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纯铜双层辉光离子渗钛组织形成机理及性能分析 总被引:6,自引:0,他引:6
采用双层辉光离子渗金属技术对纯铜进行了渗钛处理。用配有能谱仪(EDS)的扫描电子显微镜(SEM)、X射线衍射仪和透射电子显微镜对合金层的显微组织形貌、钛含量分布、相组成及相结构类型进行了观察与测定,对合金层的形成机理进行了探讨,并对其性能进行了对比测定。结果表明:渗钛层由合金层和扩散层组成,合金层主要由TiCu (Cu)固溶体 TiCu4构成,TiCu4为Dla型有序相,TiCu为B2型有序相,扩散层为(Cu)固溶体。渗钛处理后纯铜的表面得到显著强化。 相似文献
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Studies were made on the thermally stimulated discharge currents (TSDCs) in pure (undoped) and Fe-doped polystyrene films as a function of polarizing field, polarizing temperature and dopant concentration. While undoped films exhibited a single peak, doped films showed two peaks one at low temperatures and another at high temperatures. The low temperature peak, which exhibits a shift towards lower temperatures with increasing dopant concentration, is attributed to the relaxation of the main chain, while the high temperature peak, which shows a tendency to shift towards higher temperatures with dopant concentration, is due to space charge polarization. The TSDCs were higher for low dopant concentrations than their undoped counterparts, while for high concentrations of the dopant, the TSDCs decreased. Formation of charge transfer complexes at low dopant concentrations and molecular aggregates at higher dopant concentrations are suggested as the possible reasons for this behaviour. 相似文献
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The chemical oxidation of aniline to form polyaniline (PANI) films and powder samples was made using Fenton reagent as an oxidizing agent in aqueous sulfuric acid medium. The PANI films were monitored by using the quartz crystal microbalance and the electronic absorption techniques. The optimum concentration was determined and the results were justified by measuring the UV–vis absorption spectra for the in situ PANI films. The conductivity for the PANI films and powder samples, prepared in different conditions, was measured. Also, the IR spectra, X‐ray and the thermogravimetric analysis for the PANI powder formed in the bulk were measured and compared with the polymer prepared using ammonium peroxydisulfate. A preliminary investigation to the dielectric properties of the polymer powder was measured and discussed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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Namsin Park Takeyuki Shiraishi Kazuyoshi Kamisugi Yoshitaka Hara Keita Iizuka Takashi Kado Shuzi Hayase 《Journal of Applied Electrochemistry》2008,38(3):371-375
A direct ethanol fuel cell (DEFC), which is less prone to ethanol crossover, is reported. The cell consists of PtRu/C catalyst as the anode, Nafion® 117 membrane, and Ni–Co–Fe (NCF) composite catalyst as the cathode. The NCF catalyst was synthesized by mixing Ni, Co, and Fe complexes into a polymer matrix (melamine-formaldehyde resins), followed by heating the mixture at 800 °C under inert atmosphere. TEM and EDX experiments suggest that the NCF catalyst has alloy structures of Ni, Co and Fe. The catalytic activity of the NCF catalyst for the oxygen reduction reaction (ORR) was compared with that of commercially available Pt/C (CAP) catalyst at different ethanol concentrations. The decrease in open circuit voltage (Voc) of the DEFC equipped with the NCF catalysts was less than that of CAP catalyst at higher ethanol concentrations. The NCF catalyst was less prone to ethanol oxidation at cathode even when ethanol crossover occurred through the Nafion®117 film, which prevents voltage drop at the cathode. However, the CAP catalyst did oxidize ethanol at the cathode and caused a decrease in voltage at higher ethanol concentrations. 相似文献
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A prediction method for the thermal conductivity of halocarbon refrigerants in the saturated liquid state in the reduced temperature range 0.3 to well above 0.9 is presented in this paper. The aim of the method is to present a very simple calculation of the transport property useful for engineering purposes. The method determines thermal conductivity as a sole function of the reduced temperature and requires the knowledge of a parameter dependent upon easily available physical constants characteristic of each compound. The method is validated against experimental data available in the literature, giving average absolute deviations which are usually less than 5%, with maximum absolute deviations generally less than 10%. An extension of the method to estimate thermal conductivity of binary mixtures is also presented, along with a comparison with the few experimental data available in the literature.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A. 相似文献