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本文合成了四氟硼酸二芳基碘鎓盐阳离子紫外光引发剂,并且从红外、核磁、紫外光谱以及熔点测定进行了表征。结果表明,该合成方法的产率达58%,接近国外文献报道产率。 相似文献
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针对目前光固化(SLA)树脂的市场需求,采用双酚A环氧丙烯酸酯、二丙烯酸酯、三丙烯酸酯及光引发剂进行复配,制备硬质紫外SLA树脂产品,通过电子万能材料试验机、平板流变仪、电子比重计等对组分含量不同的SLA树脂材料的力学性能、黏度、体积收缩率等进行了测试,确定了产品配方,并用该配方SLA树脂进行了SLA 3D打印。结果表明,较合适的SLA树脂的配方为2 mol低聚物双酚A环氧丙烯酸酯、20 mol活性稀释剂及适量光引发剂,采用该配方制得的SLA树脂黏度为240.8 mPa?s,拉伸强度为47.1 MPa,断裂伸长率为5.62 %,体积收缩率为4.44 %,所制备的产品表面光滑、性能优异。 相似文献
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新型紫外线固化环氧树脂/丙烯酸酯改性水性聚氨酯的合成与性能 总被引:2,自引:2,他引:2
合成了一种新型的具有高交联密度和优异涂膜性能的环氧树脂和丙烯酸酯同时改性的紫外线(UV)固化水性聚氨酯(UV-EP-AC-WPUD)。通过环氧基团与以异氰酸酯基团(-N=C=O)封端的聚氨酯预聚体之间的反应引入质量分数为4%的环氧树脂E-20。同时,通过聚氨酯链的-N=C=O与二元丙烯酸酯(PEDA)以及季戊四醇三丙烯酸酯(PETA)的羟基之间的反应引入碳碳双键(C=C),C=C的含量达到4.65 meq·g-1。 质量分数为3%的光引发剂Irgacure 2959被用于引发涂膜中C=C的聚合,涂膜的凝胶含量在12 s UV辐射之后达到91%,意味着C=C的聚合和交联速度快,同时所得到的涂膜的交联度非常高,不溶于溶剂丙酮,测试表明环氧树脂和两种丙烯酸酯单体已经成功嵌入聚氨酯链中,涂膜具有优异的力学性能和化学性能。 相似文献
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The surface modifications of cellulose substrate based on the photo‐induced reaction are closely related with the radicals introduced on the surface of cellulose substrates by light irradiation. We have evaluated the ability of radical formation in lyocell fabric and two water‐soluble photoinitiator systems by using photoluminescence analyses. Namely, the relative quantum yields of fluorescence and phosphorescence were estimated by the integrated emission intensity under the same values of light absorbance and the identical measuring conditions. First of all the [2‐(acryloyloxy)ethyl](4‐benzoylbenzyl)dimethylammonium bromide (PIA) system had larger UV absorbance values below 287 nm than [3‐(3,4‐dimethyl‐9‐oxo‐9h‐thioxanthene‐2‐yloxy)‐2‐hydroxypropyl]trimethylammonium chloride (PIB) system at the same concentration. The relative quantum yields of fluorescence and phosphorescence emission in PIA system were smaller than those in PIB system even if the two systems had the same values of light absorbance. Therefore it was found that the PIA system was more easily transited to the triplet‐state and the transited molecules reacted with the cellulose substrates more effectively. The modified cellulose fabric with 2‐(dimethylamino)ethyl chloride hydrochloride (AM1) and PI system had only a little different UV absorbance and photoluminescence properties from the untreated fabric system. However, the fabric modified with 2‐(4‐chlorophenyl)‐ethylamine (AM2) and PI system showed relatively big differences. The UV absorbance values were increased and the relative quantum yields of photoluminescence were decreased remarkably. We have acquired that the tertiary amine treated cellulose fabric were very effective in photo‐induced modification of cellulose. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
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《Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment》2013,30(4):750-759
Direct analysis in real time coupled to time-of-flight mass spectrometry (DART/TOF-MS) was used to detect the non-visible set-off of photoinitiators on the food contact surface of three different packages. The samples were intentionally under-cured to provoke set-off. Twelve commercially available photoinitiators were included in the ink formulations including α-amino-, morpholino, and α-hydroxy benzophenones, thioxanthones, aryl-phosphine oxide and three polymeric versions of these. Major colours of the packages’ prints were analysed, as well as the specific areas of the inner surface in contact with them. Larger quantities of photoinitiators were detected on the food contact areas in contact with the darker colours of the images. Speed-cure 7005 and 4-phenylbenzophenone were the compounds most susceptible to set-off in each of the samples by DART response. An identification protocol for unknown set-off compounds was tested, resulting in the set-off detection of diethylene glycol ethers, erucamide and acrylates, and confirmed by solvent extraction GC-MS analysis. Finally, DART/TOF-MS was scanned across transects of the food contact side of packages to map the presence of photoinitiators. Higher photoinitiator signals were observed in patterns corresponding to the printed image, suggesting DART/TOF-MS might “image” print set-off. 相似文献
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新型阳离子光固化剂双[(4-二苯硫鎓)苯]硫醚-双-六氟磷酸盐的合成 总被引:4,自引:1,他引:3
以二苯硫醚为主要原料,以过氧化氢为氧化剂,在室温条件下氧化得到了二苯亚砜.然后,二苯亚砜与二苯硫醚在硫酸的作用下,进行缩合反应制备了双[(4 二苯硫)苯]硫醚 双 六氟磷酸盐,收率由文献报道的39%提高到75%;对其结构进行了UV、IR、H NMR和元素分析. 相似文献