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81.
n-Al2O3/Ni复合镀层的组织与滑动磨损性能研究 总被引:24,自引:4,他引:20
用电刷镀技术制得了镍基n-Al2O3复合镀层,并对镀层的滑动磨损性能进行了试验研究。纳米复合镀层的表面形貌比较细腻,镀层中纳米粒子分布均匀,与基质金属结合紧密。镀层显微硬度达到HV700,比快速镍镀层提高约40%。滑动磨损试验结果表明,随着纳米粒子含量的增大,镀层的耐磨性提高,摩擦系数也呈增大趋势;但当镀层中n-Al2O3粒子的超过2.56%(质量分数)时,镀层的耐磨性显著下降。纳米复合镀层的磨损机制以疲劳磨损为主,而快速镍底层以粘着磨损为主。 相似文献
82.
阐述了石灰竖窑的预热带、煅烧带和冷却带工作衬砖蚀损机理,并讨论了如何根据耐火砖性能和石灰竖窑不同区域的蚀损机理,选择耐火材料。 相似文献
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86.
Influence of Storage Time and Temperature on Absorption of Flavor Compounds from Solutions by Plastic Packaging Materials 总被引:1,自引:0,他引:1
R. Van Willige D. Schoolmeester A. Van Ooij J. Linssen A. Voragen 《Journal of food science》2002,67(6):2023-2031
ABSTRACT: Linear low-density polyethylene (LLDPE), oriented polypropylene (OPP), polycarbonate (PC), polyethylene terephthalate (PET film and PET bottle), and polyethylene naphthalate (PEN) were stored in a model solution containing 10 flavor compounds at 4, 20, and 40 °C and flavor absorption by the plastic materials was followed in time. The absorption rate and/or total amount absorbed increased considerably with temperature from 4 to 40 °C. Depending on storage temperature, total flavor absorption by the polyolefins (LLDPE and OPP) was 3 to 2400 times higher than by the polyesters (PC, PET, and PEN). Therefore, in the factor of flavor absorption, polyesters are preferred over polyolefins as packaging material. 相似文献
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88.
Nuclear magnetic resonance (n.m.r.) studies of 19F nuclei in a random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T2 components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T1 appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T1 were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals. 相似文献
89.
对连铸薄板坯的坯壳表面变形的物理模拟实验方法进行了分析,提出一种"铜裹铅双金属"新实验方案,并对坯壳表面弯曲变形进行了分析. 相似文献
90.
Hari B. Goyal M. O. Garg K. R. Rao R. D. Srivastava 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(2):49-56
The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid. 相似文献