Phenyl Selenosulfides as Cathode Materials for Rechargeable Lithium Batteries

The Se? Se bond in an organo‐diselenide (RSeSeR, R is an organic group) can break in a 2e^? reduction reaction, but it has limited capacity as a cathode material for rechargeable lithium‐ion batteries. To increase its capacity, redox active species (e.g., sulfur) can be added in the middle of the selenium atoms. Herein, phenyl diselenide (PDSe, PhSeSePh) is mixed with sulfur to form two hybrid compounds with 1:1 and 1:2 molar ratios, which almost double and triple the capacity of PDSe, respectively. Theoretical calculations suggest that phenyl selenosulfide (PDSe‐S, PhSe‐S‐SePh) and phenyl selenodisulfide (PDSe‐S₂, PhSe‐SS‐SePh) can form via addition reactions, which is supported by mass spectrometry analysis. The hybrid materials exhibit three highly reversible redox plateaus and enhanced cycling stability due to the reduced solubility of the discharge products. PDSe‐S and PDSe‐S₂ show initial capacities of 252 and 330 mAh g^?1, respectively, followed by stable cycling performance with a capacity retention of >73% after 200 cycles at C/5 rate. In addition, they show steady rate capabilities. This study reports a novel strategy to increase the electrochemical performance of organo‐diselenide by addition of sulfur.     

Engineering Transition Metal Layers for Long Lasting Anionic Redox in Layered Sodium Manganese Oxide

Oxygen-redox-based-layered cathode materials are of great importance in realizing high-energy-density sodium-ion batteries (SIBs) that can satisfy the demands of next-generation energy storage technologies. However, Mn-based-layered materials (P2-type Na-poor Na_y[A_xMn_1−x]O₂, where A = alkali ions) still suffer from poor reversibility during oxygen-redox reactions and low conductivity. In this work, the dual Li and Co replacement is investigated in P2-type-layered Na_xMnO₂. Experimentally and theoretically, it is demonstrated that the efficacy of the dual Li and Co replacement in Na_0.6[Li_0.15Co_0.15Mn_0.7]O₂ is that it improves the structural and cycling stability despite the reversible Li migration from the transition metal layer during de-/sodiation. Operando X-ray diffraction and ex situ neutron diffraction analysis prove that the material maintains a P2-type structure during the entire range of Na⁺ extraction and insertion with a small volume change of ≈4.3%. In Na_0.6[Li_0.15Co_0.15Mn_0.7]O₂, the reversible electrochemical activity of Co³⁺/Co⁴⁺, Mn³⁺/Mn⁴⁺, and O^2-/(O₂)^n- redox is identified as a reliable mechanism for the remarkable stable electrochemical performance. From a broader perspective, this study highlights a possible design roadmap for developing cathode materials with optimized cationic and anionic activities and excellent structural stabilities for SIBs.     

Drawing a Pencil‐Trace Cathode for a High‐Performance Polymer‐Based Li–CO2 Battery with Redox Mediator

Lithium–carbon dioxide (Li–CO₂) batteries have received wide attention due to their high theoretical energy density and CO₂ capture capability. However, this system still faces poor cycling performance and huge overpotential, which stems from the leakage/volatilization of liquid electrolyte and instability of the cathode. A gel polymer electrolyte (GPE)‐based Li–CO₂ battery by using a novel pencil‐trace cathode and 0.0025 mol L^?1 (M) binuclear cobalt phthalocyanine (Bi‐CoPc)‐containing GPE (Bi‐CoPc‐GPE) is developed here. The cathode, which is prepared by pencil drawing on carbon paper, is stable because of its typical limited‐layered graphitic structure without any binder. In addition, Bi‐CoPc‐GPE, which consists of polymer matrix filled with liquid electrolyte, exhibits excellent ion conductivity (0.86 mS cm^?1), effective protection for Li anode, and superior leakproof property. Moreover, Bi‐CoPc acts as a redox mediator to promote the decomposition of discharge products at low charge potential. Interestingly, different from polymer‐shaped discharge products formed in liquid electrolyte–based Li–CO₂ batteries, the morphology of products in Li–CO₂ batteries using Bi‐CoPc‐GPE is film‐like. Hence, this polymer‐based Li–CO₂ battery shows super‐high discharge capacity, low overpotential, and even steadily runs for 120 cycles. This study may pave a new way to develop high‐performance Li–CO₂ batteries.     

基于0.5 μm CMOS集成电路高低压兼容技术研究

将高压MOSFETs器件集成到低压CMOS数字和模拟电路中的应用越来越频繁。文章参考了Parpia提出结构,将高压NMOS、PMOS器件制作在商用3.3V/5V 0.5μmN-阱CMOS工艺中,没有增加任何工艺步骤,也没有较复杂BiCMOS工艺中用到的P-阱、P+、N+埋层,使用了PT注入。通过对设计结构的PCM测试,可以得到高压大电流的NMOS管BVdssn>23V～25V,P管击穿BVdssp>19V。同时,文章也提供了高压器件的设计思路和结果描述。     

Redox Poly-Counterion Doped Conducting Polymers for Pseudocapacitive Energy Storage

