确定合成地震记录子波主频的方法研究

针对目前合成地震记录质量不高导致层位标定解释、构造解释、储层反演精度低的问题．基于模型正演研究认为合成地震记录质量不高的原因主要是地震子波主频与实际地震子波主频不一致造成的;研究据此提出了基于模型建立地震子波主频与实际地震记录主频两者的差异之间的关系,在实际的应用过程中根据已建立的差异关系和实际地震记录主频可以获得比较准确的地震子波主频,利用这样的主频子波进行合成可获得较好的合成地震记录质量。     

Genetic evaluation of test-day milk yields from smallholder dairy production systems in Kenya using genomic relationships

Efforts to improve dairy production in smallholder farming systems of East Africa over the past decade have had limited impact because of the lack of records on performance to guide targeted breeding programs. Estimates of genetic parameters in these systems are lacking. Using data generated through a project (“Germplasm for Dairy Development in East Africa”) in Kenya and a genomic relationship matrix from genotypic records, we examined the potential impact of different models handling contemporary groups or herd effects on estimates of genetic parameters using a fixed regression model (FRM) for test-day (TD) milk yields, and the covariance structure for TD milk yield at various stages of lactation for animals using a random regression model (RRM). Models in which herd groups were defined using production levels derived from the data fitted the data better than those in which herds were grouped depending on management practices or were random. Lactation curves obtained for animals under different production categories did not display the typical peak yield characteristic of improved dairy systems in developed countries. Heritability estimates for TD milk yields using the FRM varied greatly with the definition of contemporary herd groups, ranging from 0.05 ± 0.03 to 0.27 ± 0.05 (mean ± standard error). The analysis using the RRM fitted the data better than the FRM. The heritability estimates for specific TD yields obtained by the RRM were higher than those obtained by the FRM. Genetic correlations between TD yields were high and positive for measures within short consecutive intervals but decreased as the intervals between TD increased beyond 60 d and became negative with intervals of more than 5 mo. The magnitude of the genetic correlation estimates among TD records indicates that using TD milk records beyond a 60-d interval as repeated measures of the same trait for genetic evaluation of animals on smallholder farms would not be optimal. Although each individual smallholder farmer retains only a few animals, using the genomic relationship between animals to link the large number of farmers operating under specified environments provides a sufficiently large herd-group for which a breeding program could be developed.     

基于制造特征的加工链模糊推理研究

研究了运用增量式制造特征识别技术,基于零件几何结构、拓扑关系对设计模型中单一设计特征和相交设计特征进行分析,在分析结果的基础上实现对应制造特征识别;深入研究制造特征工艺属性与对应加工方案之间存在的模糊映射关系,运用多因素模糊推理技术形成机加工特征合理的加工链,从而有力地支持设计的可制造性评价及工艺规划的生成。     

高强高性能混凝土在多轴压下强度与变形性能的试验研究

 利用大型静动真三轴试验机,进行高强高性能混凝土和普通混凝土在不同应力比下的单轴、双轴、三轴压强度与变形试验研究。多轴压试块尺寸为100 mm×100 mm×100 mm,减摩措施为3层黄油中间加3层塑料薄膜的减摩垫层,加载方式为单调比例加载。阐述试件的破坏形态和机制;测得多轴强度、峰值应变和应力–应变曲线,分析应力比对其影响规律;剖析2种混凝土多轴力学性能的差异。试验结果表明：多轴压下2种混凝土极限强度s 3f和峰值应变e 3p在所有应力比下都分别大于其单轴压强度¦c和峰值应变e cp,尤其是在三轴压下更为明显;而且s 3f和e 3p相对于¦c和e cp的提高倍数取决于混凝土的脆硬性、应力状态和应力比。建立在双轴压和多轴应力状态下的高强高性能混凝土和普通混凝土Kupfer-Gerstle和Ottosen破坏准则公式,为2种混凝土结构(如桥梁与隧道工程、地下工程、建筑工程等)在多轴压下的强度分析提供试验和理论依据。     

Heterogeneous Enantioselective Hydrogenation of Activated Ketones Catalyzed by Modified Pt‐Catalysts: A Systematic Structure‐Selectivity Study

