全文获取类型
收费全文 | 4160篇 |
免费 | 535篇 |
国内免费 | 274篇 |
专业分类
电工技术 | 437篇 |
综合类 | 166篇 |
化学工业 | 897篇 |
金属工艺 | 785篇 |
机械仪表 | 48篇 |
建筑科学 | 62篇 |
矿业工程 | 192篇 |
能源动力 | 422篇 |
轻工业 | 17篇 |
水利工程 | 7篇 |
石油天然气 | 96篇 |
武器工业 | 12篇 |
无线电 | 342篇 |
一般工业技术 | 677篇 |
冶金工业 | 727篇 |
原子能技术 | 43篇 |
自动化技术 | 39篇 |
出版年
2024年 | 12篇 |
2023年 | 70篇 |
2022年 | 138篇 |
2021年 | 184篇 |
2020年 | 221篇 |
2019年 | 164篇 |
2018年 | 141篇 |
2017年 | 169篇 |
2016年 | 168篇 |
2015年 | 147篇 |
2014年 | 230篇 |
2013年 | 204篇 |
2012年 | 287篇 |
2011年 | 350篇 |
2010年 | 228篇 |
2009年 | 213篇 |
2008年 | 207篇 |
2007年 | 325篇 |
2006年 | 276篇 |
2005年 | 230篇 |
2004年 | 202篇 |
2003年 | 168篇 |
2002年 | 142篇 |
2001年 | 107篇 |
2000年 | 106篇 |
1999年 | 80篇 |
1998年 | 40篇 |
1997年 | 38篇 |
1996年 | 34篇 |
1995年 | 23篇 |
1994年 | 20篇 |
1993年 | 8篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 9篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1951年 | 4篇 |
排序方式: 共有4969条查询结果,搜索用时 15 毫秒
51.
52.
何玲平 《上海电力学院学报》2010,(4)
基于楔条形阳极位置灵敏探测器的成像原理和二维傅里叶变换理论,提出了一种建立该类探测器成像模型的方法,进而模拟了探测器的成像效果,仿真了成像的几何非线性,仿真图像与实际图像基本符合。仿真结果表明:在阳极面板半径多出微通道板半径2P(P为阳极周期宽度)和电子云分布半宽度D为1.3P时,该类探测器的成像线性良好;电子云过小即D
5P时,电子云超出楔条形阳极工作区域,成像边缘扭曲十分明显。 相似文献
53.
介绍了直接甲酸燃料电池(DFAFC)阳极电催化机理,以及Pt基、Pd基附载型和非附载型阳极催化剂的发展状况,分析了金属合金d-带能级移动和金属表面偏析对直接甲酸燃料电池催化活性的影响,对筛选阳极催化剂合金材料具有一定的指导作用. 相似文献
54.
探讨了微悬臂梁的制作中的牺牲层释放工艺,针对FPA结构中微悬臂梁的结构层和牺牲层材料的选择和制作方法,从释放机理的角度对磷硅玻璃腐蚀速率等释放关键技术作了研究,给出了相应的加工参数。 相似文献
55.
同步产电及废水处理AFB-MFC电极研究 总被引:2,自引:0,他引:2
为了考察电极因素对微生物燃料电池产电及废水处理性能的影响,设计了一种新型厌氧流化床微生物燃料电池(AFB-MFC).研究了不同阴极电极材料,阴极与阳极面积以及阴极底边与阴极室底部距离对AFB-MFC产电及废水处理性能的影响.所有实验在阴极室曝气量为16~24 L/h、回流量为10.7 L/h、进水流量为0.6 L/h、外电阻为250 Ω以及进水COD浓度为3000.98~3789.44 mg/L下进行.结果表明,在尺寸大小均为15.0 cm×3.5cm的碳纸、铜板、铝板、镀锌铁板及铁板中,使用碳纸作阴极电极时AFB-MFC产电性能最好;阴极底边与阴极室底部的最佳距离为17.3~20.3 cm;使用面积为308.8、232.0、160.0和76.8 cm2的碳纸作阳极电极及面积为241.5、210.0、175.0和105.0 cm2碳纸作阴极时,阳极及阴极最佳面积分别为160.0和210.0 cm2.AFB-MFC系统最佳运行条件下COD的去除率维持在约80.00%.放大型AFB-MFC系统有利于今后工程实际应用. 相似文献
56.
