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101.
Alexis Tran‐Viet Alexander F. Routh Andrew W. Woods 《American Institute of Chemical Engineers》2014,60(3):1193-1201
Experiments explore the reduction in permeability of a porous bead pack when a suspension of thermally responsive polymer is injected and the temperature then increased above the thermal activation temperature. The change in permeability is greater with higher polymer concentration, provided that the ionic concentration of the solution is sufficient for floc formation. The time for activation of the blocking effect is within tens of seconds to minutes of when the polymer solution is heated. This is consistent with the timescale for diffusion‐limited aggregation, although the detailed value depends on the geometry and polymer concentration. Dynamical experiments demonstrate that once the porous media is blocked, adding additional polymer has no effect. The mechanism for permeability reduction may be modeled in the context of a pore‐network model, and we build a simple model to illustrate the permeability reduction as a function of the fraction of pores links which are blocked. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1193–1201, 2014 相似文献
102.
Oscillatory shear rheology of dilute solutions of flexible polymers interacting with oppositely charged particles
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Rangarajan Radhakrishnan Patrick T. Underhill 《American Institute of Chemical Engineers》2014,60(4):1365-1371
Fluids with both attractions and repulsions among its constituents can exist in multiple states depending on nature of the interactions. An external flow can induce such systems to transition between the different states, such as the globule‐stretch transition for polymers in poor solvents. Brownian dynamics simulations of a dilute solution of polymers and colloids interacting via short‐ranged potentials are presented. For some values of the strength and range of interactions, compact structures of polymers and colloids are formed. An external flow is capable of pulling these globules apart, causing the polymers to stretch at a critical shear rate. In oscillatory shear, the shear rate can cycle between being above and below this critical shear rate leading to interesting dynamics. These dynamics are quantified using the rheological response in large amplitude oscillatory shear. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1365–1371, 2014 相似文献
103.
Hydraulic fracturing has been used by the oil and gas industry as a way to boost hydrocarbon production since 1947. Recent advances in fracturing technologies, such as multistage fracturing in horizontal wells, are responsible for the latest hydrocarbon production boom in the US. Linear or crosslinked guars are the most commonly used fluids in traditional fracturing operations. The main functions of these fluids are to open/propagate the fractures and transport proppants into the fractures. Proppants are usually applied to form a thin layer between fracture faces to prop the fractures open at the end of the fracturing process. Chemical breakers are used to break the polymers at the end of the fracturing process so as to provide highly conductive fractures. Concerns over fracture conductivity damage by viscous fluids in ultra‐tight formations found in unconventional reservoirs prompted the industry to develop an alternative fracturing fluid called “slickwater”. It consists mainly of water with a very low concentration of linear polymer. The low concentration polymer serves primarily to reduce the friction loss along the flow lines. Proppant‐carrying capability of this type of fluids is still a subject of debate among industry experts. Constraints on local water availability and the potential for damage to formations have led the industry to develop other types of fracturing fluids such as viscoelastic surfactants and energized fluids. This article reviews both the traditional viscous fluids used in conventional hydraulic fracturing operations as well as the new family of fluids being developed for both traditional and unconventional reservoirs. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40735. 相似文献
104.
Wei Zhao Songhong Zhang Meizhen Lu Shaochuan Shen Junxian Yun Kejian Yao Linhong Xu Dong-Qiang Lin Yi-Xin Guan Shan-Jing Yao 《Chemical Engineering Research and Design》2014
The microchannel liquid-flow focusing and cryo-polymerization is an efficient method for the preparation of cryogel beads with a narrow diameter distribution. In order to prepare cryogel beads with expected diameters, it is necessary to get insights in the liquid–liquid immiscible flow characteristics of the flow-focusing fluid and the monomer solution in microchannels. In this work, the slug flow behaviors of two immiscible liquids regarding the preparation of poly(2-hydroxyethylmethacrylate) (pHEMA) cryogel beads in a rectangular cross-junction microchannel were investigated experimentally by the high-speed imaging method. Correlations of the immiscible liquid–liquid slug flow parameters like the aqueous slug velocity and length, the aqueous slug nose and tail lengths, the water-immiscible slug length as well as the aqueous droplet size were obtained. The pHEMA cryogel beads were prepared under certain flow conditions and the bead sizes were measured by laser particle size analyzer. The obtained correlations were then employed to estimate the bead sizes and compared with those obtained experimentally. The results showed that the present correlations gave reasonable estimations of the mean bead diameters at various conditions and thus, could be useful and helpful in the preparation of cryogel beads with expected size distributions in rectangular microchannels. 相似文献
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本文简单介绍了磁流变液的材料特性以及磁流变阻尼器的几种力学模型.并阐述了其在土木工程领域结构振动控制中的应用. 相似文献
107.
研究了磁流体的阻尼力特性,提出了基于粘性阻尼和回滞阻尼组成的迟滞阻尼力模型,进行了磁流变阻尼器阻尼力的响应谱分析,并用Newmark数值积分方法分析了带有磁流变流体阻尼器梁结构的多自由度振动系统在不同磁场强度和激励频率作用下的位移响应.结果表明:迟滞阻尼力模型能够很好地描述磁流体阻尼器的力学性能,而且形式简单,概念明确,适合实际应用. 相似文献
108.
The semi-actively controllable magneto-rheological(MR) fluid-based dampers have superior potentials inrealizing intelligent vehicle suspension designs, thesynthesis of an effective semi-active controller forms theessential objective[1 -4]. However, the MR… 相似文献
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