铝蜂窝负载锰基催化剂的制备及其在室温下去除低含量甲醛的性能

采用水热共沉淀法和原位氧化还原法制备MnO_x/MgAl类水滑石(Mg₃Al₁-LDHs)催化剂,以水玻璃作为黏结剂将其负载到铝蜂窝上,用于室温下去除甲醛。通过X射线衍射(XRD)、热重分析(TG)、X射线光电子能谱(XPS)、N₂吸附-脱附、傅里叶变换红外光谱(FT-IR)等手段进行表征。表征结果表明：MnO_x/Mg₃Al₁-LDHs具有典型类水滑石结构,大量结合水和羟基; MnO_x为δ-MnO₂和Mn₃O₄的混合物,具有高比例Mn⁴⁺/Mn³⁺和丰富的吸附氧。实验结果表明：室温(25 ℃,相对湿度60%)下反应4 h后,MnO_x/Mg₃Al₁-LDHs催化剂可将甲醛质量浓度由1.30 mg/m³降至0.10 mg/m³以下,且经过8次和连续15 d实际测试,表明催化剂具有良好的稳定性和甲醛去除效果。MnO_x/Mg₃Al₁-LDHs催化剂最佳负载量(质量分数)为5%,风扇最佳功率为10 W,空气中湿度对甲醛去除效果影响较小,该催化剂具有较强水分抵抗能力,反应温度提升会较大程度提高甲醛去除效果。     

环氧类玻璃高分子材料的热回收性能研究

采用动态交联技术制备了环氧类玻璃高分子材料（EPV）,将其制得的片材在不同模压条件下进行重复加工,考察了模压温度、模压时间和模压压力对EPV回收材料性能的影响。结果表明：重复加工没有造成EPV回收材料的降解;模压温度越高,模压时间越长,模压压力越大,越有利于EPV的愈合和重塑;在模压温度为180℃,模压压力为20 MPa,模压时间为10 min的较佳条件下,重复加工的EPV回收材料力学性能与初始EPV片材的接近。     

Study of filtered interphase heat transfer using highly resolved CFD–DEM simulations

Accurately predicting the complex inhomogeneous heat transfer behavior in gas–solid fluidized beds is of fundamental importance. In this work, we constitute an enhanced filtered interphase heat transfer coefficient (IHTC) closure by systematically filtering the dataset from highly resolved three-dimensional (3D) computational fluid dynamics–discrete element model simulations. Particularly, effects of several potential filtered variable markers on filtered IHTC predictions are examined by statistical analysis. We reveal the formulated filtered IHTC correction closure manifests a systematic dependence on filtered interphase temperature difference as an additional marker. The proposed closure shows good agreement with the filtered fine-grid simulation data in an a priori analysis. Moreover, the difference of filtered IHTC corrections deduced from 3D Euler–Euler and Euler–Lagrange simulations is quantified. Finally, the comparative analysis between our proposed filtered IHTC formulation and those in literature is implemented. This work holds a potential to facilitate the development of thermal gas–solid flow modeling.     

Full color white light,temperature self-monitor,and thermochromatic effect of Cu+ and Tm3+ codoped germanate glasses

Lighting sources with full-color visible output are widely preferred in practical applications. In addition, modern lighting sources also tend to be intelligentized, and the intelligentization asks for smart luminescence materials. In this work, we attempt to develop novel full-color emitting material with temperature sensing and thermochromatic ability. To this end, the Cu²⁺ is successfully reduced to Cu⁺ which is incorporated into the germanate glasses. The glasses are prepared via a melt-quenching technique using graphite powders as reducing reagent. The supper-broadening of the excitation and the emission spectra of Cu⁺ in the germanate glasses are observed. Full-color emission is realized by introducing Tm³⁺ as co-dopant to provide the blue component in the spectra. The energy transfer behavior between Cu⁺ and Tm³⁺ is investigated, and it is found that these two luminescence centers are independently existent without energy transfer between them. The chromatic properties of the Cu⁺/Tm³⁺ co-doped glasses are tuned by Tm³⁺ concentration and excitation wavelength. The temperature sensing based on the fluorescence intensity ratio technique is demonstrated, and a constant sensitivity for the temperature detection is obtained. Moreover the thermochromatic property is also investigated, and it is found that the studied Cu⁺/Tm³⁺-doped glasses exhibit excellent thermochromatic performance.     

Sintering parameter optimization of Tb3Al5O12 magneto-optical ceramics by vacuum sintering and HIP post-treatment

Transparent terbium aluminum garnet (TAG) ceramics were achieved by the vacuum sintering plus HIP post-treating from the coprecipitated TAG nanoparticles. The influences of vacuum sintering temperature and sintering aid TEOS on the optical quality of the TAG ceramics were studied. The results show that with the increase of sintering temperature, the optical quality of TAG ceramics is improved gradually, and the in-line transmittance of the TAG ceramics treated at 1720°C for 20 hours under vacuum and then HIP post-treated at 1700°C for 3 hours under 200 MPa argon gas is 81.6% at 1064 nm. The sintering additive TEOS can improve the optical quality of TAG ceramics and inhibit the valence state change of Tb³⁺ ions to Tb⁴⁺ during the annealing process. The Verdet constant of the TAG ceramics at 632.8 nm is about −178 rad·T⁻¹·m⁻¹ at room temperature, which is 1.3 times that of the commercial TGG crystals (−134 rad·T⁻¹·m⁻¹).     

