钾基地聚物防火涂料性能与陶瓷化研究

钢结构因具有多种优点而被广泛应用于工程建筑领域,但其在火灾高温环境下会丧失力学性能,造成结构失效,因此对钢结构进行防火保护成为关键。以偏高岭土、矿粉和憎水处理后的膨胀珍珠岩为主要原材料,模数为1.5的钾水玻璃为激发剂,制备非膨胀型钾基地聚物基防火涂料,并采用大板燃烧法研究该涂料在1 200 ℃下的防火性能;同时,对其在室温、1 000 ℃以及1 100 ℃热处理前后的力学性能、表观形貌、物相组成、微观结构演变进行了表征分析,探究地聚物在高温过程中的陶瓷化过程。结果表明:该防火涂料具有优异的防火能力,在1 200 ℃下进行2 h耐火极限试验后,钢板背面温度低于160 ℃;防火涂料在1 100 ℃高温热处理2 h后,抗压强度大幅增加至室温强度的5.8倍,达30.80 MPa;防火涂料基体的无定型地聚物相在800 ℃开始发生陶瓷化转变,1 100 ℃时生成的陶瓷相主要为钙长石、莫来石以及白榴石。     

聚氨酯掺杂铜粉涂层的电磁特征及其涂层织物的吸波性能

将掺杂了不同含量微米铜粉的聚氨酯（PU）涂料通过涂层工艺涂敷在棉织物上制成吸波涂层织物,并利用扫描电子显微镜、红外光谱和矢量网络分析仪等测试了不同铜粉含量聚氨酯涂层的介电常数、磁导率和电磁损耗等电磁性能,同时还探讨不同铜粉含量涂料对涂层织物电磁吸收性能的影响。结果表明,在 8~13 GHz 的频段范围内,随着涂层中铜粉含量增加,涂层介电常数实部与虚部均增大,铜粉具有良好的介电性能,在外加电场的作用下产生极化,对电磁波产生介电损耗;铜粉不属于磁损耗材料,对电磁波产生磁损耗较小;当铜粉的含量较低（3 %,质量分数,下同）时,涂层材料的吸波与电磁屏蔽性能较弱,当含量由5 %增加至11 %时,在9.0、10.5、12.8 GHz处反射损耗最低分别为-20.4、-28.3、-25.6 dB,有效吸收带宽分别为0.2、1.3、1.1 GHz,电磁屏蔽效能分别由12.24、16.59、21.1 dB增加至25.92 dB。     

钢丝帘布的剥离测试方法研究

针对钢丝帘布剥离测试结果的系统性不稳定情况,研究剥离力测试结果的影响因素。结果表明:利用夹持端包布提高夹持摩擦力不能改善剥离测试效果,反而导致试样水平端面硫化压力分布不均造成剥离力下降;帘布间敷贴带束胶片虽然能大幅提高剥离力,但从剥离后覆胶状态来看更多反映的是帘布间胶料的撕裂强度;剥离拉伸速率越大,胶料破坏方向越平直,剥离力有下降趋势;硫化时间太长导致的硫化返原可明显降低剥离力。     

Improving the flexural strength of porcelain by residual stress in anorthite coating

Flexural strength is an important parameter of domestic ceramics to meet the criteria for mechanized washing, filling, and sealing process in the automatic production line. In this work, the anorthite coating was prepared using calcite, silica, and alumina as raw materials. Taking the temperature with the highest matrix strength as the optimal temperature, the influences of chemical formulation on the phase composition and the coefficient of thermal expansion (CTE) of coatings were investigated. The enhancement effect of the coating with different formulations and surface number and thickness was compared. As a result, the flexural strength of the ordinary domestic ceramic body was improved due to the residual compressive stress in the coating caused by a mismatch of CTE between the coating and the matrix. At the optimal sintering temperature (1280°C), the coating with 20 mass% alumina addition has the best strengthening effect on the body, in which the thickness of the anorthite coating is approximately 50 µm and the flexural strength has increased by 64.6%, from 88 ± 4 to 144 ± 6 MPa.     

Laser pyrolyzed organosilazane-based Al/ZrO2 composite coating on stainless steel: Resulting microstructure and mechanical properties

Protective ceramic-based coatings are frequently the most suitable solutions for problems like corrosion and wear. It has been shown that the precursor technology is suitable for the preparation of ceramic coatings by pyrolysis in a furnace. However, the required high temperature for the preparation of the ceramic coatings limits this approach to high temperature-resistant substrates. A very innovative approach to overcome this restriction is the use of laser radiation as a thermal source for the pyrolysis of the preceramic polymer. In this paper, we report on a coating system, for steel substrates, consisting of a polysilazane (Durazane 2250) bond coat and a hard and dense top-coat composed of an organosilazane (Durazane 1800) with tetragonal ZrO₂ particles and aluminum flakes as fillers pyrolyzed using Nd:YVO₄ laser. The aluminum fillers led to a significant increase in absorption of the laser energy leading to the formation of a dense coating with a thickness up to 20 μm and a mainly cellular/columnar-dendritic microstructure. The microstructure, mechanical, and tribological behaviors of these composite coatings are reported and compared to those of laser pyrolyzed glass/ZrO₂-filled polysilazane-based coatings reported in the literature.     

