聚合物熔体在圆锥口型的挤出胀大方程

在聚合物熔体入口收敛流变中引入纯拉伸流变概念，应用张量理论进行了定量分析，导出了一个描述圆锥口型的挤出胀大方程。研究表明，入口收敛拉伸流变，是取合物熔体产生了强烈的弹性形变，导致了较大的挤出物胀大比。     

异型材口模挤出三维流动计算机模拟系统

建立了异型材口模挤出三维流动计算机模拟系统的基本框架，介绍了其结构和功能，该系统主要包括前置处理，有限元分析和后置处理三大模块，有限元分析模块又包括对口模内幂律流动的分析模块，粘弹性PTT流体流动的分析模块以及粘弹性PTTI充体三维挤出胀大的分析模块，后置处理主要包括速度场和应力场的后置处理。该系统目前只是一个雏形，经过不断发展和完善，有望成为异型材口模挤出过程模拟的通用分析软件。     

鱼尾型机头中熔体流动的三维流场分析

本文利用ANSYS和MATLAB软件，对鱼尾型片材机头中熔体的速度、压力、剪切应力和粘度的分布进行三维有限元模拟和分析。探知了熔体在流道内的运动规律及特点并分析其原因，对口模设计具有定的指导作用。     

Ultrasonic oscillations effect on rheological and processing properties of metallocene‐catalyzed linear low density polyethylene

The effects of ultrasonic oscillations and die materials on die pressure, productivity of extrusion, melt viscosity of metallocene‐catalyzed linear low density polyethylene (mLLDPE), as well as their mechanism were studied in a special ultrasonic oscillations extrusion system developed in our lab. Die materials used in our experiment included steel, brass, and polytetrafluoroethylene (PTFE)_. The experimental results showed that ultrasonic oscillations as well as die materials have great influence on the rheological and processing behavior of mLLDPE. Ultrasonic oscillations can greatly increase the productivity of mLLDPE melt extruded through different dies, and can decrease the die pressure and the melt viscosity of mLLDPE. Compared with steel or brass die, mLLDPE melt extruded through PTFE die is more sensitive to ultrasonic oscillations. A possible mechanism for the improved processability of mLLDPE is proposed in this article. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1873–1878, 2003     

热塑性弹性体SBS异型材挤出模具设计

本文通过对异型材截面形状及原材料挤出成型性能分析，设计了正确的口模形状及合理的流线形流道，设计的模具能够生产出符合尺寸精度要求的型材。     

Light-sensitive elastomers modified by 4-(N-dimethylmaleimido)-benzenesulphenyl chloride

New light-sensitive polymers were prepared by modification of four different elastomers with 4-(N-dimethylmaleimido)-benzenesulphenyl chloride (DMI-BSCI). Polydienes modified by DMI-BSCI form block copolymers. These polymers show a strong increase of the glass transition temperature T_g whereby the T_g increase of modified poly(octenamer) is much smaller. Higher modified polydienes have two T_g. Modified poly(octenamers) show a melting temperature dependence T_m on the content of trans double bonds which is characteristic of statistical copolymers. The ratio of rate constants with which trans- and cis-structures in poly(octenamer) are occupied by DMI-BSCI, is

$\text{k}{}_{\mathrm{trans}}\text{k}{}_{\mathrm{cis}}\text{= 0.34}$

     

PROBING HIDDEN POLYMERIC INTERFACES USINGIR-VISIBLE SUM-FREQUENCY GENERATION SPECTROSCOPY

Understanding the molecular-level processes underlying interfacial phenomena is important in the area of adhesion. We briefly introduce IR-visible sum-frequency generation spectroscopy (SFG) using a total-internal-reflection geometry for the study of polymer-air, polymer-solid, and polymer-polymer interfaces. The following examples, predominantly of work done in our lab, illustrating differences in molecular structure and dynamic properties at interfaces are presented: the air- and solid-interface structure of an amorphous polystyrene (PS) and a semicrystalline polymer with side-chain crystallinity, poly(octadecyl acrylate) (PA-18); structure of a polymer-polymer interface between thin films of a semicrystalline polymer with side-chain crystallinity, poly(vinyl-N-octadecylcarbamate- co-vinyl acetate), and an amorphous PS; thermal order-to-disorder transitions of the air and solid interface of PA-18, and the interface of this polymer with PS; and dynamic surface-relaxation studies of a rubbed PS film.     

Recycling of ethylene propylene diene monomer (EPDM) waste. III. Processability of EPDM rubber compound containing ground EPDM vulcanizates

The rheological behavior of ethylene propylene diene monomer (EPDM) compounds containing ground EPDM waste (W‐EPDM) of known composition was studied by using a Monsanto processability tester in a temperature range of 90–110°C and a shear rate range of 306.7–1533.24 s^?1. It is found that the shear viscosity decreases slightly with increasing W‐EPDM loading because of wall slip that results from the migration of lubricants from the W‐EPDM. The addition of W‐EPDM to raw EPDM results in a decreased die swell at all temperatures and shear rates. SEM photomicrographs of the EPDM extrudate surface show improved surface smoothness and reduced extrudate distortion when EPDM is blended with W‐EPDM. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2204–2215, 2003     

基于流动平衡的塑料挤出模优化设计

在构建流道三维参数化模型的基础上,将有限元数值分析和优化技术相结合,以口模出口处型材截面上各子区域平均流速相等为优化目标,以压缩段入口壁厚和平直段长度为设计变量,对挤出模优化设计进行了研究。并以实例说明了优化设计的具体过程,验证了所用方法的正确性和有效性。     

一种多元复合地基复合模量的计算方法

多元复合地基的沉降计算依赖于其复合模量的取值.目前多元复合地基复合模量计算均未考虑桩对桩间土的侧向挤密作用,因而其沉降计算结果与实际值相差较大.而考虑桩体与桩间土的侧向挤压作用,依据线弹性变形理论,推求的多元复合地基的复合模量公式应用于工程实例,结果表明,该方法是合理可行的,并且存在着参数易于确定、方法简便、机理清楚的特点.