In Situ Fully Light‐Driven Switching of Superhydrophobic Adhesion

An in situ fully light‐driven switching of superhydrophobic adhesion is demonstrated based on simply spin‐coating a hydrophobic azo‐polymer on an optimized micro‐nanopost arrayed silicon substrate. Furthermore, the detailed designing principles are discussed, which might shed light on efficient exploitation of superhydrophobic liquid/solid interfaces for smart microfluidic control.     

光影诗篇——墨西哥建筑艺术中的地域智慧与启迪

强烈的光照作为墨西哥一个十分突出的地域特征,对墨西哥的气候、文化乃至民众的生活习惯都产生了巨大的影响。墨西哥建筑师敏锐地捕捉到这一特征,融入自己的理解和想象,在光影与空间的交织、变化中呈现出丰富的情感色彩,使得建筑与人之间建立起直触心灵的对话。随着时代的变迁和文化的发展,建筑所要实现的功能、表达的情感在不断改变,而建筑师们对于光影的处理手段也趋于多元化,从而产生了越来越多极具特色的建筑形式。通过对墨西哥不同历史时期建筑的分析,来研究墨西哥建筑师运用光影塑造不同情感空间的多种手法和传承关系。     

Salt Concentration Effects in Planar Light‐Emitting Electrochemical Cells

Incorporation of ions in the active layer of organic semiconductor devices may lead to attractive device properties like enhanced injection and improved carrier transport. In this paper, we investigate the effect of the salt concentration on the operation of light‐emitting electrochemical cells, using experiments and numerical calculations. The current density and light emission are shown to increase linearly with increasing ion concentration over a wide range of concentrations. The increasing current is accompanied by an ion redistribution, leading to a narrowing of the recombination zone. Hence, in absence of detrimental side reactions and doping‐related luminescence quenching, the ion concentration should be as high as possible.     

龙耀路越江隧道中智能消防疏散指示系统的应用

越江隧道为人员密集型场所,针对火灾消防逃生的需求,系统地介绍智能消防疏散指示系统。以龙耀路越江隧道为例,从系统设置、布线、工作方式和效果等角度阐述了该系统在越江隧道中的实际应用。     

门式刚架轻型房屋钢结构的荷载取值和结构计算应引起重视的问题

本文对门式刚架轻型房屋钢结构的荷载取值、结构设计和计算、优化设计中应引起重视的问题做一定的分析、探讨,供设计同行参考。     

某高档别墅地下室渗漏治理与改进措施

通过对某别墅地下室渗漏水的治理过程,说明防水设计的重要性,特别阐述了应针对具体情况设计科学合理的防水构造的理念。     

White Electroluminescence by Supramolecular Control of Energy Transfer in Blends of Organic‐Soluble Encapsulated Polyfluorenes

Here, it is demonstrated that energy transfer in a blend of semiconducting polymers can be strongly reduced by non‐covalent encapsulation of one constituent, ensured by threading of the conjugated strands into functionalized cyclodextrins. Such macrocycles control the minimum intermolecular distance of chromophores with similar alignment, at the nanoscale, and therefore the relevant energy transfer rates, thus enabling fabrication of white‐light‐emitting diodes (CIE coordinates: x = 0.282, y = 0.336). In particular, white electroluminescence in a binary blend of a blue‐emitting, organic‐soluble rotaxane based on a polyfluorene derivative and the green‐emitting poly(9,9‐dioctylfluorene‐alt‐benzothiadiazole ( F8BT ) is achieved. Morphological and structural analyses by atomic force microscopy, fluorescence mapping, µ‐Raman, and fluorescence lifetime microscopy are used to complement optical and electroluminescence characterization, and to enable a deeper insight into the properties of the novel blend.     

Preparation and physical properties of the layered niobate Cu0.5Nb3O8: Application to photocatalytic hydrogen evolution

The new layered niobate Cu_0.5Nb₃O₈ is synthesized by soft chemistry in aqueous electrolyte via Cu²⁺→H⁺ exchange between copper nitrate and HNb₃O₈·H₂O. The characterization of the exchanged product is made by means of thermal gravimetry, chemical analysis, X-ray diffraction and IR spectroscopy. Thermal analysis shows a conversion to anhydrous compound above 500 °C. The oxide displays a semiconductor like behavior; the thermal variation of the conductivity shows that d electrons are strongly localized and the conduction is thermally activated with activation energy of 0.13 eV. The temperature dependence of the thermopower is indicative of an extrinsic conductivity; the electrons are dominant carriers in conformity with an anodic photocurrent. Indeed, the Mott–Schottky plot confirms n-type conduction from which a flat band potential of −0.82 V_SCE, an electronic density of 8.72×10¹⁹ m⁻³ and a depletion width of 4.4 nm are determined. The upper valence band, located at ~5.8 eV below vacuum is made up predominantly of Cu²⁺: 3d with a small admixture of O²⁻: 2p orbitals whereas the conduction band consists of empty Nb⁵⁺: 5s level. The energy band diagram shows the feasibility of the oxide for the photocatalytic hydrogen production upon visible light (29 mW cm⁻²) with a rate evolution of 0.31 mL g⁻¹ min⁻¹.     

Light and Strong SiC Networks

The directional freezing of microfiber suspensions is used to assemble highly porous (porosities ranging between 92% and 98%) SiC networks. These networks exhibit a unique hierarchical architecture in which thin layers with honeycomb‐like structure and internal strut length in the order of 1–10 μm in size are aligned with an interlayer spacing ranging between 15 and 50 μm. The resulting structures exhibit strengths (up to 3 MPa) and stiffness (up to 0.3 GPa) that are higher than aerogels of similar density and comparable to other ceramic microlattices fabricated by vapor deposition. Furthermore, this wet processing technique allows the fabrication of large‐size samples that are stable at high temperature, with acoustic impedance that can be manipulated over one order of magnitude (0.03–0.3 MRayl), electrically conductive and with very low thermal conductivity. The approach can be extended to other ceramic materials and opens new opportunities for the fabrication of ultralight structures with unique mechanical and functional properties in practical dimensions.     

含液晶缺陷层阶梯型双周期结构的电场方向调控特性

利用传输矩阵法研究了含向列相液晶缺陷层的一维阶梯型Double-period第四代准周期结构缺陷模的电场方向调控特性。分析了外加电场方向和正入射波方向间夹角θ与缺陷模的位置、品质因子、空间位置光场分布的变化关系,最后探讨了缺陷模的品质因子对光场强度的影响。结果表明：随着夹角θ的逐渐增大,缺陷模的位置向短波方向移动,缺陷模波长的调控量为84nm;随着夹角θ的逐渐增大,缺陷模的品质因子逐渐增大;缺陷模在空间位置的光场分布呈现出局域现象,随夹角θ的增大,空间位置的光场强度逐渐增强;缺陷模的品质因子与光场强度成正比关系。