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排序方式: 共有233条查询结果,搜索用时 125 毫秒
61.
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合成了光引发剂 (2,4,6-三甲基苯甲酰基 )二苯基膦氧化物( TPO),测试了其在丙烯酸改性环氧树脂体系清漆和色漆中的光引发性能.结果表明,与其它光引发剂相比, TPO可缩短清漆和色漆的固化时间;TPO的最佳用量为丙烯酸树脂的 4%(质量分数). 相似文献
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Dodecyl-benzophenone(DBP) and hexadecoxyl-benzophenone(HDBP) as type II photoinitiators used for radical photopolymerization systems were synthesized by Friedel-Crafts reaction, and characterized by 1H NMR and FTIR spectroscopy. The UV-Vis absorption spectra of DBP and HDBP, propitious to photopolymerization under a commercial mercury UV bulb are centered at 345 and 335 nm, respectively. HDBP has higher extinction coefficient than DBP, but lower photoinitiating efficiency. Their photoinitiating performances for E13605, a bisphenol A epoxy acrylate with 40%(mass fraction) tripropyleneglycol diacrylate (TPGDA), resin consisting of bisphenol A epoxy acrylate and tripropyleneglycol diacrylate in the presence of triethanolamine as a coinitiator were investigated by photo-differential scanning calorimetry(photo-DSC). DBP initiates the curing of acrylate more efficiently than HDBP,showing higher photopolymerization rate and unsaturation conversion. resulted from the poor compatibility of HDBP with the resin. The photoinitiating activity of DBP to epoxy acrylate resin is even higher than that of BP at lower loadings. 相似文献
66.
UV喷墨墨水中包含着预聚物、单体、光引发剂、颜料、助剂等组分,其中预聚物是构成UV喷墨墨水组分的基本骨架,其性能对固化过程和固化膜的性质起决定作用;单体作为活性稀释剂影响墨水体系的黏度和固化速度;光引发剂的作用是吸收紫外光能量,同时产生游离基,促使油墨发生聚合反应,是光固化体系的关键组分。介绍了常见UV喷墨墨水中预聚物、单体和光引发剂的组成、特性以及最新应用研究动向。 相似文献
67.
Synthesis and photoinitiating behavior of benzophenone-based polymeric photoinitiators used for UV curing coatings 总被引:1,自引:0,他引:1
Three benzophenone-based type II polymeric photoinitiators, poly(2-(4-benzophenone methylene ether)-1,3-dihydroxypropane maleate)) (PBM), poly(2-(4-benzophenone methylene ether)-1,3-dihydroxypropane succinate)) (PBS), and poly(2-(4-benzophenone methylene ether)-1,3-dihydroxypropane-co-2-(phenyl-methylene-ether)-1,3-dihydroxypropane maleate)) (PBPM) used for free radical UV curing systems, were prepared through the step-growth polymerization of 4-(2,3-epoxypropyloxy) benzophenone (EBP) with maleic anhydride and succinic anhydride, as well co-polymerization with phenyl glycidyl ether and maleic anhydride, respectively. The molecular structures were characterized with 1H NMR and FT-IR spectroscopy, and GPC analysis. For equimolar EBP and MA reaction system, the Mn led to the maximum of 6868 g/mol with the PDI of 1.22. The UV spectroscopy analysis showed that the synthesized polymeric photoinitiators possess higher UV absorption intensity in the wavelength range of 300–400 nm compared with benzophenone (BP). The photoinitiating activity was examined based on the photopolymerization of tripropyleneglycol diacrylate (TPGDA) in the presence of triethylamine as a coinitiator by using Photo-DSC method. It was found that PBM and PBS showed higher photoinitiating efficiency than BP in the photopolymerization of TPGDA. Moreover, the side BP moiety incorporated into the polymeric chain possessed higher initiating activity than end-capped BP moiety. Moreover, PBM with higher molecular weight was more efficient to photoinitiate TPGDA UV-cured. The side chromophore group distribution in the molecular chain also affected the photoinitiating activity. The highest photopolymerization rate at the peak maximum was obtained by the photoinitiation with PBM prepared with the molar feed ratio of 1.0 of EBP to MA. 相似文献
68.
Barry A. Goldslager Stephen J. Clarson 《Journal of Inorganic and Organometallic Polymers》1999,9(2):123-131
The use of two different types of metallocene catalysts in the dehydrogenative coupling of phenylsilane to produce poly(phenylsilane) was investigated. The metallocene catalysts were first synthesized (i) through the reaction of zirconcene dichloride with n-butyllithium in toluene and (ii) through the reaction of zirconocene dichloride with sec-butyllithium in toluene. After the catalyst synthesis, phenylsilane was added in situ commencing polymerization of the phenylsilane to poly(phenylsilane) through dehydrogenative coupling in each case. The resulting poly(phenylsilanes) were characterized by 1H NMR, GPC, FTIR, and UV/Vis, and were shown to be successful photoinitiators for a variety of acrylate and methacrylate type monomers. 相似文献
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A photoinitiator HTD bearing in-chain benzophenone (BP) and coinitiator tertiary amine, based on 4-hydroxybenzophenone (HBP),
toluene-2,4-diisocyanate (TDI) and N,N-dimethylethanolamine (DMEA), was synthesized and characterized by 1H-NMR and UV-vis absorption spectroscopy. HTD had longer absorption wavelength in the UV-vis absorption spectra than the low
molecular counterpart BP. The kinetics of photopolymerization was studied by real-time Fourier transformation infrared (FTIR)
spectroscopy. It showed that HTD was a more effective photoinitiator than BP. When this photointiator was used to initiate
polymerization of acrylates, both rate of polymerization and final conversion increased with increase of initiator concentration
and light intensity. UV-vis extract analysis showed that the extractability of HTD was much lower than BP/DMEA on the same
environment condition. 相似文献