In situ polymerization and characterization of polyester‐based polyurethane/nano‐silica composites

Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry     

低掺杂浓度Nd:YVO4激光器的输出特性研究

在对Nd:YVO_4晶体的掺杂浓度和晶体长度对激光器性能的影响进行了分析后,报道了利用掺杂浓度为0.3at％,通光长度为10mm的Nd:YVO_4晶体作为增益介质,带光纤耦合的激光二极管端面抽运的Nd:YVO_4激光器。在抽运功率为27.365W时,获得了14.85W的TEM_(00)模输出,光一光转换效率为60.49％,斜效率达64.5％。     

Equivalent Conditions for Convergence of Splittings of Non-Hermitian Indefinite Matrices

We present some sufficient and necessary conditions for convergent splitting of a non-Hermitian indefinite matrix. Some sufficient conditions to determinate a matrix with a (strongly) dominant symmetric part for a class of boundary value problem are also obtained. These results are applicable to identify the convergence of iterative methods for solving large sparse systems of linear equations.     

主动约束层阻尼板结构动力学建模研究

将有限元法和GHM法相结合，给出了建立主动约束层阻尼（ACLD）板结构动力学模型的新方法。建模时，考虑到粘弹材料（VEM）的纵向位移影响，采用GHM方法描述VEM的本构关系，解决了VEM的力学特性随温度和频率变化的难点，避免因VEM的复杂本构关系而产生的微分积分方程。算例表明本文给出的建模方法是准确的，ACLD结构能够有效控制结构振动。     

钢锭零能少氧化均热轧制的研究

根据计算机的辅助分析,采用新的钢锭传搁、注后强制水冷却、垫铁脱模等工艺后,入炉钢锭的热焓已超过开坯轧制需要,利用普通均热炉代替钢锭保温车,可完全依靠到钢锭自身潜热与显热进行均热。对不同锭型与钢种采用经试验的最佳时间均热后再轧制,收与保温车均热钢锭直接轧制相同的效果。     

光纤模式噪声的研究

综述了光纤模式噪声的产生、计算，并介绍了减小它的一些方法。     

镨掺杂分布对1.3μm光纤放大器特性影响

对掺氟化镨玻璃光纤放大器的小信号增益，用广义的高斯近似公式可获得精确的分析表达。文中研究了限制光纤芯层中央部分的镨掺杂对光纤放大器特性的影响，结果发现限制镨掺杂分布能改进光纤放大器的工作效率，且截止波长比芯层全部均匀掺镨的光纤更长。     

A method for the preparation of PMMA-SiO2 nanocomposites with high homogeneity

It is possible to optimize the performance of the inorganic-organic composites dispersing the inorganic component in the organic matrix on a nanomiter length scale. If dry the inorganic phase cannot be intimately dispersed during the incorporation in the matrix. When the particle surface is organically modified, and the incorporation is made starting from a liquid dispersion (particles in polymer solution), the resulting composites exhibit an excellent homogeneity. Here, monolithic [poly(methyl methacrylate)/monodisperse silica particles] nanocomposites have been prepared and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), dynamic light scattering (DLS), micro-hardness, and differential scanning calorimetry (DSC).     

Magnetic properties of nickel filament polymer-matrix composites

The magnetic properties of polyethersulfone-matrix composites with 3-19 vol.% polycrystalline nickel filaments (0.4 (im diam) were investigated. These filaments were found to exhibit hysteresis energy loss 10800 J/m³ of nickel and coercive force 16.9 kA/m, compared to corresponding values of 4930 J/m³ and 4.7 kA/m for 2 μ.m diam polycrystalline nickel fibers, 1020 J/m³ and 0.5 kA/m for 20 μm diam polycrystalline nickel fibers, and 1280 J/m³ and 2.3 kA/m for solid polycrystalline nickel.