合成2,4-二叔丁基苯酚工业试验

以离子交换树脂为催化剂，苯酚和甲基叔丁基醚为原料合成2，4-二叔丁基苯酚(简称2，4酚)，合成产物经过滤再经间歇真空精馏精制提纯，得到高纯度的2，4酚成品。成品精馏后釜中残液在酸性白土催化剂的作用下通过歧化反应生成对叔丁基苯酚，再经精馏提纯得到成品对叔丁基苯酚。通过工艺优化，使2，4酚、对叔丁基苯酚形成联产生产工艺，降低了生产原料消耗和成本。     

化学成分和固溶温度对1Cr17Mn9Ni4N不锈钢组织和性能的影响

为提高1Crl7Mn9Ni4N钢固溶处理后的力学性能(特别是钢的强度)，研究了化学成分及固溶处理温度对其组织和性能的影响。结果表明，1000—1125℃固溶处理后，该钢的组织为单相奥氏体。在标准成分范围内，随着镍、锰含量的增加，该钢的强度降低，塑性有所改善。氮明显提高该钢的强度。根据试验结果，每增加0．01％的氮钢的室温强度可提高大约5MPa，且塑性基本上不受影响。当合金成分(质量分数，％)控制在C0．08—0．12、Crl6．5—17．5、Ni3．5—4．2、Mn8．0—9．0、N0．22—0．28时，1Crl7Mn9Ni4N钢经1050—1100℃固溶处理后强度较高、塑性好，室温强度σ0．2和σb可分别达到400MPa和800MPa。     

Facile synthesis of nanocrystalline zinc ferrite via a self-propagating combustion method

Macroporous nanocrystalline zinc ferrite with single spinel-phase was prepared by a facile self-propagating combustion method using zinc nitrate, iron nitrate and glycine. The as-prepared ZnFe₂O₄ were characterized by X-ray diffraction (XRD) analysis, N₂ adsorption, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and energy dispersive X-ray spectrum (EDS). The magnetic properties of the prepared ZnFe₂O₄ were also studied.     

巴彦浩特探区钻井液技术初探

巴彦浩特探区钻井液工艺技术的重点是，解决疏松砂砾岩地层水涌漏同层、侏罗系地层水的HCO3^-污染及可能出现的火成岩地层井塌复杂。结合内蒙古巴彦浩特探区地层和井身结构特点，采用了两性聚合物／氯化钾钻井液和氯化钾／石膏-聚磺钻井液体系。该体系抑制能力强，性能稳定．容易实现低固相、低密度近平衡钻井，保护储层效果好。对复杂情况采取了有针对性的处理办法：平稳操作和合理的钻井工程措施是预防水层涌漏同层和火成岩井塌复杂的重要手段；用井场易得的固井水泥或石膏配合烧碱处理HCO3^-污染简便易行；处理火成岩井塌复杂，控制合适的钻井液性能是必要的。     

钢带试样位向及拉伸性能的探讨

从碳素结构钢热轧钢带各向异性的事实出发 ,阐述不同试样位向导致同一钢带不同的拉伸性能 ,因而影响钢带合格与否的判定。在全面考虑钢带和焊管标准的基础上 ,提出解决钢带判定的两种方法。同时 ,还对标准中存在的缺点作了说明 ,提出改进意见 ,供标准修订时参考。     

Reliability and Validity of the Revised Children's Manifest Anxiety Scale in a French-Canadian Sample.

The aim of this study was to examine the reliability and validity of a French version of the Revised Children's Manifest Anxiety Scale (RCMAS). A sample of 2,666 school-age French-Canadian children completed the questionnaire. With regard to factor structure, the 5-factor model found in U.S. normative samples was confirmed. The internal consistency of the 5 scales and of the 2 global scales was good to excellent. Test-retest reliabilities after a 6-month period were also similar to those of the original version. Finally, the concurrent validity, assessed by a correlation with the State-Trait Anxiety Inventory for Children, was also found to be good. Results of the present study show that the French version of the RCMAS is a good instrument to assess anxiety in children. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

纤维体积分数对K3D/MCPA复合材料力学性能的影响

本文研究了纤维体积分数对三维编织芳纶纤维增强铸性尼龙(简称K3D／MCPA)复合材料力学性能的影响。研究表明，K3D／MCPA复合材料有优异的抗冲击性能，冲击强度比三维编织芳纶纤维增强铸性尼龙(简称C3D／MCPA)和纯基体均有大幅度的提高，且随着纤维体积的提高而升高。K3D／MCPA复合材料剪切强度随纤维体积比的增大而增大，其纵向剪切强度低于纯基体和C3D／MCPA复合材料，但其横向剪切强度高于它们。K3D／MCPA复合材料弯曲强度与弯曲模量随纤维体积比的提高而提高，但与相同体积比的C3D／MCPA相比，K3D／MCPA的弯曲强度与弯曲模量均较低。     

2-巯基苯并噻唑衍生物摩擦学性能的研究

合成了S—(1—(2—苯并噻唑基巯基)—2—羟基)—丙基N，N—二烷基二硫代氨基甲酸酯和S—(1—(2—苯并噻唑基巯基)—2—乙酰基)—丙基N，N—二烷基二硫代氨基甲酸酯两种化合物。运用IR、MS、HNMR和元素分析等分析方法对其结构进行表征。用四球试验、HQ—l环块试验分别考察了其对润滑油的极压承载能力及抗磨减摩性能的影响。结果表明：在350SN中性油中添加所合成的化合物后可以显著降低四球长磨后磨斑直径、有效地降低摩擦副之间的摩擦系数，拥有优良的摩擦学性能。     

Crystalline Behavior and Magnetic Properties of Nd60Fe30-x Al10Cox（x = 0,5,10） Bulk Amorphous Alloys

Crystalline behavior and magnetic properties of Nd60Fe30-xAl10Cox( x = 0, 5, 10) bulk amorphous alloys were investigated by differential scanning calorimeter (DSC), X-ray diffraction (XRD) and the vibrating sample magnetometer (VSM). Neither glass transition nor supercooled liquid region before crystallization was observed for the as-cast Nd60Fe30-xAl10Cox ( x = 0,5,10) bulk amorphous alloys. The glass forming ability can be improved significantly by the addition of Co. The as-cast Nd60Fe30-xAl10Cox (x = 0,5,10) alloys show hard magnetic behavior. With the addition of Co content, intrinsic coercivity (iHc) increases while the saturation magnetization(σs) and remanence (σr) decrease. The Curie temperature for the as-cast Nd60Fe30-xAl10Cox alloys increases from 451 K for x =0 to 468 K for x = 10. Some pre-cipitation of crystalline phases does not affect the hard magnetic properties of Nd60Fe30-xAl10Cox(x = 0,5,10) alloys, while the hard magnetic behavior disappears quickly after the alloys being completely crystallized.     

液氮制冷低气压试验箱的仿真设计

在采用液氮制冷的低气压试验箱的设计中,用常规工程设计方法计算的降温过程冷负荷过大,从而导致真空系统设计容量过大。本文采用分布参数模型对试验箱低气压条件下降温过程的冷负荷进行了精确仿真模拟,以此作为真空系统容量设计的基础,减小了设计规模,取得了良好的效果。