核电厂小型承压容器泄漏率直读的可行性分析

对比气体泄漏率的精确计算值与直读值的差异,分析误差的成因并找出切实可行的缩小误差的方法,使得直读法在小型承压容器的大批量泄漏率检测中发挥了重要的作用。     

黄河水水质配方实验及其应用

该文通过水质调查和大量实验数据，对循环水改为黄河水质运行的配方进行了筛选，并提出了自然ｐＨ全有机配方的概念，通过监测数据，对黄河水配方运行情况进行了总结，该配方投用后，不但能节约地下水资源，而且经济效益显著。     

大理地区烤烟陈化过程中有机酸含量变化研究

使用衍生化-气质联用方法研究了大理地区烤烟连续陈化4年其有机酸变化。结果表明,烤烟在陈化过程中,①非挥发酸在6到18个月内含量明显降低,18到30个月内变化减缓,30到48个月内下降又加快,非挥发酸总量与苹果酸含量线性相关;②半挥发酸随陈化时间延长呈缓慢下降趋势;③挥发酸总量在6到24个月的陈化时间内明显增加,24到36个月内保持不变并略有下降,36到48个月内基本呈下降趋势,挥发酸总量与异戊酸含量线性相关。     

利用厌氧折流反应系统进行有机废水发酵制氢

以厌氧折流形式的发酵生物制氢反应器进行了连续流有机废水发酵产氢试验研究。反应器由有机玻璃制成,三格室,单格有效容积9.16L。以好氧生物处理系统剩余污泥为种泥,在容积负荷为8.89kg COD·(m~3·d)~(-1),水力停留时间为13.5 h,温度(35±1)℃等条件下,系统启动运行25 d后达到稳定运行状态。系统稳定运行时,总产气量和产氢量分别稳定在59.0 L·d~(-1)和32.0 L·d~(-1)左右。其中,第一格室、第二格室和第三格室的平均产气量及其氢含量分别为14 L·d~(-1)、25 L·d~(-1)、20 L·d~(-1)和50％、60％、50％。系统污泥的比产氢速率为76.64 L·(kg VSS·d)~(-1)。与同类生物制氢反应器相比,厌氧折流发酵生物制氢反应器具有结构简单、运行稳定、操作灵活、容积利用率高、生物持有量高以及运行费用较低等优点,在发酵生物制氢技术领域有很好的开发前景。     

有机化合物及聚合物的计算机辅助红外光谱法鉴定

建立了计算机辅助红外光谱法鉴定有机化合物及聚合物的新方法,介绍了计算有机化合物和聚合物的一些经验公式。程序设计首先收集、整理常用聚合物、有机添加剂和有机小分子的红外光谱数据,然后提取反映该物质特征的吸收峰数据,制作ACCESS数据库,利用VisualBasicDAO数据链接方式,根据查询要求动态链接数据库,利用要求查询的聚合物特性,经过经验公式的算法翻译,生成SQL查询语句进行查询。     

异相结/异质结TiO2光催化机理及降解有机物的研究

到目前为止TiO2是较为成熟的半导体光催化材料，但因TiO2分散性差、量子利用率低、比表面积小、难回收等问题难以工业化。多孔金属有机框架MOFs的引入可增强TiO2/MOFs复合材料的光吸收性能，提高电子-空穴对分离和提高回收率。基于TiO2/MOFs制备时前驱体添加顺序不同，综述了TiO2/MOFs的三种制备方法（即Ship-in-a-bottle法、Bottle-around-ship法、One-pot法）及TiO2/MOFs光催化机理与性能影响因素，并探讨不同MOFs与TiO2结合的作用机理。最后，对TiO2/MOFs存在的问题提出建议。     

2,4-二氯-3-乙基-6-硝基苯酚的合成

介绍了以对硝基乙苯为原料 ,经三氯异氰脲酸氯化反应、碱解反应和酸化反应 ,高纯度 (大于 99% )、较高收率和较低成本地合成了目的产物的方法。该方法具有氯化试剂的投料量易于控制和反应控制简便等优点     

Protective properties of organic phosphate-pigmented coatings on phosphated steel substrates

Investigations have been carried out on properties of coatings, differing by their pigmentation and binder, and applied on different chemical pre-treatments of the steel surface. Paints based on alkyd and alkyd-melamine binders, pigmented with zinc phosphate and modified basic zinc phosphate were applied on amorphous and crystalline phosphated steel surface and, for the comparison purpose, on degreased steel surface. The effect of the binder, the pigment and the pre-treatment of the steel surface on the protective properties of the coatings were determined by measurements of adhesion, water absorption and water permeability and by results obtained in salt spray and Prohesion tests. Coatings based on alkyd binder show a lower damage degree and good retention of adhesion in corrosion conditions, in spite of a higher water absorption and water permeability and a lower initial adhesive strength. Protective properties of coatings have been found to be highly dependent upon the substrate pre-treatment. Chemical pre-treatment of the steel substrate increases the protective properties of the system, which is particularly evident in the case of crystalline phosphating and the coating pigmented with modified basic zinc phosphate. This phenomenon can be explained by the synergism between this phosphate pigment with crystalline phosphate layer.     

Variability of light absorption properties in optically complex inland waters of Lake Chaohu,China

Absorption coefficients of phytoplankton, colored detrital matter (CDM), non-algal particles (NAP), colored dissolved organic matter (CDOM), and their relative contributions to total non-water absorption (a_t ? w) are essential variables for bio-optical and radiative transfer models. Light absorption properties showed large range and variability sampled at 194 stations throughout Lake Chaohu between May 2013 and April 2015. The a_t ? w was dominated by phytoplankton absorption (a_ph) and NAP absorption (a_d). The contribution of CDOM absorption to a_t ? w was lower than 30%. Phytoplankton and NAP were the primary sources of spatial and vertical variability in absorption properties. Light absorption by CDOM, though significant in magnitude, was relatively constant. CDM absorption (a_dg) was dominated by NAP. The spatial variation of the absorption coefficients from each of the optically active constituents were driven by several main inflow rivers in the western and middle part of Lake Chaohu. Algal blooms and bottom resuspension contributed to vertical variability as observed by phytoplankton and NAP profiles. Specific absorption of phytoplankton had significant spatial and seasonal variations without vertical variation. The spectral slope of absorption showed no significant spatial variability (p > 0.05). Variations of absorption affected different ranges of remote sensing reflectance (R_rs) spectrum, thereby increasing the difficulty of applying the remote sensing algorithm in optically complex waters. Parameters and relationships presented in this study provide useful information for bio-optical models and remote sensing of lakes similar to Lake Chaohu in terms of optical properties.