燃料性质对加热炉腐蚀结焦的影响及其防治

从加热炉燃料变化情况入手 ,分析了加热炉目前存在的炉管结垢 ,预热器烟气露点腐蚀以及炉体腐蚀等问题。从机理上进行了探讨 ,从而提出了原油脱金属、燃料气脱硫、燃料油优化、化学除垢以及预热器改造等防护措施。     

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四川目前生产的天然气中含硫天然气占７１％，而含硫天然气对高强度钻杆会产生硫化物应力腐蚀玻裂，因此，在含硫气井进行钻杆测试时，应重视钻杆的安全问题。文章探讨了高强度钻杆硫化物应力腐蚀玻裂的机理和影响钻杆脆断时间的各种因素，并提出在一定的条件下，高强度钻杆在含硫气并中进行测试是安全的。采用向钻杆内加缓蚀剂或内涂层钻杆，防硫油管测试，钻杆测试更加安全。建议继续开展高强度钻杆硫化物应力腐蚀玻裂时间的试验研究，以确定合理的钻杆测试安全时间。     

Dental amalgam – the effect of the technology of alloy powder preparation on the corrosion behaviour and the release of mercury

Dental amalgams are based on a broad spectrum of materials differing in their chemical composition, metallurgical treatment, and in the way the initial alloys powders are prepared. In addition to their chemical composition, amalgams based on various powders differ in both their microstructure and the amount of mercury needed for preparation. All these facts may affect electrochemical processes occurring during their interaction with oral fluids, and also mercury release. While verifying the effect of the technology used for the preparation of the high‐copper ternary alloy powder on the properties of resulting amalgams, this study aimed at the mechanism of their interaction with a model saliva solution as well as mercury release was included. Measurements were done in a model saliva solution using standard electrochemical methods and exposition measurements. The interaction of individual types of amalgams with artificial saliva did not reveal any significant differences. The free corrosion potential of all these amalgams in an aerated solution settled in the range of values in which tin oxidation, resulting in a layer of insoluble corrosion producsts, turned out to be the dominant anodic process. The rate of mercury release was the lowest for amalgams based on a gas‐atomized alloy. The highest rate of mercury release, and also its dependence on time, was exhibited by lathe‐cut powder based amalgam. In addition to different volume fraction of the Ag‐Hg phase and the level of its tin alloying, this different behaviour may be explained by differences in the rate at which a layer of tin corrosion products acting as a barrier to mercury release is formed.     

氯碱生产中的腐蚀与防护

介绍了氯碱装置中介质的腐蚀特性、常用材料的耐腐蚀特性及应用实例。     

200kt／a蒸馏装置硫腐蚀典型事例分析

通过对200kt/a蒸馏装置几起硫腐蚀典型事例的分析,提出了改进措施,消除了腐蚀泄漏隐患,确保了装置安全、平稳、长周期运行。     

锌加(ZINGA)防腐钢筋在杭州湾跨海大桥施工中的应用

杭州湾跨海大桥在极其复杂的海洋环境下施工，外露钢筋极易腐蚀，锌加钢筋能提高钢筋的抗腐蚀能力，本文简介锌加防腐钢筋在大桥施工中的应用情况。     

焊补法带压堵漏技术与不停车带压堵漏技术的应用

介绍了传统的焊补法堵漏及目前常用的不停车带压堵漏技术的基本原理、操作步骤以及密封剂类型，并对两种方法进行了比较。     

200m3液氨球罐裂纹成因分析

通过检验,从球罐的应力状态、球罐的金属材料和腐蚀介质等方面对200m3液氨球罐表面裂纹的形貌及产生裂纹的原因进行了分析,确定了球罐的裂纹是应力腐蚀裂纹,并对球罐进行了强度计算及安全评估。     

Corrosion failure of Zn–Al detonator housing

Some batches of detonator housings made up of Chromium plated Zn–Al alloy were found in an extensively cracked condition after few months of storage at room temperature. An analysis of the failure showed that the cracks were due to intergranular corrosion facilitated by segregation of lead at the grain boundaries. Improper chromium plating further aggravated the corrosion problem. This failure case emphasises the need for strict control of chemical composition for components made from Zn–Al alloy and the process of Cr plating of the components.     

劣化环丁砜再生技术的工业应用

为解决国内外环丁砜抽提芳烃工艺中环丁砜的劣化问题，在不添加单乙醇胺的前提下，采用阴离子交换树脂处理劣化的环丁砜，可使系统的pH值从3．4升到5．5左右，离子交换树脂需30d左右再生一次，降低了设备的腐蚀，减少了装置的堵塞，使系统运行稳定，取得了可观的社会效益和经济效益。