A systematic structure‐selectivity study was carried out for the enantioselective hydrogenation of activated ketones with chirally modified Pt/Al₂O₃ catalysts. For this, 18 modifiers containing an extended aromatic system able to form a strong adsorption complex with the Pt surface, and a suitable chiral group with an amino function capable to interact with the keto group of the substrate ( HCd, Qd, HCn, Qn , and semi‐synthetic derivatives, as well as synthetic analogues) were prepared and tested on 8 different activated ketones in AcOH and toluene under standard conditions. It was found that relatively small structural changes of the substrate and/or modifier structures strongly affected the enantioselectivity, and that no “best” modifier exists for all substrates. The highest ees for all substrates were obtained with quinuclidine‐derived modifiers in combination with naphthalene or quinoline rings, either in AcOH (substrates 1 – 5 and 8 , all carrying an sp³ carbon next to the keto group) or toluene ( 6 and 7 , with an sp² carbon next to the ketone). The presence and nature of the substituent R' at the quinuclidine significantly affected the ee (positive and negative effects). Certain combinations of an aromatic system and an amino function were preferred: For the quinuclidine moiety, quinoline and to a somewhat lesser extent naphthalene were a better match, while for the pyrrolidinylmethyl group anthracene was better suited. Methylation of the OH group often had a positive effect for hydrogenations in AcOH but not in toluene. With the exception of 8 , higher ees were obtained for the Cd / Qn series [leading to (R)‐products] than for the Cn / Qd series [leading to (S)‐products]. In several cases, opposite structure‐selectivity trends were detected when comparing reactions in toluene and AcOH, indicating a significant influence of the solvent.     

Exploring the methods on improving CH4 delivery performance to surpass the Advanced Research Project Ageney-Energy target

CH_4 storage associated with adsorbed natural gas(ANG) technology is an issue attracting great concern.Following the Advanced Research Project Agency-Energy(ARPA-E) targeted deliverable capacity of 315 cm~3·cm~(-3)(STP), hundreds of thousands of materials have been experimentally or theoretically evaluated,while the best results still show a 35% gap from the target. Moreover, recent theoretical research reveals that the target is beyond the possibility that real materials can be designed. To get rid of the awkward situation, we make attempts on investigating the CH_4 delivery performance under other operation conditions. Methods of raising the discharge temperature(to infinite high) or elevating the storage pressure(to 25 MPa) have been proved to show limited effectiveness. In this work, it is found that the ARPA-E target can be achieved by using a decreasing storage temperature strategy. By taking 280 Co RE(computation-ready, experimental) COFs(covalent organic frameworks) as ANG materials, when reduce the storage temperature to 190.6 K, the highest deliverable capacity can reach 392 cm~3·cm~(-3)(STP), and16.1% Co RE COFs can surpass the target. The target is also achievable when storage at 220 K. Structure performance relationships study shows strong correlation between deliverable capacity and void fraction. Hence, 120 hypothetical COFs are generated to ascertain the optimum void fraction. In addition,the performance of 2 D-COFs can be greatly enhanced by increasing the interlayer spacings, e.g. CH_4 deliverable capacity(storage at 190.6 K) of ATFG-COF can be improved from 239 to 411 cm~3·cm~(-3)(STP) when interlayer spacing is enlarged to 1.65 nm.     

低碳环保生活与环境监测的关系内涵分析

随着世界经济进入工业化时代,化石能源的大量使用导致了不可再生能源的迅速消失和自然环境的大规模污染,经济发展与环境资源之间的矛盾日益突出.因此,各行业的技术人员开始接受低碳发展理念,发展低碳生产技术,提高能源效率,实施生产方式改革,逐步改变世界经济发展格局.本文以人们的生活现状为出发点,分析了低碳生活与环境监测的现状及存...     

高职新生宿舍人际关系现状调查分析

高职生特别是大一新生进入大学期间,每个人所必须面对的问题是宿舍的人际关系。宿舍成为高职生除课堂外活动时间最多的空间,是其生活和学习的必要场所。因此,与同宿舍其他成员之间的关系成了高职生除了学习之外课余生活的主要关系。本文采用抽样调查,自行设计问卷的方式调查并分析了我院高职新生宿舍人际关系的现状,为高职新生建立良好宿舍人际关系提供一些参考作用。     

Organic additive implantation onto cement hydration products

In polymer modified cementitious materials, it is hard to set up a chemical connection between the added polymer and the cement moiety. In this study FS （functional silane） was adopted to form this connection as a bridge component which has the functional group forming bonds with polymer. To testify the connection between FS and cement moiety, Q2/Q1 ratio （Qx： intensity ratio） investigation was carried out by the means of quantitative solid state 29Si MAS NMR. The results show that the Q2/Q1 ratio has increased with the addition of FS which indicates that the silicon chain length has increased, and the quantity of silicon atoms at site of Q2, chain site, has enhanced, showing that the silicon atom of FS has connected to the silicon chain of cement moiety by the bond ＂-Si-O-Si-＂ formation.     

闽南红砖在现代室内空间中的表征与应用

从泉州所用闽南红砖的地方性表征与建筑的在地文化,浅谈红砖文化在室内空间设计中的可创造性和可复制性.文章从室内运用现状和材料特性方面探讨闽南红砖材质与尺寸在室内空间设计中的构成法则.