轧膜成型法制备燃料电池NiO/YSZ多孔阳极材料的研究

以水基轧膜工艺制备出了不同粘结剂含量的NiO/氧化钇稳定氧化锆(YSZ)固体氧化物燃料电池多孔阳极材料。研究了粘结剂含量和制备工艺条件等对多孔阳极微结构和性能的影响。实验结果表明:轧膜坯体的烧结温度对NiO/YSZ阳极烧结体的孔隙率有着决定的影响;为获得较高孔隙率和一定孔径分布的阳极烧结体,轧膜生坯的烧结温度应不超过1450℃。此外,粘结剂含量对轧膜生坯的烧结行为及烧结体的性能也有明显的影响,在相同的烧结温度下,高粘结剂含量阳极烧结体的孔隙率和孔径范围明显高于低粘结剂含量的烧结体,其中,粘接剂含量5%的生坯烧结后得到的NiO/YSZ阳极材料具有较好的综合性能;此外,NiO/YSZ材料还原后所得Ni/YSZ金属陶瓷多孔阳极的电导率随试样烧结温度的升高而升高,随测试温度升高而降低,800℃下的其电导率可达150S/cm。     

提高出口大型开槽阳极质量的探讨

从阳极成型工艺和焙烧工艺等重要环节对改进和提高大型开槽阳极的生产质量进行了探讨.     

固体氧化物燃料电池

本文综述了高温氧化物燃料电池的种类、结构、发展现状及应用前景。介绍了固体电解质、阴电极、阳电极，内联接材料的组成及制造工艺。     

金属阳极电解槽修订标准释义

对HG/T 2471-1993《隔膜法电解槽金属阳极涂层》和HG 2951-1988（原GB 9844-88）《隔膜法金属阳极电解槽制造技术条件》标准的修订版HG/T 2471-2001《电解槽金属阳极涂层》和HG/T 2951-2001《隔膜法金属阳极电解槽》进行了技术性解释。公布了按照HG/T 2471-2001《电解槽金属阳极涂层》要求对产品质量达标企业的型式检验结果。     

近年来我国炭阳极行业的发展特点和技术进步

介绍了近年来我国炭阳极行业发展的特点,扼要论述了炭阳极原料处理、煅烧、生阳极制造、焙烧、产品性能和测试技术等方面主要的技术进步;指出了存在的问题,特别是从炭素生产质量控制环节的隐蔽性和系列性特点,分析指出炭素厂生产管理者管理理念上的差距是我国炭制品质量与外国差距大的主要原因。     

Preparation of Sn-Si-C Composite as Li-ion Battery Anode Material by High Energy Ball Milling and Its Properties

Electrochemically active Sn-Si-C composite was synthesized by high energy ball milling(HEBM) in Ar atmosphere.The so-obtained composite was characterized by X-ray diffraction and field emission scanning electron microscopy.Lithium insertion/extraction characteristics of the composites were examined by constant current charge-discharge and cyclic voltammetry methods.The results show that there is no new alloy generated by HEBM.The composite synthesized by two-step HEBM resulted in initial lithium insertion s...     

硅/氧化硅/锡/碳锂离子电池负极复合材料制备及电化学性能

以一氧化硅、二氧化锡和导电碳(Super P)为原料,通过高能球磨,加入稀盐酸与糠醇发生聚合反应,再采用高温固相法制得硅/氧化硅/锡/碳复合材料作为锂离子电池负极材料.用 XRD、SEM 进行表征,并进行有关电化学性能测试,首次放电比容量高达 1503 mAh·g<'-1>,循环性能得到了较大改善.     

锂离子电池富锂化Li_（1＋x）（Ni_zCo_（1-2z）Mn_z）_（1-x）O_2正极材料的研究

近年在锂离子正极Li1＋x（NizCo1-2zMnz）1-xO2材料开发时,存在使用Li＋替代迁移金属这类方法（也可称为＂富锂化＂）来提高该类材料的电化学性能。进行富锂化处理的主要目的在于增加正极材料的晶体结构稳定性。本文结合富锂化正极材料的发展现状,讨论了富锂化对正极材料的结构和性能影响程度。     

Performances of metal fluoride added carbon anodes with pre-electrolysis for electrolytic synthesis of NF3

Metal fluoride added carbon anodes treated by pre-electrolysis were investigated for electrolytic production of nitrogen trifluoride (NF₃) in molten NH₄F·KF·4HF at 100 °C. The conditions for pre-electrolysis were first optimized using a graphite sheet anode as a model anode. The formation of fluorine-graphite intercalation compounds (fluorine-GICs) with semi-covalent C–F bonds, (C_xF)_n, on the MgF₂ and CaF₂ added carbon anode surface was accelerated by pre-electrolysis at potentials less than 4.0 V. Critical current densities (CCD) on the MgF₂ added carbon anodes pre-electrolyzed under various conditions were determined, and the highest CCD was 290 mA cm⁻² obtained for that pre-electrolyzed at 3.5 V for 500 C cm⁻². This anode was successfully used in the electrolysis at 100 mA cm⁻² for 290 h and the maximum NF₃ current efficiency was 55%. From these results, it was concluded that the metal fluoride added carbon anode treated by pre-electrolysis has a high potential for electrolytic production of NF₃ at higher current density.     

Enhanced lithium storage performance of silicon anode via fabricating into sandwich electrode

Silicon electrode with sandwich structure as anode of lithium ion batteries is fabricated by adding a carbon layer between current collector and active coating. The prepared silicon electrode with the sandwich structure can exhibit high reversible capacity of 2500 mAh g⁻¹ for 30 cycles, which is much higher than that of bare silicon electrode with normal structure. The electrochemical impedance spectroscopy and electrode morphologies characterizations show that the improved performance of sandwich electrode is attributed to the carbon layer, which not only enhances the electric conductivity at the current collector/active coating interface but also releases the rigid stress caused by volume change of silicon. The results demonstrate that such sandwich structure is a potential facile method for performance improvement of silicon-based anode compared with the previous reports.