Long-term effect of diesel degradation on polyoxymethylene at different temperatures

Diesel is an important fuel, partly because of the longevity and cleanliness of diesel engines. Often, polymers are in direct contact with diesel and understanding compatibility is critical. Polyoxymethylene (POM) is a thermoplastic used to manufacture automotive fuel pump gears and rotors due to its low coefficient of friction and thermal and dimensional stability. In this study, tensile tests were performed on plain and glass fiber reinforced (POM and POMGF) after immersion in diesel at different temperatures (−10°C, 23°C, and 60°C) for 1000, 2000, 3000, 5000, and 10 000 hour. A mathematical model was developed using data from just three tensile stress-strain curves obtained at two different fluid temperatures and three different immersion times. Model and experimental results show good agreement with one another for all conditions tested.     

Effect of tacticity of poly(methyl methacrylate) on interfacial region with silica in polymer nanocomposite

The effect of tacticity on the interfacial region between poly(methyl methacrylate) (PMMA) and silica in a PMMA/silica nanocomposite was investigated by differential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The glass transition temperature (T_g) values of the syndiotactic (st-) and atactic (at-) PMMA/silica nanocomposites are higher than those of the neat PMMA. Conversely, the T_g of the isotactic (it-) PMMA/silica nanocomposite is slightly higher than that of the neat it-PMMA. DSC and XRD results suggest that the restriction of the PMMA chain mobility in the silica nanoparticle interfacial region heightens as the syndiotactic content increases. FT-IR results show that this phenomenon is caused by the interaction between the carbonyl group of PMMA and the silanol group on the silicon dioxide surface. Therefore, it can be concluded that the syndiotactic-rich PMMA has a significantly different molecular mobility from that of the neat PMMA in the interfacial region with silica nanoparticle surface than isotactic-rich PMMA.     

Influence of nucleation and growth mechanisms on the heat deflection temperature of a reactively processed polypropylene nanocomposite

The development of a reactively processed polypropylene nanocomposite (PPNC) with consequential improvements in the heat deflection temperature (HDT), Vicat softening temperature (VST), and crystallization peak temperature (T_c) is reported herein. Neat PP without nanoclay was also reactively processed to elucidate the effects of fillers on the improvement in physical properties. The results show a considerable improvement in the HDT of PPNC (77.9 °C) compared to those of neat PP (62.6 °C) and reactively processed branched PP (BPP; 69.2 °C). Moreover, the T_c of PP in PPNC improved by ~14% compared to that of neat PP. Various models of nonisothermal crystallization kinetics were employed to elucidate the nucleation and crystal growth mechanisms, and to correlate them with the observed HDT improvement in PPNC. Thermal transitions investigated by modulated differential scanning calorimetry explained the changes observed in the VSTs of all the samples. To the best of our knowledge, this is the first report on a significant improvement in HDT along with a marked increase in Tc. Such simultaneous improvements in HDT, VST, and T_c are highly desirable for applications involving the use of PP-based materials in rigid packaging.     

探空温度传感器误差预测技术研究

随着气候诊断、气候变化、天气预报等学科的深入开展,对探空温度传感器的测量精度提升到了 0. 1 ℃ 的量级要求,而 由于太阳辐射、升空速度、入云出云等因素的干扰,引起的测量误差可达 3℃甚至更高,已成为制约气象探测精度提升的主要障 碍。 针对此问题,首先通过三维建模及流体力学分析,得到了温度传感器最优的设计方案,从传感器形态设计上实现了测量误 差最小化。 然后对历史气象探测数据进行分析和汇总,构造出国内首个基于真实环境的、包含 900 000 条探测记录的高空气象 探测数据集,以解决仿真环境与真实环境存在偏差的问题。 最后,将 Morlet 小波作为深度神经网络的激活函数,并将支持向量 机、XGBoost、深度神经网络、线性回归相融合,构造出一个针对探空温度传感器测量误差的预测模型。 经过本文所提出的误差 预测模型,平均误差从 0. 817 降低到了 0. 008,均方误差从 0. 878 降低到了 0. 068,标准差从 0. 458 降低到了 0. 204,拟合系数 R 2 为 0. 93,使温度传感器的测量精度得到显著提升,更有利于气象学科相关内容的展开。     

Experimental investigation on evaporation interface temperature and evaporation rate of water in its own vapor at low pressures

Evaporative phase transitions are widely present in industrial production and daily life such as thin film processes and crystal growth. The evaporation of the liquid layer and the thermocapillary convection affect each other and restrict each other, making the energy transfer mechanism of the evaporation interface very complicated. To understand the evaporation characteristics of water in its low-pressure pure vapor environment, a series of experimental studies were carried out on the temperature distributions and evaporating rate of water evaporation in the annular pool. The cylinder temperature of the annular liquid pool is controlled between 3℃ and 15℃, and the evaporation environment pressure ranges from 394 Pa to 1467 Pa, when the temperature measurement starts, the depth of water is 10 mm. The results show that the temperature of the vapor side on the liquid-vapor interface is higher than that of the liquid side and there is an obvious temperature jump across the vapor-liquid interface. With the decrease of the pressure ratio, the evaporation rate increases, and the interface temperature jump is enlarged. Meanwhile, with the increase of the distance from the cylinder, the local evaporation rate decreases, thus, the temperature jump decreases. At the same pressure ratio, as the cylinder temperature increases, the heat flux from vapor side decreases, the temperature jump decreases at all measurement points. Within the experimental controlled parameters, the maximum temperature jump obtained in the measurements is 2.56℃. Due to the coupling effect of evaporation cooling and thermocapillary convection, there is a uniform temperature layer with a thickness of about 2 mm under the evaporation interface. The thickness of the uniform temperature layer near the cylinder is always larger than that in the middle of the evaporation interface. In the uniform temperature layer, the thermocapillary convection induced by radial temperature gradient transfers heat from the cylinder to the liquid-vapor interface to compensate for the latent heat of evaporation. Below the uniform temperature layer, the temperature rises rapidly due to heat conduction and buoyancy convection.