Electrochemical pitting behaviour of type 321 stainless steel in sulfide-containing chloride solutions

The pitting behaviour of type 321 stainless steel in sulfide-containing chloride aqueous environments was studied using cyclic potentiodynamic polarization. A well-established correlation between H₂S and Na₂S₂O₃ in the study of corrosion was applied, that is, H₂S was simulated by Na₂S₂O₃. The major factors affecting the pitting corrosion of type 321 stainless steel are the Cl^- concentration, solution pH and temperature. The results clearly indicate that both E_pit and E _pp decrease with increasing Cl^- concentration and temperature, while I _pass is more sensitive to temperature variation. E _pit decreased with decreasing pH in the range 2 < pH < 7.5. The surface morphology and chemistry of the corroded type 321 stainless steel resulting from anodic polarization in 0.01 M S₂O ₃ ^2- -containing Cl^- solution were analysed by XRD, SEM and EPMA. A higher concentration of sulfur was found in the pits, and the dark surface film was mainly composed of FeS and -Fe₂O₃. The results describe the pitting behaviour of type 321 stainless steel in sulfide-containing Cl^- aqueous environments.     

阻垢缓蚀剂对不锈钢管缓蚀效果的评定方法

用点蚀电位法和失重法评价了七种阻垢缓蚀剂在不同冷却水样中对不锈钢的缓蚀效果。用腐蚀失重法评价阻垢缓蚀剂对不锈钢的缓蚀效果，既不合理也很难测准。点蚀电位法是评价阻垢缓蚀剂对不锈钢缓蚀效果的有效方法，但要选择合适的空白水样。     

混凝土内钢绞线的蚀坑形状及分布特征

为研究预应力钢筋的锈蚀特性,在自然气候条件下,采用内掺盐的方式,进行了混凝土内钢绞线的锈蚀实验．实验结果表明：钢绞线的蚀坑形状可抽象为2种典型形状,即椭球形和马鞍形;随着锈蚀率增大,蚀坑总个数增大,椭球形蚀坑出现的概率呈先增后减趋势;马鞍形蚀坑出现概率呈先减后增趋势,但变化幅度都不大;蚀坑的长度、宽度、深度都较好地呈对数正态分布．     

Fabrication of high nitrogen austenitic stainless steels with excellent mechanical and pitting corrosion properties

A series of high nitrogen austenitic stainless steels were successfully developed with a pressurized electroslag remelting furnace. Nitride additives and deoxidizer were packed into the stainless steel pipes, and then the stainless steel pipes were welded on the surface of an electrode with low nitrogen content to prepare a compound electrode. Using Si3N4 as a nitrogen alloying source, the silicon contents in the ingots were prone to be out of the specification range, the electric current fluctuated greatly...     

Evaluation Indicators and Extraction Method for Pitting Corrosion of Structural Steel

A set of evaluation indicators based on corrosion ratio in theory for assessing the extent of pitting corrosion and performance reduction are proposed. In order to quantify the morphology of pitting co...     

321不锈钢钝化膜孔蚀破坏的原子吸收光谱研究

采用原子吸收光谱方法测定不锈钢局部破坏后各种元素的析出量，研究了３２１不锈钢在ＮａＣｌ水不溶液中钝化膜孔蚀破坏的特征。研究结果表明：ＡＡＳ可有效地用于不锈钢孔蚀动力学的研究。     

321不锈钢点蚀电位影响因素的研究

通过正交设计和对比实验研究了温度、pH值以及Cl-和SO2-4含量对321不锈钢点蚀电位的影响.正交设计表明,温度和Cl-(Cl-≥0.014mol/L)含量对点蚀电位Eb的影响显著,但pH值(6～9)则没有影响.对比实验表明,当Cl-≤0.014 mol/L时,Cl-对Eb没有影响,当Cl-＞0.014 mol/L,则Eb随Cl-浓度对数升高而线性下降.点蚀电位随温度升高而下降.如不含Cl-,则SO2-4对Eb没有影响,当Cl-=0.028 mol/L时,Eb随SO2-4浓度升高而升高,并趋于稳定值.     

水陆装甲车车体锈层分析

采用x射线衍射、SEM和EPMA等方法对服役20年～30年 水陆装甲车车体锈层进行了研究，研究表明：锈层中含有Cl-，锈层主要由α-FeOOH、β-FeOOH、γ-FeOOH、γ-Fe2O3、Fe3O4以及α-Fe等相组成，同时还残留有极少量的绿锈GR*(I).结合水陆装甲车的使用环境(海水、淡水，干湿交替)，对锈层各相的成因进行了分析.内锈层致密，大蚀坑下有小蚀坑，锈层中包含有呈小岛状弥散分布的Fe基体，均匀腐蚀与局部点蚀共同造成了材料的腐蚀破坏.     

热变形参数对23Cr-6.2Mn-2.1Ni-0.28N节Ni型双相不锈钢点蚀行为的影响

采用热模拟、动电位极化曲线、交流阻抗谱等手段研究了热变形参数对23Cr-6.2Mn-2.1Ni-0.28N节Ni型双相不锈钢点蚀行为的影响。结果表明:实验钢的耐蚀性对应变速率、变形温度比较敏感,晶粒细化有利于提高试样的耐点蚀性能。在1和10 s-1的较高应变速率下,随变形温度升高,试样的耐蚀性先增加后降低,1050℃耐蚀性最好。随应变速率增加,再结晶晶粒细化程度降低,钝化膜稳定性减弱,试样耐蚀性逐渐降低。点蚀坑主要分布在δ相和δ/γ相界,随应变速率增加点蚀坑数量明显增多,尺寸变大。     

含Cl^-溶液中SO4^2-对316不锈钢临界点蚀温度的影响

采用外加恒电位下腐蚀电流-温度扫描方法研究了在0．5％Cl^-溶液中，SO4^2-浓度对316不锈钢点腐蚀行为的影响．结果表明，随着SO4^2-浓度的增加，钝化电流增加，开路电位降低．当SO4^2-浓度低于0．42％时，316不锈钢的临界点蚀温度比不存在SO4^2-时的临界点蚀温度低；当SO4^2-浓度大于0．42％时，临界点蚀温度比不存在SO4^2-时的临界点蚀温度高．从离子竞争吸附的角度进行分析，对SO4^2-加速与抑制点蚀两种作用规律的形成原因进行了解释．