Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

双三羟甲基丙烷的制备及应用研究进展

综述了双三羟甲基丙烷的合成法和回收法的特点,对比说明了蒸馏-结晶回收法和溶剂-结晶回收法的原理、条件和优缺点。对双三羟甲基丙烷应用进行了重点综述,从合成原理、应用配方和应用特点等方面详细介绍了各个领域中的具体应用情况。指出产品应用开发是今后双三羟甲基丙烷的主要研究方向,重点研究双三羟甲基丙烷的酯化物合成技术、应用配方,加快工业化进程,解决产品积压问题。     

多测井曲线的综合处理合成

测井曲线是地质分层的基础，但在利用单一测井曲线解决复杂地质问题时也存在多解性和局限性。为克服多解性，人们采用多种测井曲线进行地质分层，提高了分层的精度。本文在此基础上提出把多条曲线分别赋予不同的加权因子，然后进行归一化处理，形成一条标准综合参数测井曲线。此综合参数曲线突出了所选的多条测井曲线的公共信息，减少或削弱了单一测井曲线中的偶然误差，提高了综合后测井资料的可信度。该方法可应用于地质分层、岩性分析、含油气预测等诸多领域。应用时要注意，并非所选择的测井曲线种类越多越好，而是要选择那些最能反映地层单元特征信息的测井曲线。     

Synthesis of unsaturated polyesters of increased solubility in styrene

The present study presents the synthesis of unsaturated polyester resins using only one glycol i.e., ethylene glycol. Polyesters of inorganic solubility in styrene were prepared. Properties of the resins in the noncrosslinked state in the process of crosslinking and after curing were studied. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3143–3150, 2006     

Hydrothermal Reaction Mechanism and Pathway for the Formation of K2Ti6O13 Nanowires

Calculations and detailed first principle and thermodynamic analyses have been performed to understand the formation mechanism of K₂Ti₆O₁₃ nanowires (NWs) by a hydrothermal reaction between bulk Na₂Ti₃O₇ crystals and a KOH solution. It is found that direct ion exchange between K⁺ and Na⁺ plus H⁺ interactions with [TiO₆] octahedra in Na₂Ti₃O₇ promote the formation of an intermediate H₂K₂Ti₆O₁₄ phase. The large lattice mismatch between this intermediate phase and the bulk Na₂Ti₃O₇ structure, and the large energy reduction associated with the formation of this intermediate phase, drive the splitting of the bulk crystal into H₂K₂Ti₆O₁₄ NWs. However, these NWs are not stable because of large [TiO₆] octahedra distortion and are subject to a dehydration process, which results in uniform K₂Ti₆O₁₃ NWs with narrowly distributed diameters of around 10 nm.     

新型香料苹果酯-B的合成

以硫酸高铈为催化剂,通过乙酰乙酸乙酯和1,2-丙二醇反应合成了苹果酯-B,研究了各有关因素对产品收率的影响。实验表明,硫酸高铈是合成苹果酯-B的良好催化剂,在酯醇物质的量比为1∶1.25、催化剂用量为0.3g/0.1mol乙酰乙酸乙酯、环己烷10mL、反应时间2h的条件下,苹果酯-B的收率可达91.5%。     

低压合成甲醇催化剂的工业侧线试验

在0 25m3反应釜中,对QCM-01低压合成甲醇催化剂进行了工业放大试验。试验结果表明,产品性能达到了小试试样的水平。在此基础上进行了1000h的原粒度工业侧线试验,试验结果表明,中试产品的性能达到了国外MK101催化剂的水平。     

The enhanced coercivity for the magnetite/silica nanocomposite at room temperature

Magnetite/silica nanocomposite was synthesized by a facile solvothermal processing at 150 °C for about 10 h. X-ray diffraction (XRD) analysis revealed the effect of annealing on the crystallinity of silica. Transmission electron microscopy (TEM) images showed the good dispersion of magnetite in the silica matrix. Magnetic properties of the nanocomposite were characterized by vibration sample magnetometer (VSM), and the enhanced coercivity was explained by the intrinsic anisotropy of the particles enhanced by the interparticle dipolar fields.     

Fault-aware Communication Mapping for NoCs with Guaranteed Latency

As feature sizes shrink, transient failures of on-chip network links become a critical problem. At the same time, many applications require guarantees on both message arrival probability and response time. We address the problem of transient link failures by means of temporally and spatially redundant transmission of messages, such that designer-imposed message arrival probabilities are guaranteed. Response time minimisation is achieved by a heuristic that statically assigns multiple copies of each message to network links, intelligently combining temporal and spatial redundancy. Concerns regarding energy consumption are addressed in two ways. First, we reduce the total amount of transmitted messages, and, second, we minimise the application response time such that the resulted time slack can be exploited for energy savings through voltage reduction. The advantages of the proposed approach are guaranteed message arrival probability and guaranteed worst case application response time.     

L-乳酸和聚乳酸的研究进展

综述了乳酸发酵和提取工艺以及聚乳酸的合成进展,分析了L-乳酸及合成聚乳酸两种产品的市场前景,对进一步的技术开发提出了建议。