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131.
H. Chen L.‐H. Liu L.‐S. Wang C.‐B. Ching H.‐W. Yu Y.‐Y. Yang 《Advanced functional materials》2008,18(1):95-102
In this study, thermally responsive alkyl end‐capped poly(N‐isopropylacrylamide‐co‐acrylic acid) amphiphilic copolymers were synthesized, and successfully utilized to fabricate reversed micelles and immobilize enzymes. Transmission electron microscopy (TEM) study showed that the reversed micelles were spherical in nature. The activity of Candida rugosa lipase immobilized in the reversed micelles towards catalyzing the esterification of lauric acid and 1‐propanol was analyzed in comparison with naked enzyme. Immobilized lipase provided much greater catalytic activity. In addition, the effects of pH, water content, polymer and enzyme concentration on the catalytic activity were investigated. The optimized fabrication conditions of lipase‐loaded reversed micelles, under which lipase gave the highest activity, were as follows: polymer concentration, 12 mg mL–1; enzyme concentration, 25 mg mL–1 phosphate buffered saline (PBS); pH, 7.4; W0 ([water]/[surfactant]), 83.3. Lipase immobilized in these micelles was much more stable than that in conventional sodium bis(2‐ethylhexyl) sulfosuccinate micelles. More importantly, the size of lipase‐immobilized micelles decreased, and the enzyme solution precipitated from the reaction mixture when the temperature increased to a value slightly higher than the lower critical solution temperature (LCST) of the polymer. The recovery rate of enzyme was about 75 %. The α‐helix structure of the recovered lipase remained intact. In addition, the enzymatic reaction was terminated after raising the environmental temperature slightly above the LCST. These thermally responsive micelles may make a promising system for enzyme immobilization. 相似文献
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In this article, a redox-responsive poly(ionic liquid) (redox-PIL) hydrogel Poly(1-vinyl-3-propionate imidazole phenothiazine sulfonic acid)-chitosan [Poly(VPI+PTZ-(CH2)3SO3−)-CS] was produced by using chitosan (CS) crosslinking with redox-PIL Poly(1-vinyl-3-propionate imidazole phenothiazine sulfonic acid [Poly(VPI+PTZ-(CH2)3SO3−)]. The incorporation of redox-active counter anions 3-(phenothiazine-10-yl) propane 1-sulfonic acid anions (PTZ-(CH2)3SO3−) into cationic PIL-polyimidazole rendered Poly(VPI+PTZ-(CH2)3SO3−) with electron catalytic ability, ionic conductivity, and electron conductivity. Poly(VPI+PTZ-(CH2)3SO3−)-CS combines the properties of hydrogel and redox-PIL, thus offering intrinsic porous conducting frameworks and promoting the transport of charges, ions, and molecules, leading hydrogel with excellent electrochemical properties. The crosslinking occurrence of Poly(VPI+PTZ-(CH2)3SO3−) and CS resulting from the synthetic process of hydrogel was verified by differential scanning calorimetry and thermogravimetric analysis. A three-dimensional polymer network hydrogel with good biocompatibility and permeability was formed after crosslinking. In addition, only 64% weight loss within 600 °C was observed in Poly(VPI+PTZ-(CH2)3SO3−)-CS representing its thermally stable performance. When used as an electrochemical sensor, the hydrogel-modified gold electrode improved the electrocatalytic oxidation of cysteine. Differential pulse voltammetry results indicated that the detection range was from 5 × 10−8 to 5 × 10−3 M and the limit of detection was 6.64 × 10−8 M. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48051. 相似文献
135.
