Amorphous Dual-Layer Coating: Enabling High Li-Ion Conductivity of Non-Sintered Garnet-Type Solid Electrolyte

Garnet-type oxide Li_6.4La₃Zr_1.4Ta_0.6O₁₂ (LLZTO) has attracted considerable attention as a highly promising solid state electrolyte. However, its high ionic conductivity is achievable only after high temperature sintering (≈1200 °C) to form dense pellets but with detrimental brittleness and poor contact with electrodes. Herein, a novel strategy to achieve high Li⁺ ion conductivity of LLZTO without sintering is demonstrated. This is realized by ball milling LLZTO together with LiBH₄, which results in a LLZTO composite with unique amorphous dual coating: LiBO₂ as the inner layer and LiBH₄ as the outer layer. After cold pressing the LLZTO composite powders under 300 MPa to form electrolyte pellets, a high Li⁺ ion conductivity of 8.02 × 10^–5 S cm^–1 is obtained at 30 °C, which is four orders of magnitude higher than that of the non-sintered pristine LLZTO pellets (4.17 × 10^–9 S cm^–1). The composite electrolyte displays an ultrahigh Li⁺ transference number of 0.9999 and enables symmetric Li–Li cells to be cycled for 1000 h at 60 °C and 300 h at 30 °C. The significant improvements are attributed to the continuous ionic conductive network among LLZTO particles facilitated by LiBH₄ that is chemically compatible and electrochemically stable with Li metal electrode.     

大振幅纵-扭复合振动模式超声变幅杆

研究了纵向及扭转振动在指数型变幅杆中的传播规律。通过选择指数型变幅杆的截面函数变化形式，导出了在同一变幅杆中纵向及扭转振动同频共振的条件，推出了指数型纵－扭复合变幅杆的频率设计方程，为超声应用技术中纵－扭复合振动系统的研究及开发奠定了一定的理论基础。     

压电晶体-固体-液体结构中IDT的体声波激励

对压电晶体－固体（层）－液体结构中叉指换能器的体声波激励效应进行了深入探讨，通过引入压电晶体－固体层界面的界面有效介电常数，研究了叉指换能器的体声波激励效应与晶体切向、电边界条件及固体层归一化厚度之间的关系。数值分析表明，电边界条件对叉指换能器体声波激励效应的影响可忽略；体声波激励效应与压电晶体切向和固体层归一化厚度密切相关；通过选择恰当的晶体切向、固体层归一化厚度和慢度，叉指换能器仅向液体中激励体声波，且可确定出最强体声波激励时的结构参数。文中所得结果，为有关液体声传感器结构的优化设计奠定了基础。     

用调制转移光谱技术研制微型全固体稳频激光器

报道采用自行研制的半导体激光泵浦微片Nd∶YVO4晶体,经驻波腔内KTP晶体倍频获得532 nm激光输出的全固体单频可调谐微型激光器.采用光外差调制转移光谱技术获得超高信噪比碘分子跃迁超精细结构光谱,并实现频率稳定度优于10-12(1秒积分时间)的激光频率高精度绝对锁定.     

Synthesis,characterization, magnetic measurements and liquefied petroleum gas sensing properties of nanostructured cobalt ferrite and ferric oxide

In the present paper, a series of nanostructured cobalt ferrite systems was synthesized in different compositions via chemical co-precipitation method. The X-ray diffraction analysis of cobalt ferrite systems confirmed the formation of its nanoparticles having minimum crystallite size 7 nm. The surface morphologies of the cobalt ferrite illustrate the distribution of partially agglomerated spherical nanoparticles having particle size ~12 nm. The magnetic behaviors of the synthesized materials were characterized by magnetic measurements. Liquefied petroleum gas sensing investigations of the fabricated pellets illustrate that the cobalt ferrite synthesized in 1:1 M ratio possesses an improved response in comparison to other compositions. The maximum sensitivity of cobalt ferrite film sensor was 2.0 MΩ/s. The response and recovery times were ~30 and 60 s, respectively. The sensor was 95% reproducible after three months of fabrication of the film, showing the stability of the fabricated sensor.     

改性的薄SOS膜CMOS器件辐射加固特性

利用注硅固相外延的方法对0.2μm SOS薄硅膜材料进行改性,并制作了单管pMOSFET,nMOSFET及54HC04电路．测量了单管的迁移率,并对样品进行了瞬态辐射实验和总剂量辐射实验,发现用改性后的SOS薄硅膜材料制作的电路,不仅具有同标准0.5μm SOS材料制作的电路相当的动态特性,而且具有很好的抗瞬态辐射能力,并且其抗总剂量辐射能力也达到了很高的水平．     

不同方法制备BiNbO4微波陶瓷的研究

研究了固相反应法和熔盐法两种制备方法对BiNbO4微波陶瓷的烧结温度、微观形貌、结构和介电性能的影响。实验表明:在添加CuO和V2O5分别为0.1%(质量分数)时,固相反应法在较低的烧结温度下可获得较致密的陶瓷样品,样品表面晶粒呈球状,品质因数与谐振频率的乘积即Q×f值较大,谐振频率温度系数为正值;熔盐法制得的陶瓷样品具有明显的各向异性,晶粒呈棒状,谐振频率温度系数随烧结温度的升高由正值向负值变化,在940℃烧结,介电常数为38,Q×f值为7781 GHz,谐振频率温度系数近零,为0.92×10-6/℃。两种方法制得的陶瓷样品在微波频段介电常数相近。     

固体微粒遮蔽的红外突防措施分析

随着弹道导弹防御系统对弹道导弹中段弹头的发现、识别跟踪和拦截能力的不断提高,针对中段弹头突防措施的研究越来越重要.针对采用固体微粒进行红外遮蔽这种突防措施进行了探索,建立了气体携带固体微粒的喷射过程数学模型,利用数值求解方法得出了喷射过程中气体及固体颗粒在弹头周围空间的瞬态浓度分布,计算了其红外遮蔽效果.研究结果表明:...     

模拟扫描电镜像衬度的体构件Monte Carlo方法

利用Mollte Carlo计算方法可以模拟电子束与样品的相互作用过程,从而了解扫描电子显微学中信号的产生机制,本工作中,我们采用体构件法来产生复杂试样的几何构型,利用光线追踪算法求得散射事件间的步长抽样修正。电子散射的物理模型则采用Mott散射截面描述电子与原子间的弹性相互作用,以及用介电函数理论描述电子与固体的非弹性相互作用,同时还考虑到了二次电子的级联产生过程．以此,我们模拟计算出了若干复杂几何体的二次电子像和背散射电子像。     

稳腔固体激光器运转时热透镜焦距的测量

给出一测量激光二极管 (LD)端面抽运固体激光器稳态运转时腔内激活介质热透镜焦距的简便方法。采用混合模类高斯光束描述激光器输出镜后的光场分布 ,通过一狭缝在不同位置横向扫描光场来测得光束的光斑尺寸和描述光束的质量因子M2 ,根据混合模类高斯光束传播规律推导出光束的束腰及在相同激光器参数下对应的基模高斯光束束腰的大小 ,由此利用稳定谐振腔标准传输矩阵理论可得到相应的激光介质的热透镜焦距。基于上述测量原理 ,对LD端面抽运Nd∶YVO4 固体激光器热透镜焦距进行了测量 ,实验结果和理论分析相符。