Monitoring plasma etching of biomolecules by imaging ellipsometry

Low-pressure plasma discharges can be applied to remove various biomolecules from surfaces. However, the knowledge on the interaction between plasma and biomolecules and the kinetics of their removal is still rather poor, which is a major limiting factor for the optimization of this type of plasma treatment. This is, among other reasons, because of the restrictions of currently used techniques for the evaluation of the rates of biomolecule removal during plasma treatment. Therefore, an alternative method based on imaging ellipsometry is applied in this study. It is shown that this method allows reliable semi-quantitative comparison of the treatment efficiency of plasma discharges sustained in different gas mixtures.     

Growth and optical properties of Pr~(3+):La_2CaB_(10)O_(19) crystal

Pr3+ doped La2CaB10O19 crystal were grown by the top-seeded solution growth(TSSG) method.The absorption spectra,emission spectra and lifetime were measured at room temperature.The J-O parameters(Ωt,t=2,4,6),the radiative transition probabilities AJ,J',oscillator strengths PJ,J',radiative lifetime τ,fluorescence branch ratios βJ and the value of integrated emission cross section have also been calculated.Five main absorption bands,3H4 to 3P1+3P2,3P0,1D2,3F3 + 3F4 and 3F2,were observed in the absorption spect...     

微晶玻璃的制备与光谱特性

高温熔制摩尔组分为32CaO-12Y₂O₃-24Al₂O₃-31SiO₂-1Yb₂O₃的玻璃, 制得的玻璃于950、1050、1100℃三个不同温度进行热处理, 用XRD分析热处理后样品的相变, 用TEM观察1050℃热处理后的样品, 并研究了1050℃热处理前后样品的光谱特性. 研究结果表明: 玻璃在1050℃热处理后, 在玻璃中产生单一YAG相微晶颗粒; 热处理前后样品光谱特性的变化表明热处理后掺杂的Yb ³⁺离子择优进入到YAG晶格位, 制备得到了透明Yb:YAG微晶玻璃.     

掺Er3+碲铌酸盐玻璃的发光特性研究

以TeO2,Nb2O5,ZnO,Na2O为基质原料制备了掺铒碲铌酸盐玻璃,差热分析表明,Nb2O5的加入可以明显提高碲酸盐玻璃的热稳定性。同时应用McCumber原理计算的结果显示,摩尔分数为4%的Nb2O5的加入可使碲酸盐玻璃在1.53μm处的受激发射截面提高8%,其峰值达8.9×10-21cm2,而受激发射截面的有效带宽几乎不变。     

Tribochemistry in contact recording

Even though the flying height is approaching molecular dimensions, it is expected to decrease as the areal recording density is increased. This study employs a new low-velocity test to obtain ultralow flying height with sustained intermittent asperity contacts and random seek accessing in a region near the middle diameter of the disk. Sensitive surface analytical tools are employed to follow tribochemical changes. Profiles are periodically measured across the disk surface using Fourier transform infrared spectroscopy for lubricant thickness and scanning-imaging micro-ellipsometry. Zdol lubricant is removed from the tested region through evaporation of low molecular weight scission fragments. The removal rate increased with increasing chemisorbed fraction and decreasing relative humidity. The increased removal rate is attributed to increases in the Zdol relaxation time. A longer relaxation time allows more time for bond dissociation following asperity contacts. Chemisorption sites in the tested region were occupied by chemisorbed scission fragments with a carboxylic acid end group. Amine and sodium salts of the carboxylic acid were detected on the tested regions of Zdol lubricated, and unlubricated, overcoats. The presence of tribochemically generated carboxylic acid groups on Zdol and overcoat carbon explain the increased water adsorption measured on the tested regions.     

钛合金中钒元素看谱分析方法研究

使用光栅看谱镜和棱镜看谱镜研究了钛合金中V元素看谱分析用可见光谱线特征,计算机模拟了V和Ti元素的可见光谱图,摄制了彩色图谱.研究了钛合金中V元素的V437.92 nm、V459.41 nm和 V485.15 nm等分析谱线组的特征,给出了分析用谱图和半定量分析用强度标志.研究了钛合金中V元素的看谱分析方法,进行了牌号鉴别应用研究.结果可用于钛合金和其他合金中V元素的定性分析、半定量分析,满足生产现场材料牌号鉴别的需要.     

电子束蒸发非晶硅光学薄膜工艺研究

研究了沉积时真空室真空度、基片温度和沉积速率对常用电子束蒸发非晶硅(a-Si)光学薄膜的折射率和消光系数的影响。结果表明,在300~1100nm的波长范围内,真空室真空度、基片温度和沉积速率越高,则所得a-Si薄膜折射率越高,消光系数越大。并将实验结果用于半导体激光器腔面高反镜用a-Si膜镀制,发现在选择初始真空为1E-6×133Pa、基片温度为100℃和沉积速率为0.2nm/s时所得高反镜的光学特性比较好,在808nm处折射率和消光系数分别为3.1和1E-3。     

The Spectroscopic Systems for the Study of Light Impurity Particle Transport in the HT-7 Tokamak

Three spectroscopic systems have been developed for the study of light impurity particle transport in the HT-7 tokamak. A visible multi-channel spectroscopic system （VIS） is used to obtain the brightness distribution of the line emission from ionized light impurities. The profile of Zeff（r） has been obtained from the visible multi-channel bremsstrahlung measurement （VB）. The system with a rotating hexahedral mirror for space-time resolved spectroscopy measurement from ultraviolet to visible （UV） can provide the brightness distribution of two different emission lines of the light impurities simultaneously. The emissivities by these multi-channel measurements can be obtained by Abel inversion. The measurement was performed in typical OH discharges in the HT-7 tokamak. The carbon particle transport was analyzed. The feasibility of these diagnostic systems for the impurity particle transport study is clearly demonstrated.     

立方ZnMgO基体中六方ZnO量子点的化学溶液制备技术

首次报道了利用相分凝技术在非晶石英衬底上立方ZnMgO基体中制备六方ZnO量子点的化学溶液方法.对所制备的ZnO/ZnMgO/SiO2进行了原子力显微镜(AFM)、X射线衍射(XRD)、光致发光(PL)、椭圆偏振光谱(SE)表征.XRD表征表明当六配位Zn2 以替位的形式取代六配位Mg2 时,会导致相同衍射条件下立方ZnMgO的2θ比立方MgO的2θ小.SE表征发现ZnO量子点的量子效应导致了ZnO量子点的激子吸收能(3.76eV)比ZnO体晶的能带隙(3.37 eV)大.AFM表征表明:导致薄膜的XRD的衍射峰、α吸收峰和PL发射峰皆很宽的部分原因是由于组成所制备薄膜的晶粒尺寸分散较大、形状不一引起的.     

螺旋波等离子体发射光谱研究

为了解螺旋波等离子体的光学行为及特性,对螺旋波等离子体氩气放电进行了发射光谱(OES)测量,结果显示:谱线强度在模式转换时出现大幅增加。研究了不同气压下谱线强度随功率的变化关系,并采用发射光谱强度比值法对电子激发温度进行了计算,结果表明:在螺旋波放电阶段对应的电子激发温度随着功率增加呈下降趋势。