含Zr多晶Ni3Al合金在不同热处理温度下的组织与性能

研究了冷轧多晶Ni3Al-(0．2％，0．6％，1．0％，1．5％)Zr(原子分数)合金在不同热处理温度(800-1100℃)下的显微组织和力学性能，结果表明，适当的热处理温度，可使无硼Ni3Al-Zr多晶合金获得优良的室温拉伸强度和塑性，随着热处理温度的升高，不同Zr含量Ni3Al合金的再结晶体积分数增加，再结晶晶粒尺寸增大，室温拉伸强度下降．随着合金中Zr含量的增加，再结晶温度降低，再结晶晶粒尺寸减小．不同Zr含量Ni3Al合金的拉伸塑性明显依赖于热处理温度，对于低Zr(0．2％)合金，在1000℃热处理后，拉伸塑性最佳；对于中Zr(0．6％)合金，在850℃热处理后，拉伸塑性达到最大值；对于高Zr(≥1．0％)合金，拉伸塑性峰值出现在900℃热处理下，当热处理温度超过900℃，拉伸塑性显著降低。     

用径迹显微照相技术测定Mo对硼在Ni中扩散的影响

本文建立了通过脱硼处理用径迹显微照相技术测量硼在合金中扩散系数的新方法。该法灵敏度高,简捷可靠。实验发现,Ni中加入0.5％Mo对硼的扩散影响不大;而加入3％Mo则有使硼的矿散激活能降低,频率因子减小,在900—1250℃的温度范围内有加快硼扩散的作用。     

Borides at interfacial zone of IC6 TLP bonded joints

1　INTRODUCTIONTransientliquidphase (TLP)bondingtechniquehasbeensuccessfullyusedinjoiningheatresistantal loys ,likeHastelloyX ,Inconel713C ,In10 0 ,Udimet5 0 0 ,70 0 ,MarM 2 0 0 ,0 0 7,2 4 7,30 2 ,Rene′80 ,TD NiCr ,MA75 4,6 0 0 0 ,PWA14 2 2 ,CSMX 2etc ,whicharesusceptibletohotcrackingor post weldheat treatmentcrackingproblemsduringfusionweld ing[14 ] .Inaddition ,therewerereportsofjoiningNiAlandTiAlintermetallicsbyTLPbondingmethod[510 ] .Forexample ,Galehadinvestigatedthemic…     

镍磷合金镀层防变色性能初探

采用正交试验和条件试验，筛选出了一种以植酸、苯甲酸钠、钼酸钠和EDTA为基本组成的镍磷合金抗蚀防变色剂。通过孔隙率测定、18％～20％盐酸点滴实验、10％氯化钠浸泡实验和阳极极化曲线测试等实验，对镍磷合金层的抗腐蚀性能进行了研究。     

Effects of phosphorus addition on the magnetic properties of sintered Fe-50 wt.% Ni alloys

Phosphorus was added to Fe-50 wt.% Ni in the form of a coated composite powder via an electroless plating process. Addition of phosphorus to Fe-50 wt.% Ni facilitated increases in density and grain size, both of which were beneficial to magnetic performance. Because of the homogeneous distribution of phosphorus in the powder, the optimal phosphorus addition was much lower than for those using Fe₃P as the phosphorus precursor. The optimal phosphorus addition was close to its maximum solubility in Fe-50 wt.% Ni (about 0.5 wt.%), above which precipitation of excessive phosphorus in the form of iron nickel phosphide, (Fe,Ni)₃P, effectively degraded the magnetic properties of Fe-50 wt.% Ni. Without the addition of phosphorus, good magnetic properties could be achieved only when the sintering temperature was high enough (>1200 °C) to result in a high sintered density and large grains in the sintered structure.     

12Cr2Ni4MoVNb钢热处理工艺参数的研究

通过对12Cr2Ni4MoVNb钢锻件的热处理工艺试验研究,重点进行了晶粒长大倾向、奥氏体化温度、奥氏体化保温时间、回火温度及回火保温时间对性能的影响的试验工作,分析了各种热处理工艺参数对力学性能的影响,优化了热处理工艺参数并在生产中进行了验证。在限定回火温度并且不损失塑韧性的前提下可以使σ_b和σ_(0.2)满足订货条件要求:σ_b≥90OMPa、σ_(0.2)≥60OMPa。     

化学镀Ni┐P/Fe双层结构材料中氢的扩散

采用超高真空气相氢渗透技术在80～250℃温度范围内,测定了氢在化学镀非晶态Ni-P/Fe双层结构材料中的扩散系数,研究了化学镀Ni-P镀层及其在300℃下真空退火热处理1h后对氢在基材中扩散行为的影响。结果表明,在实验温度范围内,氢在化学镀Ni-P/Fe双层结构中的有效扩散系数D与温度T的关系遵循Arrhenius方程,300℃真空退火处理后,有效扩散系数基本不变。     

Application of an analytical phase transformation model

Employing isothermal and isochronal differential scanning calorimetry, an analytical phase transformation model was used to study the kinetics of crystallization of amorphous Mg82.3Cu17.7 and Pd40Cu30P20Ni10 alloys. The analytical model comprised different combinations of various nucleation and growth mechanisms for a single transformation. Applying different combinations of nucleation and growth mechanisms, the nucleation and growth modes and the corresponding kinetic and thermodynamic parameters, have been determined. The influence of isothermal pre-annealing on subsequent isochronal crystallization kinetics with the increase of pre-annealing can be analyzed. The results show that the changes of the growth exponent, n, and the effective overall activation energy Q, occurring as function of the degree of transformation, do not necessarily imply a change of nucleation and growth mechanisms, i.e. such changes can occur while the transformation is isokinetic.     

Nickel Electroplating

NICKEL ELECTROPLATING has been practicallyused for decades.There is an unknown part in theplating,although this is easy to plate.Applications ofthe plating are described from the practical viewpoint.Purpose of Nickel Electroplating(1)Decorative,and corrosion resistanceNickel electroplating is deposited on iron,cupper,zinc and aluminum substrate etc.,and chromiumplating is usually deposited on nickel plating.Hexavalent chromium plating has an important effecton the corrosion resisitan…     

换热器表面预处理及防腐工艺

石化换热器许多设备都由碳钢制作,需要涂镀渗防腐,为保证防腐层质量,需要进行严格的表面预处理。概述了机械与化学表面预处理及相关的防腐工艺。