Conducting polymers (CPs) have been widely studied for electrochemical energy storage. However, the dopants in CPs are often electrochemically inactive, introducing “dead-weight” to the materials. Moreover, commercial-level electrode materials with high mass loadings (e.g., >10 mg cm⁻²) often encounter the problems of inferior electrical and ionic conductivity. Here, a redox-active poly-counterion doping concept is proposed to improve the electrochemical performance of CPs with ultra-high mass loadings. As a study prototype, heptamolybdate anion (Mo₇O₂₄⁶⁻) doped polypyrrole (PPy) is synthesized by electro-polymerization. A 2 mm thick PPy electrode with mass loading of ≈192 mg cm⁻² reaches a record-high areal capacitance of ≈47 F cm⁻², competitive gravimetric capacitance of 235 F g⁻¹, and volumetric capacitance of 235 F cm⁻³. With poly-counterion doping, the dopants also undergo redox reactions during charge/discharge processes, providing additional capacitance to the electrode. The interaction between polymer chains and the poly-counterions enhances the electrical conductivity of CPs. Besides, the poly-counterions with large steric hindrance could act as structural pillars and endow CPs with open structures for facile ion transport. The concept proposed in this work enriches the electrochemistry of CPs and promotes their practical applications.     

化学镍金工艺中的镍足控制方法研究

PCB上的线路日趋精细,焊盘间距也在不断缩小。目前,PCB上的最小焊盘间距可以达到0.050 mm。而在这些小间距的焊盘上进行化学镍金处理后,镍足就会从焊盘边缘往外延伸,从而导致渗金短路。分析了镍足变化的主要影响因素,研究了铜箔毛面粗糙度,钯离子吸附和沉镍药水活性对镍足生长的不同作用,总结了减小镍足的若干措施。     

Effective capacity of a correlated Nakagami‐m fading channel

The grail of next‐generation wireless networks is providing real‐time services for delay‐sensitive applications, which require that the wireless networks provide QoS guarantees. The effective capacity (EC) proposed by Wu and Negi provides a powerful tool for design of QoS provisioning mechanisms. In this paper, we intend to generalize their formula for the effective capacity of a correlated Rayleigh fading channel; specifically, we derive a closed form approximate EC formula for a special correlated Nakagami‐m fading channel, for which the inverse of the correlation coefficient matrix is tridiagonal. To verify its accuracy via simulation, we develop a Green‐matrix based approach, which allows us to analytically obtain the effective capacity (given the joint probability density function of a correlated Nakagami‐m fading channel) while being able to simulate the corresponding channel gain process. Simulation results show that our EC formula is accurate. Furthermore, to facilitate the application of the EC theory to the design of practical QoS provisioning mechanisms, we propose a simple algorithm for estimating the EC of an arbitrary correlated Nakagami‐m fading channel, given channel measurements; simulation results demonstrate the accuracy of our proposed EC estimation algorithm showing its suitability in practice. Copyright © 2011 John Wiley & Sons, Ltd.     

Redox‐Responsive and Drug‐Embedded Silica Nanoparticles with Unique Self‐Destruction Features for Efficient Gene/Drug Codelivery

The development of advanced gene/drug codelivery carriers with stimuli‐responsive release manner for complementary cancer therapy is desirable. In this study, novel disulfide‐bridged and doxorubicin (DOX)‐embedded degradable silica nanoparticles (DS‐DOX) with unique self‐destruction features are synthesized by a facile one‐pot method. In order to realize codelivery of genes and drugs, the surface of DS‐DOX nanoparticles is readily functionalized with the assembled polycation (CD‐PGEA), comprising one β‐cyclodextrin core and two ethanolamine‐functionalized poly(glycidyl methacrylate) arms, to achieve DS‐DOX‐PGEA. The redox‐responsive self‐destruction behavior of DS‐DOX imparts DS‐DOX‐PGEA with a better ability to release anticancer drug DOX, while the low‐toxic hydroxyl‐rich CD‐PGEA brushes can efficiently deliver genes for cancer treatment. Very interestingly, the degradation process of DS‐DOX starts from the outside, while the destruction of the degradable silica (DS) nanoparticles without DOX begins from the center of the nanoparticles. The embedded DOX inside the DS‐DOX nanoparticles can significantly influence the structures and facilitate the cellular uptake and the subsequent gene transfection. The as‐developed DS‐DOX‐PGEA nanostructure with coordinating biodegradability, stimuli‐responsiveness, and controlled release manner might be desirable gene/drug codelivery carriers for clinical cancer treatment.     

RFID防碰撞算法中扩频码特性研究

标签碰撞是射频识别(RFID)技术的常见问题,该问题影响了RFID系统数据通信过程中数据传输的完整性。针对在解决防碰撞问题中新出现的码分多址方法,对Walsh码、m序列和Gold序列的3种扩频码组进行比较,研究在标签防碰撞算法中扩频码的性能。仿真实验结果:m序列和Gold序列在基于码分多址技术的防碰撞算法中性能要好一些。由于m序列互相关性能不是很好,因此在以后的研究中,使用Gold序列效果会更明显。     

多遥测天线集中校准源的设计与应用

遥测天线校准通常采用误码仪产生的信号经调制后送入校准天线发射,接收机收到信号解调后,再送入误码仪测量链路误码率完成单天线校准。该校准方式无法进行多天线集中校准,针对该校准方式的弊端挺出了一种多天线集中校准的方法,利用反馈式移位寄存器理论在FPGA中产生伪随机序列,给出了伪随机序列的仿真波形,并利用IN—SNEC公司接收机测试软件完成多天线集中校准源的测试。