复合材料的最新进展与应用

叙述了复合材料的发展概况 ,详细介绍了增强材料的种类、性能、形式及加工技术 ,指出了复合材料具有广阔的应用前景     

Ni-Al2O3纳米复合电镀工艺的初步研究

初步研究了复合电镀各工艺条件：电流密度、镀液pH值和温度以及搅拌方式对Al2O3纳米微粒在镍基复合镀层中含量的影响。研究表明：电流密度增大不利于提高镀层中纳米微粒的含量；pH值增大也明显使复合量降低;镀液温度升高，镀层中微粒的复合量随之略有改变；电镀时，加强搅拌或适当改变搅拌方式，可以使复合镀居中的纳米微粒含量提高。还利用扫描电镜及能谱对Ni-Al2O3镀层表面进行了观察与分析。     

陶瓷及陶瓷基复合材料微缺陷的超声检测

为研究陶瓷及陶瓷基复合材料微缺陷的超声检测能力，针对一些人工缺陷试样进行了超声检测试验。试验主要采用了纵波垂直入射法和泄漏瑞利波法。通过试验结果，比较了两种方法的检测能力。     

负载型复合载体及其镍基催化剂的性能

采用溶胶-凝胶法制备了负载型ZrO_2/Al_2O_3和ZrO_2/Al_2O_3-SiO_2复合载体,研究了不同复合载体对Ni基催化剂CO_2重整甲烷反应和性能的影响,并用XRD、IR、TPR、TPD和BET等方法对复合载体及催化剂进行了表征。结果表明,ZrO_2负载在基载体后比表面积、碱性、活性组分Ni的分散度和Ni与ZrO_2的相互作用增大。NiO在复合载体表面的分散容量与ZrO_2的负载量有关,ZrO_2的负载量为37．5%时NiO的分散容量达最高值(24．0%)。与Ni/ZrO_2相比,Ni/ZrO_2/Al_2O_3-SiO_2和Ni/ZrO_2/Al_2O_3催化剂对CO_2的吸附能力增大,CO_2吸附量增加,酸强度降低,CO_2重整CH_4反应活性提高,其中以Ni/ZrO_2/Al_2O_3催化剂的活性最好。     

中压蒸汽管道焊接质量统计分析及建议

中压蒸汽管道作为工厂的公用管网的组成部分,在生产中起着非常重要的作用,其主要用于压缩机蒸汽透平等关键工艺单元,除了对材料有特殊要求外,还要求运行可靠、管内高度洁净,因此对焊接质量提出了更高要求。结合齐鲁石化公司煤代油技术改造工程的中压蒸汽管道的施工,就焊接质量用统计分析的方法,对焊接产生的气孔、夹渣、未焊透等缺陷产生的原因及采取的控制措施进行了分析,并就今后的焊接质量控制提出建议。     

丝网气液分离器分离性能和压力损失分析

对丝网气液分离器的分离机理进行了详细分析,在此基础上给出了丝网气液分离器的分离效率和压降计算公式。与HG/T 21618-1998《丝网除沫器》中的公式相比,此公式可以用于任意组合的丝网结构,更具普适性,并且能定量分析各种分离机理对分离的贡献。对丝网式空气过滤器计算的结果表明,此公式具有很好的精度,可以用于工程设计。     

Cu基络合物催化甲醇液相氧化羰化反应

针对甲醇液相氧化羰基化法合成碳酸二甲酯(DMC)工艺,开发了新型Cu基络合催化剂(CuB rnLm)。对CuB rnLm催化剂的活性及其稳定性进行了研究。实验结果表明,采用该催化剂,甲醇转化率和DMC选择性较高;元素价态和物质结构分析表明,CuB rnLm催化剂循环使用5次后仍保持较好的稳定性。采用正交设计和中心响应曲面法设计实验,并使用S tatistica软件进行统计分析,寻求出反应的主要影响因素,并得到优化的工艺条件:反应温度100~110℃、反应压力3.0~3.5M Pa、反应时间4~6h、CuB rnLm催化剂质量浓度(以甲醇的体积计)0.15~0.20g/mL。在此工艺条件下,甲醇转化率可达23%以上,DMC的选择性为96%~98%。     

复合材料层合曲梁分层问题的解析解法

根据叠加原理将含有分层的复合材料层合曲梁在横向载荷作用下的受力状态分解为在面受力状态与出面受力状态,再将出面受力状态分解为无分层曲梁受横向载荷状态与含分层曲梁承受附加剪切载荷状态。将分层问题归结为在附加剪切载荷状态中,层合梁附加位移与附加应力的分析,并据此建立了一个简单的力学模型。最后得到了由分层引起的附加位移与应力的解析解答,并用能量释放率方法确定了应力强度因子。     

Improving Short-Circuit Current Capacity, Resistance, and Breaking Load of OPGW Constructions by Modifying Aluminium Alloy With AlB2

This article presents a method that can be applied to molten AA-6101 alloy to improve electrical properties of the aluminium part of the optical ground wire (OPGW) used in overhead transmission lines to protect phase conductors from lightning strike and to transmit signals and data. AA-6101 alloy in casting of the log as 6 m length and 178 mm diameter for extrusion has been inoculated by AlB₂ to decrease detrimental effects of Cr, Ti, V, and Zr on the conductivity of the material. After inoculation, improved billets were extruded as 9.5 mm diameter feedstock. Required wires drawn from the feedstock according to the construction types of OPGW to be tested were exposed to aging at 175°C, 6 h (T-8). Upon completion of the back-twist and performing-type stranding process, resistance, and short-circuit current capacity and breaking load of the OPGW 88/44 constructions with other metal combinations have been examined and tested to show improvement. Results are summarized in tables and graphically.     

Fatigue crack growth in SiC particulates reinforced Al matrix graded composite

The SiC/Al graded composite was fabricated by powder metallurgy processing and its fatigue crack growth behavior was studied. The volume percentage of SiC particulates was distributed from 5 to 30% layer by layer on the cross section. Since the aluminium was dissolved together, there was no evident interface between the two layers with different volume fraction of SiC particulates. Fatigue crack growth was in direction of from 5 to 30% SiC layers under sinusoidal wave-form. The retardation of fatigue crack growth was found when crack propagated from low volume fraction of SiC to high volume fraction of SiC. The crack deflection and branching between two layers were observed, which decreased crack growth rates. In view of crack tip driving force, the plasticity mismatch between the layers shielded crack tip driving force, i.e. decreased the effective J-integral at the tip of the crack as the plastic zone of the crack tip spread from the weaker material into the stronger material.