Plasma-assisted catalysis was used for the destruction of 500 ppm of dichloromethane, CH2Cl2 (DCM), in gas streams of air using a non-thermal, atmospheric pressure plasma utilising a dielectric packed bed. The combination of plasma and catalyst gave improved destruction of DCM. Eight catalysts which including alumina, TiO2 and various zeolites were investigated with the finding that alumina in a one-stage reactor configuration and TiO2 and HZSM-5 in two-stage configurations gave the best DCM destructions. The sodium zeolites are capable of reducing by 50% the unwanted NOx by-products, formed by plasma processing in air. The nature of the catalyst is important in terms of the destruction efficiency, end-product selectivity and NOx reduction. 相似文献
The role of ozone was studied for two different configurations combining non-thermal plasma (NTP) and heterogeneous catalysis, namely the use of a gas phase plasma with subsequent exposure of the effluent to a catalyst in a packed-bed reactor (post-plasma treatment) and the placement of the catalyst directly in the discharge zone (in-plasma catalysis). Non-porous and porous alumina and silica were deployed as model catalysts. The oxidation of immobilised hydrocarbons, toluene as a volatile organic compound and CO as an inorganic pollutant were studied in both operational modes.
While conversion and selectivity of hydrocarbon oxidation in the case of catalytic post-plasma treatment can be fully explained by the catalytic decomposition of O3 on γ-Al2O3, the conversion processes for in-plasma catalysis are more complex and significant oxidation was also measured for the other three materials (-Al2O3, quartz and silica gel). It became obvious that additional synergetic effects can be utilised in the case of in-plasma catalysis due to short-lived species formed in the NTP.
The capability of porous alumina for ozone decomposition was found to be correlated with its activity for oxidation of carbon-containing agents. It could be clearly shown that the reaction product CO2 poisons the catalytic sites at the γ-Al2O3 surface. The catalytic activity for O3 decomposition can be partially re-established by NTP treatment. However, for practical purposes the additional reaction pathways provided by in-plasma catalytic processes are essential for satisfactory conversion and selectivity. 相似文献
A fluidized bed granulation method, pressure swing granulation (PSG), was applied to granulation of a hardmetal powder without pressing lubricants for making the upstream process of spark plasma sintering (SPS) more efficient.
The properties of the granules were examined and compared with those of spray dried granules and extruded ones under the present system using a sieve.
Spherical granules between 0.15 and 0.84 mm in diameter difficult to obtain by the spray drying were obtained with high yield. The flowability of the granules was far better than that of spray dried granules and similar to that of extruded ones. Iron contamination and oxidization during pressure swing granulation were tolerable to the real production. 相似文献
This paper reports the development of a method for simultaneously measuring zeolite, silicate, and phosphate in laundry detergent
products by inductively coupled plasma atomic emission spectrometry. A sample is decomposed under alkaline oxidative conditions
to decompose zeolite, silicate, phosphate, and organic substances. Then hydrochloric acid is added to the decomposed solution
to dissolve aluminum hydroxide precipitate before analysis. This sample preparation procedure was investigated by using a
total organic carbon analyzer and was confirmed to be applicable to simultaneous measurements of zeolite, silicate, and phosphate.
Relative standard deviation for the analysis is less than 2.1%, recovery is more than 99.0%, and the calibration curve gives
a correlation coefficient ofR=1.000. The detection limit of this method for aluminum and silicon is 0.1%, and for phosphorus, 0.2% by weight in the product.
This method is applicable to various laundry detergent products that contain zeolite, silicate, or phosphate and is five times
faster than the three wet chemical methods. 相似文献
Two n‐3 polyunsaturated fatty acid (PUFA)‐rich diets differing in their chemical and physical forms were given to rats during 2 wk. Liposomes [phospholipids (PL) organized in bilayer structures] made from a natural marine lipid extract or a mixture of fats containing fish oil [similar fatty acids esterified in triacylglycerols (TAG)] were used. The influence of n‐3 PUFA dietary sources on plasma parameters, i.e. TAG, cholesterol and PL concentrations, was investigated. A similar hypotriglyceridemic effect of n‐3 PUFA from liposomes or fish oil was observed. In contrast, feeding rats with liposomes led to different PL and cholesterol patterns. In the plasma of rats fed liposomes, total cholesterol amounts were positively correlated with PL levels. Liposome and fish oil feedings caused a marked increase in the amounts of n‐3 PUFA, which occurred mainly at the expense of n‐6 PUFA. However, the enrichment in n‐3 PUFA in the different plasma lipid classes differed substantially when ingested in the form of fish oil or liposomes. These results were interpreted in terms of different lipid bioavailability and metabolic fate during the digestive steps and in the liver, with the dietary source. 相似文献