The pH-responsive microgels (MGs) consisting of methacrylic acid-ethyl acrylate (MAA-EA), methacrylic acid-butyl methacrylate (MAA-BMA) or methacrylic acid-methyl methacrylate (MAA-MMA) crosslinked with di-allyl phthalate (DAP) were synthesized via emulsion polymerization. It was found that the energy required to extract a proton from MGs with higher glass-transition temperature (Tg) was greater than at a lower Tg. Procaine hydrochloride (PrHy) was used to study the release of a model hydrophobic drug from MGs with different Tgs. A drug selective electrode (DSE) was used to monitor the release as a function of pHs and Tgs. With increasing pH or decreasing Tg, the swelling of MGs was enhanced, leading to greater release of the drug. From the Berens and Hopfenberg model, the contributions of chain relaxation and diffusion processes during a release process were determined. The drug release from lower Tg MGs and at high pH is dominated by diffusion rather than chain relaxation. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47284. 相似文献
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Xinhui Zhang Mingming Guo Balarabe B. Ismail Qiao He Tony Z. Jin Donghong Liu 《Comprehensive Reviews in Food Science and Food Safety》2021,20(5):5258-5282
Microbial growth and fluctuations in environmental conditions have been shown to cause microbial contamination and deterioration of food. Thus, it is paramount to develop reliable strategies to effectively prevent the sale and consumption of contaminated or spoiled food. Responsive packaging systems are designed to react to specific stimuli in the food or environment, such as microorganisms or temperature, then implement an informational or corrective response. Informative responsive packaging is aimed at continuously monitoring the changes in food or environmental conditions and conveys this information to the users in real time. Meanwhile, packaging systems with the capacity to control contamination or deterioration are also of great interest. Encouragingly, corrective responsive packaging attempting to mitigate the adverse effects of condition fluctuations on food has been investigated. This packaging exerts its effects through the triggered release of active agents by environmental stimuli. In this review, informative and corrective responsive packaging is conceptualized clearly and concisely. The mechanism and characteristics of each type of packaging are discussed in depth. This review also summarized the latest research progress of responsive packaging and objectively appraised their advantages. Evidently, the mechanism through which packaging systems respond to microbial contamination and associated environmental factors was also highlighted. Moreover, risk concerns, related legislation, and consumer perspective in the application of responsive packaging are discussed as well. Broadly, this comprehensive review covering the latest information on responsive packaging aims to provide a timely reference for scientific research and offer guidance for presenting their applications in food industry. 相似文献
139.
Shuangjiang Feng Shuxue Wang Yuanfei Lv Lei He Qiurong Li Tao Zhang 《Polymer International》2019,68(3):494-502
Hydrogels have been widely used as mild biomaterials due to their bio‐affinity, high drug loading capability and controllable release profiles. However, hydrogel‐based carriers are greatly limited for the delivery of hydrophobic payloads due to the lack of hydrophobic binding sites. Herein, nano‐liposome micelles were embedded in semi‐interpenetrating poly[(N‐isopropylacrylamide)‐co‐chitosan] (PNIPAAm‐co‐CS) and poly[(N‐isopropylacrylamide)‐co‐(sodium alginate)] (PNIPAAm‐co‐SA) hydrogels which were responsive to both temperature and pH, thereby establishing tunable nanocomposite hydrogel delivery systems. Nano‐micelles formed via the self‐assembly of phospholipid could serve as the link between hydrophobic drug and hydrophilic hydrogel due to their special amphiphilic structure. The results of transmission and scanning electron microscopies and infrared spectroscopy showed that the porous hydrogels were successfully fabricated and the liposomes encapsulated with baicalein could be well contained in the network. In addition, the experimental results of response release in vitro revealed that the smart hydrogels showed different degree of sensitiveness under different pH and temperature stimuli. The results of the study demonstrate that combining PNIPAAm‐co‐SA and PNIPAAm‐co‐CS hydrogels with liposomes encapsulated with hydrophobic drugs is a feasible method for hydrophobic drug delivery and have potential application prospects in the medical field. © 2018 Society of Chemical Industry 相似文献
140.
Supramolecular Materials: Multifunctional Supramolecular Hybrid Materials Constructed from Hierarchical Self‐Ordering of In Situ Generated Metal‐Organic Framework (MOF) Nanoparticles (Adv. Mater. 30/2015)
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Abhijeet K. Chaudhari Intaek Han Jin‐Chong Tan 《Advanced materials (Deerfield Beach, Fla.)》2015,27(30):4523-4523