学法的工艺流程和发展前景进行了综述,其中,C1化学法主要分为乙烯合成法、合成气合成法和甲醛、甲醇合成法。作为合成气合成法之一的合成气偶联合成法,具有工艺要求不高、反应条件温和等优点,是目前最有希望大规模工业化生产乙二醇的工艺路线。     

Highly active lanthanum doped nickel anode for solid oxide fuel cells directly fuelled with methane

Lanthanum doped nickel and YSZ composite anode (LaNi–YSZ) exhibited a greatly reduced polarization resistance and high performance for electrochemical oxidation of hydrogen and methane, which resulted from a fine anode structure with a high dispersion of nickel catalyst and a high catalytic activity towards methane.     

Assessing the performance of intumescent coatings using bench‐scaled cone calorimeter and finite difference simulations

A method was developed to assess the heat insulation performance of intumescent coatings. The method consists of temperature measurements using the bench‐scaled experimental set‐up of a cone calorimeter and finite difference simulation to calculate the effective thermal conductivity dependent on time/temperature. This simulation procedure was also adapted to the small scale test furnace, in which the standard time–temperature curve is applied to a larger sample and thus which provides results relevant for approval. Investigations on temperature and calculated effective thermal conduction were performed on intumescent coatings in both experimental set‐ups using various coating thicknesses. The results correspond to each other as well as showing the limits of transferability between both fire tests. It is shown that bench‐scaled cone calorimeter tests are a valuable tool for assessing and predicting the performance of intumescent coatings in larger tests relevant for approval. The correlation fails for processes at surface temperatures above 750°C, which are not reached in the cone calorimeter, but are attained in the small scale furnace set‐up. Copyright © 2006 John Wiley & Sons, Ltd.     

B2O3/TiO2-ZrO2催化剂上环己酮肟的气相Beckmann重排反应

用共沉淀法制备了TiO2-ZrO2复合氧化物载体，BET，DTA，XRD表征结果表明，该复合载体具有较大的比表面和较好的热稳定性，对于环己酮肟气相Beckmann重排反应制己内酰胺，用复合载体制备的B2O3／TiO2-ZrO2催化剂，比分别以TiO2,ZrO2为载体所制备的B2O3/TiO2和B2O3／ZrO2催化剂具有更高的活性和选择性，实验表明，催化剂表面中等强度的酸位是环己酮肟气相Beckmann重排反应的有效活性中心。     

中国软磁铁氧体用氧化铁

介绍了中国软磁铁氧体用氧化铁的发展历史和现状，预测了未来的市场需求，并探讨了氧化铁的应用技术问题。     

Dynamics of hydrated iron(II) cations in nafion polymer membranes

Mössbauer studies of Fe²⁺ in water-soaked nafion polymer membranes in the temperature range between 90 K and 250 K have been performed. Above a critical temperature (～ 180 K) the spectra exhibit both elastic narrow absorption lines and quasielastic broad lines. These spectra are typical of bounded diffusion phenomena observed by Mössbauer spectroscopy in macromolecular systems like haemoglobin, myoglobin and ferritin. Similar spectral shapes have been observed by quasielastic neutron scattering from water in nafion membranes. Within 50 K above the critical temperature the total Mössbauer absorption area decreases by an order of magnitude whereas the narrow absorption line decreases by two orders of magnitude. The results are interpreted in terms of bounded diffusive motion of the iron. Using a model based on overdamped harmonically bound Brownian motion, the essential parameters of the iron motion can be derived as a function of temperature. The iron motion most probably reflects the motion of a large Fe²⁺ complex, e.g. Fe(H₂O)²⁺₆, which is attached to the polymer side chains via the sulphonic group.