中空纤维超滤膜去除乳酸钙中蛋白质的研究

发酵法联合生产乳酸-乳酸钙工艺中,分离出的乳酸钙产品含有蛋白质、还原糖、重金属等杂质,影响产品的品质。本实验研究了中空纤维膜对乳酸钙中蛋白质的去除,并分析了压差、温度、浓度及pH值等因素的影响。得到了较好的工艺操作条件为Δp=0.05MPa,Δ=30g/L,30°C,pH=4。进一步提出用多步超滤能提高蛋白质的去除率15%～27%。     

建筑外墙涂装的施工质量控制

对建筑外墙涂装施工的质量问题进行了分析,提出了有关施工质量控制的方案和建议。     

改良MEA脱碳技术在小氮厂变换气脱碳中的应用

介绍了改良MEA脱碳技术的基本原理、工艺特点以及在工业中的应用情况，实践表明，改良MEA提高了溶液的吸收能力，降低了再生热耗，解决了MEA易降解损耗等问题。     

A2O工艺缺氧生物磷去除

A lab-scale anaerobic-anoxic-oxic （A^2O） process used to treat a synthetic brewage wastewater was investigated. The objectives of the study were to identify the existence of denitrifying phosphorus removing bacteria （DPB）, evaluate the contribution of DPB to biological nutrient removal and enhance the denitrifying phosphorus removal in A^2O bioreactors. Sludge analysis confirmed that the average anoxic P uptake accounted for approximately 70% the total amount of P uptake, and the ratio of anoxic P uptake rate to aerobic P uptake rate was 69%. In addition, nitrate concentration in the anoxic phase and different organic substrate introduced into the anaerobic phase had significant effect on the anoxic P uptake. Compared with conventional A^2O processes, good removal efficiencies of COD, phosphorus, ammonia and total nitrogen （92.3%, 95.5%, 96% and 79.5%, respectively） could be achieved in the anoxic P uptake system, and aeration energy consumption was saved 25%. By controlling the nitrate recirculation flow in the anoxic zone, anoxic P uptake could be enhanced, which solved the competition for organic substrates among poly-P organisms and denitrifiers successfully under the COD limiting conditions. Therefore, in wastewater treatment plants the control system should be applied according to the practical situation to optimize the operation.     

载锰氮化碳催化臭氧法降解水中草酸研究

草酸是废水中多种有机物氧化降解的中间产物,与臭氧反应速率很低,难以直接氧化去除。本研究通过热解法煅烧不同摩尔比例的三聚氰胺与醋酸锰(Ⅲ)二水合物,制备出不同负载量的载锰氮化碳催化剂,并研究了不同条件下载锰氮化碳催化臭氧法对草酸的降解效果,考察三聚氰胺与醋酸锰摩尔比、催化剂投加量、p H值、臭氧浓度等因素以及叔丁醇对草酸去除效果的影响。实验结果表明:相对于单独臭氧氧化而言,载锰氮化碳催化臭氧法可以极大的提高草酸的去除率,在投加0.15 g/L三聚氰胺与醋酸锰20∶1的催化剂后,草酸在60 min的TOC去除率可达到89.1%。叔丁醇加入对草酸的去除率影响较小,表明·OH在载锰氮化碳催化氧化草酸的过程中起作用但不是唯一因素。     

Absorption of carbon dioxide in alkanolamines in the presence of fine activated carbon particles

The rates of absorption of CO₂ into water and 0.1 kmol/m³ aqueous solutions of MEA, DEA and AMP were measured in a stirred cell with a flat gas-liquid interface in the presence of fine activated carbon particles. Experiments showed that the rates of absorption increased significantly with increases in the loading of activated carbon up to about 6 kg/m³ and thereafter remained constant.     

环氧酯底漆的研制

介绍了用环氧树脂、脂肪酸、干性油、季戊四醇、邻苯二甲酸酐制成的气干型环氧酯底漆。讨论了各种因素对树脂、涂料性能的影响。     

Influence of anode material on the electrochemical oxidation of 2-naphthol: Part 2. Bulk electrolysis experiments

The electrochemical oxidation of 2-naphthol has been studied by galvanostatic electrolysis, using a range of electrode materials such as lead dioxide, boron-doped diamond (BDD) and Ti-Ru-Sn ternary oxide anodes. The influence of some operating parameters, such as current density, flow-rate and chloride concentration on naphthol oxidation has been investigated in order to find the optimum experimental conditions. Measurements of chemical oxygen demand, HPLC and total organic carbon have been used to follow the oxidation. The experimental data indicate that on PbO₂ and BDD, naphthol oxidation takes place by reaction with electrogenerated hydroxyl radicals and is favoured by low current density and high flow-rate. On the contrary, on a Ti-Ru-Sn ternary oxide the mineralisation of naphthol occurs only in the presence of chloride ions that act as redox mediators and COD removal is affected by chloride concentration and is not significantly influenced by the current density and mass-transfer coefficient. From a comparison of the results of the three electrodes it has been found that boron-doped diamond gives a faster oxidation rate and better current efficiency.     

电泳四氟乙烯耐磨涂层

论述了电泳四氟乙烯的泳前处理、工艺规范、质量控制、验收技术标准。