Jernej Drofenik Robert Dominko Mogens Mogensen Stane Pejovnik 《Electrochimica acta》2003,48(7):883-889
Four types of cellulose, in particular carboxy methyl cellulose (CMC), are tested as potential binding materials in graphitic anodes for lithium ion batteries. It is shown that a minimum content of a cellulose which gives acceptable anode properties (reversible capacity>300 mA h g−1 during the first 10 cycles, irreversible loss<20%) is about 2 wt.%, which is less than in the case of conventional polymeric binders (5-10 wt.%). Kinetics of insertion-deinsertion and passivation processes seem not to be affected by the presence of cellulose. Explanation for the electrode failure at cellulose contents lower than 1 wt.% is given based on X-ray diffraction and microscopy investigations. Finally, the structure (distribution) of cellulose in the composite anode material is discussed and (indirectly) checked with a series of experiments. Most results are compared with the corresponding results obtained either with gelatin or conventional polymeric binders or both. 相似文献
57.
In order to study the anodic behavior and microstmctures of A1/Pb-Ag-Co anode during zinc electrowinning, by means of potentiodynamic investigations, scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses, the mechanism of the anodic processes playing on the surface of A1/Pb-0.8%Ag and A1/Pb-0.75%Ag-0.03%Co anodes prepared by electro-deposition from methyl sulfonic acid bath for zinc electrowinning from model sulphate electrolytes have been measured. On the basis of the cyclic voltammograms obtained, information about the corrosion rate of the composite in PbO2 region has been concluded. The microstructures were also observed by means of SEM and XRD which showed Pb-0.75%Ag-0.03%Co alloy composite coating has uniform and chaotic orientation tetragonal symmetry crystallites of PbSO4, but Pb-0.8%Ag alloy composite coating has well-organized orientation crystallites of PbSO4 concentrated in the certain zones after 24 h of anodic polarization. It is important that Al/Pb-0.75%Ag-0.03%Co anode oxide film consists of non-conductive dense MnO2 and PbSO4 and a, fl-PbO2 penetrated into which, in fact, are the active centers of the oxygen evolution after 24 h of anodic polarization. 相似文献
58.
Zhenya Wang Hao Guo De Ning Xiaobai Ma Lirong Zheng Dmitry Smirnov Kai Sun Dongfeng Chen Limei Sun Xiangfeng Liu 《Journal of the American Ceramic Society》2021,104(11):5934-5945
Li4Ti5O12 (LTO) attracts great interest due to the “zero strain” during cycles but the poor electronic and ionic conductivity critically impede the practical application. Herein, we report a synergy strategy of tuning localized electrons to shift Fermi level and band gap by Mg/Zr co-doping and oxygen vacancy incorporation, which significantly improves Li+ and electronic transport. More importantly, the intrinsic synergistic mechanism has been revealed by neutron diffraction, X-ray absorption spectra, and first-principles calculations. The “elastic effect” of lattice induced by Mg/Zr co-doping allows LTO to accommodate more oxygen vacancies to a certain degree without a severe lattice distortion, which largely improves the electronic conductivity. Mg/Zr co-doping and oxygen vacancy incorporation effectively enhanced the dynamic characteristics of LTO electrode, achieving the excellent rate performance (90 mAh/g at 20C) and cycle stability (96.9% after 500 cycles at 10C). First-principles calculations confirm Fermi level shifts to the conduction band, and the band gap becomes narrowed due to the synergistic modulation, and the intrinsic mechanism of the enhanced electronic and Li-ion conductivity is clarified. This study offers some insights into achieving the fast Li+ insertion/extraction by tuning the crystal and electronic structure with lattice doping and oxygen vacancy engineering. 相似文献
59.
采用复合溶胶–凝胶法结合后续热处理,制备了具有包埋结构的氧化亚硅/碳(SiOx/C)复合负极材料。扫描电子显微镜分析结果表明:氧化亚硅纳米颗粒嵌入在无定形碳中。电化学性能测试表明:SiOx/C复合材料具有较高的比容量、优异的循环稳定性和倍率性能。材料在0.1 A/g的电流密度下100次循环后的可逆比容量为710 m A·h/g,容量几乎无衰减;在1.6 A/g的电流密度下,可逆比容量为380 m A·h/g。优异的电化学性能是由于材料的包埋结构能有效地缓冲SiOx充放电过程中的体积膨胀,保证材料的结构完整性和电化学循环稳定性。 相似文献
60.