A New Variable Diffusion Drying Model for the Second Falling Rate Period of Paddy Dried in a Rapid Bin Dryer

The objectives of this article is to propose a new drying model for the second falling rate period known as the variable diffusion controlled period that follows after the first falling rate period and to propose a new method to determine the second critical moisture content that separates these two periods. Experimental work on paddy drying at minimum fluidization velocity was carried out in a rapid bin dryer. The effects of operating temperatures (60-120°C) and bed depths (2-6 cm) on the paddy drying characteristics were investigated. It was found that the normalized drying rate of paddy was proportional to the normalized moisture content in the first falling rate period but in the second falling rate period, the normalized drying rate of the material varies exponentially with the normalized moisture content. The different relationship between the normalized drying rate and the normalized moisture content in the first and second falling rate periods indicate that two different mechanism of moisture transport are at work. The new exponential model of the second falling rate period and the linear model of the first falling rate period were found to fit the experimental data very well. Derivation from variable diffusion equation shows that the linear model is the result of constant diffusion coefficient whereas the new exponential model is the result of linear diffusion coefficient. This also implies that the first falling rate period is a constant diffusion controlled period and the second falling rate period is a variable diffusion controlled period. In addition, drying kinetics data of a drying process that fits the exponential model over a very slow drying period will show that the drying process is under the effect of a linear diffusion coefficient. It was also found that the proposed new method to determine the second critical moisture content that distinguishes between the first and second falling rate periods by using a sudden change in the value of the drying rate gradient to a much lower value at that point is more rigorous and yet simpler than the method of determining the specific location of the receding drying boundary since it is based on the behavior of the actual drying kinetic data.     

发光体MAl2O4:Eu2+,RE3+的长余辉形成机理

提出了Eu^2 激活的MAl2O4:Eu^2 ,RE^3 （M＝Ca,Sr,Ba;RE=Dy,Nd,Ho,Er,Pr,Tb等稀土元素）系列铝酸盐发光体的长余辉发光机理。认为O^2-空位Vo是一种电子俘获陷际，是形成余辉的根本原因，RE^3 的引入使陷阱深度适宜而使余辉时间延长。缺陷在晶格中成簇分布，Vo和碱土金属离子空位VM在高温下可相互缔合。利用电子陷阱模型解释了实验中的一些普遍现象并提出了固相反应法合成此类发光体的工艺改进措施。     

Luminescence Characterization of Mg Doped Y2O2S:Ti Long Afterglow Phosphor

Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves were investigated. The results show that the luminescence intensity of Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors decrease gradually with increasing Mg2 ion content, and the shape of luminescence spectra and chromaticity coordinate change as well. Furthermore, two thermoluminescent peaks in single Ti-doped Y2O2S sample are found at 91.8 and 221.5 ℃, respectively. Nevertheless, significant different spectra were found for the Mg, Ti co-doped Y2O2S samples that three thermoluminescence peaks appear at 52.3, 141.7 and 226.8 ℃, respectively. These results indicate that the co-doped Mg ion changes the inherent trap depth of single Ti-doped Y2O2S:Ti phosphor, and induces simultaneously a new trap level in the Y1.94-xMgxO2S:0.06Ti phosphor. Based on the analysis of thermoluminescent spectra, photoluminescent spectra, decay curve and crystal structure defect, it was proposed that the varied structure defect and introduced new trap level by the doped Mg2 ions should be responsible for reducing luminescence intensity and varying color in the Y1.94-xMgxO2S:0.06Ti phosphor.     

水电站施工期水土流失预测

水电站建设的水土流失问题主要体现在施工期和运行期，并以施工期的影响较为突出．如不采取必要的减免措施，将会对周围生态环境造成无法挽回的损失。本文阐述了水电站建设水土流失的几种常用的预测方法，对水土流失量进行预测，并结合具体工程实例对水电站建设过程中新增水土流失量进行了预测。     

河南电力远程教育网系统安全方案开发应用

河南省电力公司远程教育平台,作为一个省内电力系统职工的再教育、技术培训、技能培训中心,访问量大,安全要求高,我们在软件设计时充分考虑到系统的安全性。     

Delta4型外流式压力筛的长纤维浆筛选实践

介绍了Delta4型压力筛生产全漂白硫酸盐法马尾松浆的运行情况，对存在的问题进行分析探讨，并对比了技改重新选型后的生产情况。     

中原高温高盐油藏疏水缔合聚合物凝胶调剖剂研究

针对中原油田高温(>80℃)、高盐度(>50 g/L)、高硬度(>1 g/L)砂岩油藏,研制了地下成胶的高热稳定性聚合物凝胶调剖剂。所用聚合物为疏水缔合聚合物AP-P4,M=9.0×106,HD=27%,疏水基摩尔分数0.2%;交联剂为可生成酚醛树脂的3种化合物;调剖剂胶液用矿化度160 g/L的马寨油田污水配制;实验温度95℃。根据形成的凝胶黏度(95℃,1.1 s-1)确定交联剂各组分用量为:MZ-YL 0.429%,MZ-BE 0.060%,MZ-XS 0.012%;酸度调整剂用量0.12%;成胶时间10~15小时。2.5、3.0、3.5 g/L AP-P4的凝胶在95℃老化100天后黏度保持在~40 Pa.s及以上。初配制胶液在3000 r/min下剪切15分钟后黏度降低87.5%~89.0%,但成胶后和老化过程中凝胶黏度只比未剪切样降低17.1%~6.6%。3.5 g/L AP-P4的调剖剂对~1μm2的6支储层岩心的堵塞率在88.1%~95.8%范围,平均93.3%,造成的残余阻力系数在15.2~28.6范围,平均19.8,使渗透率级差2.3~8.0的4组双人造岩心的注水流量比发生不同程度的反转。认为该凝胶调剖剂高温下稳定性好的原因,是强化学交联密度低,因而凝胶脱水收缩作用弱。图2表5参5。     

吐哈油田葡北3-12井超长封固段固井技术

葡北3-12注气井位于吐哈盆地葡北构造带中断葡北1号构造．井深为3610m。针对该区块地层承压能力低，易漏失，油气水窜严重，常规固井方法无法满足固井要求的问题，该井采用三段三凝制、常规水泥浆和泡沫水泥浆体系固井，并采用重钻井液顶替技术．降低施工压力。该技术能保证固井候凝过程中井底压力平衡，施工安全。现场应用表明，采用常规水泥浆和泡沫水泥浆固井技术．提高了低压易漏井、长封固井段的固井质量，解决了水泥返高不足的问题；并通过一次常规固井工艺实现了全井封固，简化了施工工艺，节约了成本，经济效益和社会效益十分显著。该井封固优质段累计达2600m，优质率达85％，固井结果良好。     

英台地区天然水驱油藏的开发特点及稳产技术

掌握边底水运动规律，控制并利用活跃的边底水能量，是成功开发天然水驱油藏的关键。英台地区的英台、四方坨子和一棵树等三个油田均为天然水驱油藏，天然能量充足。油藏投入开发后初期含水较高，含水上升极快，造成产油量大幅度递减。针对其开发特点，适时采用大泵、电潜泵提液强采，通过大量补孔层间接替以及加密调整和扩边等稳产技术措施，确保了油藏以3％-5％的采油速度长期稳产，水驱采收率高达50％以上。