冲击加载条件下AZ31B镁合金变形孪晶的微观特征

采用分离式Hopkinson压杆(SHPB)对A231B热轧板材沿轧向进行冲击实验,加载应变率约为1200 s-1．利用金相显微镜和透射电子显微镜观察微观组织特征。结果表明：在应变量约为0.003的条件下,压缩孪生{10?1}/<10?2>与拉伸孪生{1?02}/< 1?01>均为孪生塑性变形机制,这与准静态加载下单一的拉伸孪生机制不同。孪晶内部的微观特征演化过程包括：1）平行排列基面层错的出现;2）与孪晶界成特定角度平行排列位错线的形成;3）位错胞的产生。     

芝麻香型白酒生产条件对比研究

芝麻香酒以特殊的口感及香气而独树一帜,高温堆积、高温发酵是形成其特殊风格的关键工艺。通过对芝麻香型白酒的关键工艺点——堆积及发酵进行生产试验研究。结果表明,综合酒质及出酒率考虑,芝麻酒生产最适堆积温度为45-50℃,最佳入窖温度为30-33℃。     

虚拟弧齿锥齿轮齿面可控性椭球抛物面误差的叠加新方法

为了研究弧齿锥齿轮测量精度稳定性及不同程序测量误差的问题,提出了一种对虚拟弧齿锥齿轮进行可控误差叠加的方法.分析虚拟弧齿锥齿轮建立时产生的误差,在虚拟工件上叠加可控的椭球抛物面误差,调用OpenGL图形库中的函数将叠加误差后的效果进行直观对比.研究结果表明:对虚拟弧齿锥齿轮进行误差可控的叠加,得到了齿面误差可控的虚拟弧齿锥齿轮.     

基于自适应遗传算法的复合材料层合板铺层顺序优化设计

分析了杂交概率和突变概率对遗传算法收敛性的影响,提出了一种自适应遗传算法,并利用该方法研究了复合材料层合板的铺层顺序优化设计问题。算例结果表明,提出的复合材料层合板铺层顺序优化设计方法能够明显的提高计算效率。     

Investigations on physical,mechanical, morphological and water absorption properties of ramie/hemp/kevlar reinforced vinyl ester hybrid composites

Structural uses in the vehicle, aerospace, and sporting goods industries are being supplanted by hybrid composites that utilized natural fibers as reinforcements. The main focus of this work is to fabricate and characterize the ramie, hemp, and kevlar fabric reinforced hybrid vinyl ester composites. The composite laminates were fabricated via economically feasible and flexible hand lay-up technique. Overall six composites were prepared by varying the stacking sequence, including both hybrid and non-hybrid composites. The prepared composites were subjected to physical analysis (density, void fraction), mechanical tests (tensile, flexural, interlaminar shear, and impact test), morphological analysis (scanning electron microscopy), and water absorption test. The hybrid composites exhibited lesser void percentage than the non-hybrid composites. The mechanical properties were maximum for kevlar fabric skinned with core natural fabric reinforced composites (L-5, L-6) due to hybridization of highly strengthened kevlar fabrics. Moreover, the number fabric layers reinforced to achieve the standard thickness also affected the mechanical properties. All composite morphologies exhibited the same failure characteristics, including transverse interlaminar shear cracking, microbuckling, and fiber rip. The texture of the Kevlar yarns is uniform, but the texture of the natural fabric yarns is relatively less uniform. In comparison to the salt water medium, the percentage of water absorbed by composites in normal and distilled water was greater. This is due to the presence and accumulation of salt particles on the surface of the materials, which inhibits the action of water molecules, resulting in a drop in the proportion.     

Efficient Stacking on Protein Amide Fragments

The less polar π‐surface of protein amide groups is exposed in many receptor binding sites, either as part of the backbone or in Gln/Asn side chains. Using quantum chemical calculations and Protein Data Bank (PDB) searches on model systems, we investigate the energetics and geometric preferences for the stacking on amide groups of a large number of heteroarenes that are relevant to medicinal chemistry. From this study, we discern that the stacking energy of an aromatic ligand substituent can be improved by: 1) orienting the fragment dipole vector such that it is aligned in an antiparallel fashion with the dipole of the interacting protein amide group, 2) increasing its dipole moment, and 3) decreasing its π‐electron density. These guidelines should be helpful to more rationally exploit this interaction type in future structure‐based drug design.     

DNA‐Templated Synthesis of Perylenediimide Stacks Utilizing Abasic Sites as Binding Pockets and Reactive Sites

DNA is considered to be a promising biomolecule as a template and scaffold for arranging and organizing functional molecules on the nanoscale. The construction and evaluation of DNAs containing multiple functional molecules that are useful for optoelectronic devices and sensors has been studied. In this paper we report the efficient incorporation of perylenediimide (PDI) units into DNA by using abasic sites both as binding sites and as reactive sites and the construction of PDI stacks within the DNA structure, accomplished through the preorganization of the PDI units in the hydrophobic pocket within the DNA. Our approach could become a valuable method for construction of DNA/chromophore hybrid structures potentially useful for the design of DNA‐based devices and biosensors.     

Functionalization of reduced graphene oxide nanosheets via stacking interactions with the fluorescent and water-soluble perylene bisimide-containing polymers

Reduced graphene oxide (RGO)-polymer composites were prepared via π-π stacking interactions of RGO with the perylene bisimide-containing poly(glyceryl acrylate) (PBIPGA). PBIPGA was synthesized via atom transfer radical polymerization (ATRP) of solketal acrylate (SA), using bifunctional N,N′-bis{2-[2-[(2-bromo-2-methylpropanoyl)oxy]ethoxy]ethyl}perylene-3,4,9,10-tetracarboxylic acid bisimide (PBI-Br) as the initiator, and subsequent hydrolysis of the acetal-protecting group. PBIPGA was characterized by ¹H NMR spectroscopy, gel permeation chromatography (GPC), UV-visible absorption spectroscopy and fluorescence spectroscopy. The presence of π-π stacking interactions between PBI and the RGO surface was suggested by fluorescence and UV-visible absorption spectroscopy results. The chemical states and π-π stacking interaction, morphology, and composition of RGO-PBIPGA composites were characterized, respectively, by X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The low cytotoxicity level of the RGO-PBIPGA composites was revealed by incubation with 3T3 fibroblasts in 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) assays in vitro.     

永磁感应子式步进电动机转子铁心迭片系数的影响及其修正方法

介绍了混合式步进电动机转子铁心迭片系数产生的影响和修正方法，以及利用提高转矩的有关结构。