Immobilizing chromium in stainless steel slags with MnO addition

This work investigates the stabilizing impact of MnO on the leaching behavior of hazardous Cr-containing CaO-SiO₂-Al₂O₃-Cr₂O₃-MnO stainless steel slags after equilibrating at various elevated temperatures and evaluates the potential immobilization of Cr into a MnCr₂O₄ spinel phase from the existing Cr₂O₃ phase. The MnCr₂O₄ spinel phase was found to be an excellent Cr-stabilizer in stainless steel slags, where the leaching tendency of potentially hazardous Cr-related ions decreased with higher MnO content and lower equilibration temperatures within the range of 0 to 15 mass pct. and 1500 to 1300°C, respectively. Thermodynamic calculations by conducting the phase stability diagram also showed that the MnCr₂O₄ spinel phase was relatively stable and the Ca₃Si₂O₇ (Ca_3-xMn_xSi₂O₇) phase was relatively unstable compared with other crystal phases in acid extractant with pH value of 3.2. Combined with the scanning electron microscopy and X-ray powder diffraction results along with the thermodynamic calculations, the leached Cr-related ions was predominantly originating from the unstable amorphous glass phase.     

Wear mechanisms of PcBN tools when machining AISI 316L

This paper investigates the machinability of AISI 316L stainless steel without and with NMI treatment, when machined with three different PcBN tool grades: low cBN content (50% vol.), medium (65% vol.) and high (90% vol.). The NMI treatment consisted of resulfurized and Ca-treated steels with two different Si/Al ratio. The tool materials were evaluated in terms of tool life, showing the best performance for the medium cBN content grade. Results showed that the crater wear has a more significant effect on the tool performance than the standard wear criteria of maximum flank wear. The worn tools were examined using scanning electron microscopy (SEM), focused ion beam (FIB) and transmission electron microscopy (TEM). In most cases, the crater exhibited three distinct regions from the edge to the end of the contact zone: the plateau, middle crater, and the upper region. Plateau and crater region displayed tool protective layer (TPL), consisting mostly of Al, Si, Mg and Ca-oxides; and some dimples in the tool from preferential wear of cBN grains. In the upper region of the best performing material, a ~1.5 μm thick TPL of mostly MnCr₂O₄ spinel was found, a result of the transfer of Mn- and Cr-rich oxide NMIs found in this material or oxidation of workpiece material, during the machining process.     

High Temperature Oxidation of Steels in Air and CO2–O2 Atmosphere

Three kinds of hot rolled steel slabs, viz. high strength steel, bake hardened steel and low carbon steel, were oxidized isothermally between 1100 and 1250 °C for up to 2 hr in 1 atm of air and an 85%N₂–10%CO₂–5%O₂ gas mixture. The steels were oxidized in a similar fashion in both the atmospheres. The oxidation process followed an initial linear rate law, which then gradually transformed to a nearly parabolic rate law. Thick, porous and nonadherent scales formed rapidly, due to the high oxidation temperature. The scales formed consisted of Fe₂O₃,(Fe₂O₃+Fe₃O₄), (Fe₃O₄+Fe₂O₃ +FeO) and (FeO+Fe₃O₄) from the outer surface. The presence of supersaturated oxygen beneath the scale resulted in grain boundary oxidation and the formation of internal oxide precipitates.     

离心铸造高速钢轧辊铸造缺陷形成与控制技术研究

采用离心铸造方法制造高速钢轧辊工艺简单,操作方便,但易出现偏析、裂纹、气孔、缩孔及夹杂等缺陷,影响轧辊的力学性能和使用性能.采用稀土-钛复合变质处理改善合金的组织和性能,同时改进离心铸造工艺参数可以消除高速钢轧辊铸造缺陷,提高力学性能,改善使用效果.     

The influence of sulphate-reducing bacteria biofilm on the corrosion of stainless steel AISI 316

This work investigates microbially-influenced corrosion (MIC) of stainless steel AISI 316 by two sulphate-reducing bacteria, Desulfovibrio desulfuricans and a local marine isolate. The biofilm and pit morphology that developed with time were analyzed using atomic force microscopy (AFM). Electrochemical impedance spectroscopy (EIS) results were interpreted with an equivalent circuit to model the physicoelectric characteristics of the electrode/biofilm/solution interface. D. desulfuricans formed one biofilm layer on the metal surface, while the marine isolate formed two layers: a biofilm layer and a ferrous sulfide deposit layer. AFM images corroborated results from the EIS modeling which showed biofilm attachment and subsequent detachment over time.     

Influence of chromium on the local structure and morphology of ferric oxyhydroxides

The extended X-ray absorption fine structure (EXAFS) method and transmission electron microscopy (TEM) have been used for characterizing the local structure and morphology of ferric oxyhydroxides, α-FeOOH and γ-FeOOH, with and without chromium. These ferric oxyhydroxide powders were prepared from aqueous solutions containing iron and chromium ions. Radial structural functions for iron obtained by Fe K edge EXAFS spectra showed that the linkage of structural units formed by FeO₆ octahedra in γ-FeOOH is distorted by chromium addition, while such distortion in α-FeOOH is not clearly detected. On the other hand, Cr K edge EXAFS spectra showed that the local structure around chromium does not necessarily correspond to the local structure around of iron, which is observed by Fe K edge EXAFS spectra. This suggests that the structural units containing iron and chromium are heterogeneously distributed in these ferric oxyhydroxides. The local structural information was discussed coupled with morphological features of these ferric oxyhydroxides observed by TEM.     

高精度冷轧不锈钢管生产

介绍了用ＬＤ型冷轧管机生产高精度冷轧不锈钢管的经验和质量保证措施。     

奥氏体化温度及冷却方式对20Mn2SiVB钢组织及性能的影响

通过各种试验手段,研究了20Mn2SiVB钢不同奥氏体化温度及不同冷却方式处理后其显微组织及其强度和塑性的变化,确定了最佳的热处理工艺。结果表明:900℃奥氏体化后风冷时钢的强塑性最好;在强塑性最佳时的微观组织是铁素体+粒状贝氏体。     

Microstructural Investigation of Protective and Non-Protective Oxides on 11% Chromium Steel

FIB, SEM and STEM/EDX were used to investigate X20 stainless-steel samples exposed to dry O₂, or O₂ containing 40% H₂O, with a flow velocity of 0.5 cm/s or 5 cm/s, for 168 hr or 336 hr at 600°C. Thin protective Cr-rich (Cr,Fe)₂O₃ was maintained on the samples exposed to dry O₂, even after 336 hr, and on the sample exposed to O₂/H₂O mixture with the low-flow velocity (0.5 cm/s) for 168 hr. The oxide scale formed in the latter environment contained less Cr, due to Cr loss through CrO₂(OH)₂ evaporation. Breakaway oxidation occurred on the samples exposed in high-gas-flow velocity for shorter time (168 hr) or in low-gas-flow velocity (0.5 cm/s) for longer time (336 hr). The breakaway scales featured a two-layered structure: an outward-growing oxide “island” consisting of almost pure hematite (α-Fe₂O₃), and an inward-growing oxide “crater” consisting of (Cr,Fe)₃O₄. The transition from a thin protective (Cr,Fe)₂O₃ scale to a non-protective thick scale on this martensitic/ferritic steel originated locally and was followed by rapid oxide growth, resulting in a thick scale that covered the whole sample surface.     

国内外不锈钢精炼剂研究发展现状

分析了精炼剂组元元素的作用能力，讨论并总结了精炼剂组元的复合作用，介绍了几种国内、国外精炼剂产品，提出发展高效复合精炼剂的想法。