高砂比压裂技术研究

应用由美国ＮＳＩ公司引进的“ｓｔｉｍｐｌａｎ”拟三维压裂设计软件，对影响裂缝内支撑剂铺置浓度的诸因素进行了灰色关联度分析，从中找出了主要的影响因素。并以高砂比压裂的技术指标为依据，研究了在目前压裂工艺水平下，进行高砂比压裂所必须遵循的原则。文中还对国内的高砂比压裂进行了实例分析，进一步论证了文中的观点。     

特征线法分析长距离输油管道的流动瞬变过程

本文建立了基于特征线方法求充动瞬变过程的数值模型，编制了针对长距离输油管道流动瞬变过程的分析软件。在数值处理上，Ｄａｒｃｙ＝Ｗｅｉｓｂａｃｈ摩擦力项用二阶精度格式来近似，因此保证了高粘度流体在流动瞬变过程分析时的计算稳定性和精确度。模型考虑了埋管地形对沿线瞬变压力的影响，当某一泵站发生水击后其它站的反应同其上控程序确定。应用该软件，分析模拟了某一长距离输油管道在中间泵站停电或末站瞬时关阀情况下的流     

Enantioseparation of catechin and epicatechin in plant food by chiral capillary electrophoresis

The enantiomers of catechin and epicatechin were separated by chiral capillary electrophoresis using modified cyclodextrins as chiral selectors. Various conditions for the separation system were optimized, including the pH value and the concentration of the running buffer. A baseline separation of the catechin and epicatechin enantiomers could be achieved by using 0.1 mol l⁻¹ borate buffer (pH 8.5) with 12 mmol l⁻¹ (2-hydroxypropyl)-γ-cyclodextrin as chiral selector, a fused-silica capillary with 40 cm effective length (75 μm I.D.), +18 kV applied voltage, a temperature of 20 °C and direct UV detection at 280 nm. The method was applied to different plant food samples. (+)-Catechin and (−)-epicatechin could be verified as the most common flavan-3-ols. In the case of guaraná, however, we were able to identify all four enantiomers, both (+)- and (−)-catechin and (+)- and (−)-epicatechin, as naturally occurring compounds. This finding was verified by further isolation and purification of the flavan-3-ols and subsequent LC–MS analysis. This method allows for the identification of the authenticity of guaraná through the analysis of the catechin and epicatechin enantiomers, additionally to the conventional methods like HPLC.     

A new environmental friendly method for the preparation of sugar acids via catalytic oxidation on gold catalysts

A novel and efficient way of producing of aldonic acids is reported. The selective catalytic oxidation of monosaccharides (arabinose, ribose, xylose, lyxose, mannose, rhamnose, glucose, galactose, N-acetyl-glucosamine) and disaccharides (lactose, maltose, cellobiose, melibiose) on Au, Pd and Pt catalysts was investigated. By using the gold catalyst, a total selectivity with respect to aldonic acids and a high catalytic activity for all investigated sugars was found. The reaction conditions for the production of maltobionic and lactobionic acids via oxidation on gold catalysts were optimised. A high long-term stability of two different gold catalysts for the oxidation of maltose and lactose, respectively, was found.     

MOS结构准静态测试中的异常C—V曲线

本文报导了MOS结构在准静态测试中的异常电容-电压曲线。讨论了它们产生的原因。     

葛洲坝电站2号水轮机转轮室中环修复

针对葛洲坝电站2号机组运行中出现转轮室中环损坏的现象,设计制造出转轮室现场机加工的大型专用机床,在修复改造过程中,解决了一系列技术难题,改造后技术指标均达到理想水平,为电站机组现场修复技术积累了宝贵经验.     

塔式烘干中心干燥控制系统采样数据的实时性

传统的干燥控制系统思维方式是把干燥流程看成是一个大的惯性场，以惯性的形态看待与过程相关的数据，对输入参数的过程实时性很少研究，这样的结果就是控制准确性、精确度与实际过程的吻合程度较差。拟从干燥系统输入体系的结构入手，采用时序分析的手法对入粮到干燥的传输时序进行解析，推理出动态实时数据模型。     

Partial oxidation of methane towards hydrogen production over a promising class of catalysts: Rh supported on Ti-modified MgO

The partial oxidation of methane over the supported Rh (0.8 wt.%) catalysts was investigated. Two kinds of supports were used, MgO and Ti-modified MgO (prepared by grafting technique). Among the Ti-modified MgO supports, two different compounds were used as source of Ti: inorganic (chloride) and organic (alkoxide). The catalytic performance of Rh-supported catalysts depends on the support and varies in the sequence: Ti-MgO/I > Ti-MgO/O > MgO. Ti-containing catalysts exhibited higher activity and selectivity compared to MgO, which is especially noticeable at low temperature. Possible explanations for the phenomena observed were proposed on the basis of characterization results.     

PDC钻头在胜利油田深井钻井中的应用

胜利油田为提高深井钻井速度，试验应用了PDC钻头，结果表明，深井钻井应用PDC钻头可大幅度提高机械钻速，缩短建井周期，降低钻井成本，经济效益明显。通过大量的现场试验，扩大了PDC钻头在胜利油田的使用范围，并取得很好的效果，初步形成了PDC钻头推广应用区域模式。详细介绍了胜利油田不适用PDC钻头钻进的地层岩性，给出了钻头选型及钻井参数选择原则，并对应用效果进行了分析。