水包油型多彩涂料的生产及施工

介绍了水包油型多彩涂料的组成、各组份的作用、生产工艺路线和工艺参数的选择。对多彩涂料的施工机具和方法作了简单介绍。     

红外隐身技术的现状与发展

综述了红外隐身技术的现状，指明了存在的问题以及发展的方向。     

粉末涂层抗冲击缺陷分析

讨论了粉末静电涂装中出现的涂层抗冲击试验缺陷，通过设计实验寻找造成该缺陷的原因，揭示了产生涂层起皱和脱离基材的原因是钢板与磷化液之间的匹配性差。通过提高磷化液的游离酸酸度解决了该问题。从理论上推出了游离酸与附着力之间可能的关系：游离酸影响磷化膜与基材的结合力，或影响形成的磷化膜的形态。     

Stabilization of bioethanol recovery with silicone rubber‐coated ethanol‐permselective silicalite membranes by controlling the pH of acidic feed solution

In order to produce highly concentrated bioethanol by pervaporation using an ethanol‐permselective silicalite membrane, techniques to suppress adsorption of succinic acid, which is a chief by‐product of ethanol fermentation and causes the deterioration in pervaporation performance, onto the silicalite crystals was investigated. The amount adsorbed increased as the pH of the aqueous succinic acid solution decreased. The pervaporation performance also decreased with decreasing pH when the ternary mixtures of ethanol/water/succinic acid were separated. Using silicalite membranes individually coated with two types of silicone rubber, pervaporation performance was significantly improved in the pH range of 5 to 7, when compared with that of non‐coated silicalite membranes in ternary mixtures of ethanol/water/succinic acid. Moreover, when using a silicalite membrane double‐coated with the two types of silicone rubber, pervaporation performance was stabilized at lower pH values. In the separation of bioethanol by pervaporation using the double‐coated silicalite membrane, removal of accumulated substances having an ultraviolet absorption maximum at approximately 260 nm from the fermentation broth proved to be vital for efficient pervaporation. Copyright © 2005 Society of Chemical Industry     

n-Al2O3P/Ni复合刷镀层的组织和摩擦磨损特性

研究了镍基纳米Al2O3复合电刷镀层（n-Al2O3^p/Ni）的组织特征及擦磨损特性，并与快镍刷镀（Ni)进行了比较。结果表明：n-Al2O3^p/Ni复合刷镀层表面粗糙度更小，组织更致密，镀层摩擦系数随镀液中纳米粒子含量增加稍有增大；n-Al2O3在复合刷镀层中弥散分布，与基相良好结合；复合镀的耐磨性能明显优于Ni刷镀层，镀液中n-Al2O3含量为20g/L时，复合刷镀层具有最佳耐磨性能。     

宽带激光熔覆WCP/Ni基合金梯度复合涂层组织与摩擦磨损特性

研究了铸造WC_P/Ni基合金梯度复合涂层组织与摩擦磨损特性。结果表明,梯度复合涂层与基材实现了良好的冶金结合,涂层内有γ-Ni枝晶组织,γ-Ni＋M₂₃C 6共晶组织以及凝固结晶析出的M₆C、M₂₃C₆、M₇C₃等块状或条状组织;随着铸造WC_P体积分数的增加,复合涂层摩擦系数减小,耐磨性增加。19-4试样的耐磨性最高值为4.61,是基材的3倍以上。梯度涂层的磨损机理为磨粒磨损与粘着磨损的复合作用。     

Determination of Discrete-Structure Parameters of Coatings with Allowance for Residual Stresses

The authors suggest that the dimensions of a discrete section of a coating should be chosen on the basis of calculation of the critical crack spacing in cohesion cracking. This approach allows for residual stresses in the coating. The reliability of the calculation method has been verified experimentally by direct measurement of the crack spacing.     

薄膜包衣技术及应用

对薄膜包衣技术及其在制剂生产中应用的研究进展作一综述。     

Synthesis and Evaluation of Blends Formed by Polymeric Crown Ethers and a Fullerene-Containing Primary Ammonium Salt in Organic Thin Films

The synthesis of a series of polymers and cyclopolymers bearing crown ethers of differing structure and affinities towards primary ammonium ions is discussed. These polymers have been tested in their efficiency to form structurally homogeneous thin films when blended with an amphiphilic C₆₀ compound containing a primary ammonium ion functional group. The X-ray reflectivity characterization of the films revealed that the polymer bearing the crown ether with the least affinity for primary ammonium ions, but having the highest degree of polymerization, is the most effective in forming structurally homogeneous thin films.