Effect of alloying element on microstructure,mechanical property,and oxidation resistance of Zr─Me─C (Me═Si/Y) coatings

Accident-tolerant fuels (ATFs) are proposed to provide improved safety response to a loss of coolant accident (LOCA) scenario while maintaining good operational characteristics under normal conditions. In this work, Zr─Me─C (Me═Si or Y) was proposed as candidate coatings for ATF applications. The influence of Si and Y with varied concentration on microstructural evolution, mechanical property, and oxidation resistance of Zr─Me─C coatings were investigated. Based on combined results of X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy, it was found that Si or Y doped ZrC_0.55 coatings presented tunable composition and microstructure. Improved air oxidation and spallation resistance were achieved with the incorporation of Me atoms, attributing to the formation of SiO₂ and ZrSiO₄ and/or the stabilization of zirconia. Under a simulated LOCA condition, decreased weight gains of 13.6 at.% Si and 22.5 at.% Y coated Zry-4 alloys were achieved. nc-ZrSiC/nc-ZrSi (13.6 at.% Si) coating exhibited enhanced mechanical property and oxidation resistance in both high-temperature air and LOCA conditions, which could be regarded as potential candidate for the applications in ATFs.     

The effect of substrate surface integrity on the surface properties of TiCrN coating applied via the CAE-PVD method

This study aims to investigate how the predeposition machining processes such as magnetic grinding, turning machining, and wire electrical discharge machining can influence the surface properties including electrochemical and tribological behavior of TiCrN nanostructured coating applied on Mo40 steel substrate. A physical vapor deposition technique using cathodic arc evaporation was used to apply the coating. The crystallographic phases and the microstructure of the coating were studied by X-ray diffraction and scanning electron microscope, respectively. Rockwell-C, electrochemical impedance spectroscopy and potentiodynamic polarization, and pin-on-disk wear tests were employed to evaluate the adhesion strength, corrosion behavior, and tribological property of specimens, respectively. The electrochemical results after 24 h of exposure to 3.5 wt% NaCl solution showed that TiCrN coating pretreated with a turning process with polarization resistance of about 3525.32 Ω.cm² had the best corrosion resistance among all specimens. This was because of the improvement of the smoothness, surface quality, and adhesion after the turning process. On the other, the friction coefficient of the grounded sample is less than that of other ones. This is probably due to its higher adhesion strength and higher surface smoothness.     

活塞顶面热障涂层对活塞热负荷的影响

活塞顶面热障涂层可以有效降低活塞工作热负荷、提高活塞使用寿命。以一款非道路高压共轨柴油机铝合金活塞为研究对象,采用硬度塞测温法试验测试了无热障涂层活塞在最大转矩工况下表面19个特征点的温度值,同时采用等参法建立了活塞有限元仿真分析模型,对比分析了活塞顶面热障涂层对活塞温度场和热应力场的影响。研究结果表明：活塞顶面热障涂层能有效降低活塞头部和环槽区域的工作温度,活塞头部顶面区域温度下降幅度为20~32 ℃,一环和二环的环槽区域温度下降幅度为15~18 ℃;但活塞顶面采用热障涂层后,活塞基体顶面黏结层区域的热应力会急剧升高,活塞基体顶面、喉口区域以及边缘棱角处热应力集中现象明显,在活塞顶面喉口黏结层区域最大热应力达到291MPa,易导致热障涂层的剥落失效。     

分段压裂可降解涂层球座密封设计

针对分段压裂可降解球座在井下环境中易自行降解使密封时间较短的问题,基于发明问题解决理论(TRIZ)技术冲突解决原理提出一种涂层球座锥面的创新设想,采用热喷涂工艺在可降解球座锥面制备耐降解金属涂层;应用Pro/E软件建立可降解球及球座相接触的三维几何模型,应用ANSYS软件对可降解涂层球座进行有限元仿真分析,并对可降解球座涂层锥面进行承压性能试验。仿真结果表明:可降解球的接触应力集中区域主要位于球座接触密封的涂层锥面,在接触面上的接触应力最大,最大应力值为205 MPa,并向两侧递减。试验结果表明:可降解球与球座涂层锥面可形成良好的密封系统,并且具备50 MPa承压性能。